The History of Chemistry

This is a brief history of how chemists understand the way liquids wet things. The first glimpse was by Francis Hauksbee in the early 1700s, and how water rises in narrow tubes. Through the 18th century, natural philosophers described surface tension. The 19th century brought understanding of wetting via macroscopic observations and descriptions. The 20th century added insights of quantum mechanics and the influence of surface roughness. Finally we discuss the 20th-century observation of superhydrophobicity, both natural and eventually artificial.Support the show Support my podcast at https://www.patreon.com/thehistoryofchemistry Tell me how your life relates to chemistry! E-mail me at steve@historyofchem.com Get my book, O Mg! How Chemistry Came to Be, from World Scientific Publishing, https://www.worldscientific.com/worldscibooks/10.1142/12670#t=aboutBook

In which we talk about the history of fractals and how they relate to chemistry. There is a brief overview of what a fractal is and how it developed in mathematics. Then we talk of how fractals apply to chemistry, including surface reactions, descriptions of molecular structures both artificial and natural, growth of polymers, and even how the concentrations and flows of minerals in streams follow a fractal variation with time.Support the show Support my podcast at https://www.patreon.com/thehistoryofchemistry Tell me how your life relates to chemistry! E-mail me at steve@historyofchem.com Get my book, O Mg! How Chemistry Came to Be, from World Scientific Publishing, https://www.worldscientific.com/worldscibooks/10.1142/12670#t=aboutBook

It's an ancient story, but fossils have been with us since time immemorial. In this episode, we hear about the history of chemists and their interpretation of fossils. Scientists first began considering fossils as evidence of past life in the 17th century. We hear about the fossil record, and the oldest fossils, then the oldest fossils with organic matter preserved, and the chemical controversy over how collagen can remain for millions of years.Support the show Support my podcast at https://www.patreon.com/thehistoryofchemistry Tell me how your life relates to chemistry! E-mail me at steve@historyofchem.com Get my book, O Mg! How Chemistry Came to Be, from World Scientific Publishing, https://www.worldscientific.com/worldscibooks/10.1142/12670#t=aboutBook

Refrigeration always has been closely intertwined with chemistry. In this episode we explore the history of refrigerants, from the first hints of artificial cooling in the mid-1700s, through the invention of the first practical refrigerator 8 decades later. We talk about a variety of refrigerants through the 20th century. Finally we examine some other newer or less-common methods of cooling.Support the show Support my podcast at https://www.patreon.com/thehistoryofchemistry Tell me how your life relates to chemistry! E-mail me at steve@historyofchem.com Get my book, O Mg! How Chemistry Came to Be, from World Scientific Publishing, https://www.worldscientific.com/worldscibooks/10.1142/12670#t=aboutBook

Magnetic tape was an integral part of the new, growing recording industry. Herein we talk about the chemical history of magnetic recording, from the first idea in 1888, onward. We encounter Poulsen, Pfleumer, Stille, Nagai, Mullin, and an array of corporations as well. Finally we discuss a bit about digital computers and the history of magnetic tapes for data.Support the show Support my podcast at https://www.patreon.com/thehistoryofchemistry Tell me how your life relates to chemistry! E-mail me at steve@historyofchem.com Get my book, O Mg! How Chemistry Came to Be, from World Scientific Publishing, https://www.worldscientific.com/worldscibooks/10.1142/12670#t=aboutBook

Here we talk about supersized sandwich compounds and their history, beginning with ferrocene in the 1950s. We go from single-decker to double-, triple, and quadruple-decker sandwich compounds through the 1970s and 1980s, a variety of "breads" and "fillings," and then even bigger as we move to the 21st Century.Support the show Support my podcast at https://www.patreon.com/thehistoryofchemistry Tell me how your life relates to chemistry! E-mail me at steve@historyofchem.com Get my book, O Mg! How Chemistry Came to Be, from World Scientific Publishing, https://www.worldscientific.com/worldscibooks/10.1142/12670#t=aboutBook

Herein we examine the cubical hydrocarbon, cubane, and its role in chemical history. We talk of difficulties in synthesis, possible uses as an explosive, its use as an isostere to benzene in medicinal compounds, and polymers of cubane. Patreon supporters can download a supplemental sheet to see some of the molecular structures I discuss.Support the show Support my podcast at https://www.patreon.com/thehistoryofchemistry Tell me how your life relates to chemistry! E-mail me at steve@historyofchem.com Get my book, O Mg! How Chemistry Came to Be, from World Scientific Publishing, https://www.worldscientific.com/worldscibooks/10.1142/12670#t=aboutBook

In which we talk about how chirality, or handedness, has diffused through chemistry since its discovery in the 19th century, starting with Louis Pasteur. We look at work by Arnaldo Piutti and Emile Fischer. We discuss not only organic compounds, but amino acids, proteins, DNA, and inorganic chiral compounds. Ultimately we have to bring up the question of the biochemical handedness of life. Patreon supporters may download a supplemental sheet of some of the molecular structures mentioned in this episode.Support the show Support my podcast at https://www.patreon.com/thehistoryofchemistry Tell me how your life relates to chemistry! E-mail me at steve@historyofchem.com Get my book, O Mg! How Chemistry Came to Be, from World Scientific Publishing, https://www.worldscientific.com/worldscibooks/10.1142/12670#t=aboutBook

In which we talk about the history of using ammonia, the nitrogen analog of methane, as a fuel. We start two centuries ago with Goldsworthy Gurney, move to the mid-19th century when horseless carriages began to appear in Europe. World War II spurred necessary fuel adjustments to public transportation. We then examine post-war research. We tackle some pros and cons of using ammonia as fuel, as well as the ecological spectrum of ammonia sources.Support the show Support my podcast at https://www.patreon.com/thehistoryofchemistry Tell me how your life relates to chemistry! E-mail me at steve@historyofchem.com Get my book, O Mg! How Chemistry Came to Be, from World Scientific Publishing, https://www.worldscientific.com/worldscibooks/10.1142/12670#t=aboutBook

Here we talk about how chemists historically have viewed the way life began: as chemicals self-organizing. The earliest serious chemical views began in the 1870s, with synthesis of proteins. Ideas through the decades included warm ponds, auto-catalytic enzymes, genes (whatever they were), a primitive reducing atmosphere, lightning bolts, and DNA or RNA.Support the show Support my podcast at https://www.patreon.com/thehistoryofchemistry Tell me how your life relates to chemistry! E-mail me at steve@historyofchem.com Get my book, O Mg! How Chemistry Came to Be, from World Scientific Publishing, https://www.worldscientific.com/worldscibooks/10.1142/12670#t=aboutBook

Contrary to popular belief, chemists have always found involvement in politics. Herein are some examples of chemists getting involved politically, whether willingly or unwillingly, from the past 250 years, starting with Englishman Joseph Priestley.Support the show Support my podcast at https://www.patreon.com/thehistoryofchemistry Tell me how your life relates to chemistry! E-mail me at steve@historyofchem.com Get my book, O Mg! How Chemistry Came to Be, from World Scientific Publishing, https://www.worldscientific.com/worldscibooks/10.1142/12670#t=aboutBook

We look at the history of some recent problems in recycling materials. First we examine the history of wind farms, and how to recycle the fan blades. Second we talk about recent history and problems of recycling polyethylene terephthalate. Then we discuss the persistent and growing problem of electronics waste. Finally, we briefly touch on recycling of spent batteries.Support the show Support my podcast at https://www.patreon.com/thehistoryofchemistry Tell me how your life relates to chemistry! E-mail me at steve@historyofchem.com Get my book, O Mg! How Chemistry Came to Be, from World Scientific Publishing, https://www.worldscientific.com/worldscibooks/10.1142/12670#t=aboutBook

Given the environmental catastrophe into which we now zombie-walk, here is a bit about the history of extracting greenhouse gases directly from the air. Extracting carbon dioxide from the atmosphere began in the 1930s, but proposals to do it environmentally only began about 25 years ago, with the first large-scale systems appearing in the 2020s. We also talk a little about pulling a worse gas, methane, from the atmosphere.Support the show Support my podcast at https://www.patreon.com/thehistoryofchemistry Tell me how your life relates to chemistry! E-mail me at steve@historyofchem.com Get my book, O Mg! How Chemistry Came to Be, from World Scientific Publishing, https://www.worldscientific.com/worldscibooks/10.1142/12670#t=aboutBook

We hear about the history of hydrogen gas as a fuel, starting in the early 1800s with François Isaac de Rivaz. We continue through the 19th and 20th centuries, with dual-burning vehicles, airplanes, and fuel-cells. We talk of advantages and disadvantages of such engines, and the ecological spectrum of hydrogen gas.Support the show Support my podcast at https://www.patreon.com/thehistoryofchemistry Tell me how your life relates to chemistry! E-mail me at steve@historyofchem.com Get my book, O Mg! How Chemistry Came to Be, from World Scientific Publishing, https://www.worldscientific.com/worldscibooks/10.1142/12670#t=aboutBook

In which we talk about the history of differently abled chemists, from around the year 1600 to the present. We mention some differently abled chemists, and how the American Chemical Society and Royal Society of Chemistry handle things, plus hope for continued improvement in the future.Support the show Support my podcast at https://www.patreon.com/thehistoryofchemistry Tell me how your life relates to chemistry! E-mail me at steve@historyofchem.com Get my book, O Mg! How Chemistry Came to Be, from World Scientific Publishing, https://www.worldscientific.com/worldscibooks/10.1142/12670#t=aboutBook

We hear about the recent history of quantum computing to do quantum calculations on molecules. First we briefly discuss different types of computers. Then we talk about the kinds of calculations chemists want to do with quantum computers. We also learn about some ways chemists currently use to simplify the mathematics for quantum calculations.Support the show Support my podcast at https://www.patreon.com/thehistoryofchemistry Tell me how your life relates to chemistry! E-mail me at steve@historyofchem.com Get my book, O Mg! How Chemistry Came to Be, from World Scientific Publishing, https://www.worldscientific.com/worldscibooks/10.1142/12670#t=aboutBook

In which we [cue theremin!] discuss how chemistry is presented in science-fiction stories. We start with Mary Shelley's "Frankenstein," move through Jules Verne and H.G. Wells, then to 20th-century writers like Isaac Asimov. Kurt Vonnegut, Fred Hoyle, H. Beam Piper, and many others. We talk of "Star Trek," "Battlestar Galactica," and David Foster Wallace.Support the show Support my podcast at https://www.patreon.com/thehistoryofchemistry Tell me how your life relates to chemistry! E-mail me at steve@historyofchem.com Get my book, O Mg! How Chemistry Came to Be, from World Scientific Publishing, https://www.worldscientific.com/worldscibooks/10.1142/12670#t=aboutBook

We discuss the history of finding quasicrystals, those arrays of atoms that are like crystals--but aren't quite crystals. These are rarely talked about in undergraduate classes. We start with a purely mathematical question by David Hilbert, and move forward through the 1960s and 1970s, till actual quasicrystals were discovered in the 1980s. Then we reach the point where natural quasicrystals were found. Then we hear about some of their potential uses.Support the show Support my podcast at https://www.patreon.com/thehistoryofchemistry Tell me how your life relates to chemistry! E-mail me at steve@historyofchem.com Get my book, O Mg! How Chemistry Came to Be, from World Scientific Publishing, https://www.worldscientific.com/worldscibooks/10.1142/12670#t=aboutBook

We finally return to polymers, but in a more ecological way. We learn about using wood waste to make plastics. We hear of how to make plastic naturally degrade in the environment, whether with bacteria, sunlight, zapping it with ions, or heating up without oxygen. We also learn of new methods to mine plastics for hydrogen as fuel.Support the show Support my podcast at https://www.patreon.com/thehistoryofchemistry Tell me how your life relates to chemistry! E-mail me at steve@historyofchem.com Get my book, O Mg! How Chemistry Came to Be, from World Scientific Publishing, https://www.worldscientific.com/worldscibooks/10.1142/12670#t=aboutBook

We give a "solid foundation" to chemistry by recounting the history of concrete, starting with the earliest architectural use of lime around 10,000 years ago. We continue through ancient history and modern times with Roman concrete, the loss of its recipe, and (partial) rediscovery in the Renaissance. We continue to the present and the likely complete rediscovery of Roman concrete in the 21st century. We talk of the chemical reactions to make and set concrete, and its ecological problems. Finally we learn a bit about some efforts to make concrete a little more "green."Support the show Support my podcast at https://www.patreon.com/thehistoryofchemistry Tell me how your life relates to chemistry! E-mail me at steve@historyofchem.com Get my book, O Mg! How Chemistry Came to Be, from World Scientific Publishing, https://www.worldscientific.com/worldscibooks/10.1142/12670#t=aboutBook

This episode relates the history of the new field of "skeletal editing" of molecules. While there have been a few known reactions of this type since the very late 1800s, the general system was unknown till the 21st century, beginning with Marcos Suero. We add to the mix Mark Levin and Guangbin Dong, talk of what precisely this type of chemistry does, and relate the wish-list of chemists of all the wonderful things that scientists would like in skeletal editing.Support the show Support my podcast at https://www.patreon.com/thehistoryofchemistry Tell me how your life relates to chemistry! E-mail me at steve@historyofchem.com Get my book, O Mg! How Chemistry Came to Be, from World Scientific Publishing, https://www.worldscientific.com/worldscibooks/10.1142/12670#t=aboutBook

We reach the Big 1-5-0, in which I discuss the venerable history of mRNA vaccines, from the 1960s to the present, from a chemical point of view. We hear of transferring mRNA into cells, then transferring anti-viral mRNA into cells. There are a variety of mRNA vaccines under study--not merely COVID, but flu, RSV, and even cancer treatments. Patreon supporters may download a supplemental sheet with diagrams of some of the biochemical systems I describe.Support the show Support my podcast at https://www.patreon.com/thehistoryofchemistry Tell me how your life relates to chemistry! E-mail me at steve@historyofchem.com Get my book, O Mg! How Chemistry Came to Be, from World Scientific Publishing, https://www.worldscientific.com/worldscibooks/10.1142/12670#t=aboutBook

In this episode we touch on how chemistry has directly influenced religion. Our example is how knowledge of chemistry affected a rabbi's decision to allow a certain brand of carbonated beverage to claim that it is kosher, that is, fit to be ingested by Jews who follow traditional Jewish laws and customs regarding food.Support the show Support my podcast at https://www.patreon.com/thehistoryofchemistry Tell me how your life relates to chemistry! E-mail me at steve@historyofchem.com Get my book, O Mg! How Chemistry Came to Be, from World Scientific Publishing, https://www.worldscientific.com/worldscibooks/10.1142/12670#t=aboutBook

What if we could make flexible electronics for clothing or medical sensors? We examine the history of this quest from the 1990s onward, focusing on liquid-metal electronics. We explore what that means, the pros and cons, and how it might work. Then we talk about creating electronic components using wood (really!), which began in the 2010s, ranging from wooden batteries to wooden transistors.Support the show Support my podcast at https://www.patreon.com/thehistoryofchemistry Tell me how your life relates to chemistry! E-mail me at steve@historyofchem.com Get my book, O Mg! How Chemistry Came to Be, from World Scientific Publishing, https://www.worldscientific.com/worldscibooks/10.1142/12670#t=aboutBook

The history of chemistry in water microdroplets is discussed. We start with the observation by R. Graham Cooks that certain chemical reactions went faster inside ultra-small droplets of liquid relative to beaker-sized amounts. We examine the years-long arguments between Dick Zare and Himanshu Mishra over peroxide formation in microdroplets. We talk a bit about some reasons why reactions may go differently in tiny drops versus bulk amounts, and counter-arguments.Support the show Support my podcast at https://www.patreon.com/thehistoryofchemistry Tell me how your life relates to chemistry! E-mail me at steve@historyofchem.com Get my book, O Mg! How Chemistry Came to Be, from World Scientific Publishing, https://www.worldscientific.com/worldscibooks/10.1142/12670#t=aboutBook

In this episode we examine the history of non-lithium batteries. We talk of changing the anode material and cathode material, whether separately or together. This involves changing the graphite anode to silicon, changing to sulfur anodes, air-based cathodes, different solvent molecules to assist transport of lithium ions, and even calcium batteries. Finally we discuss the flow battery, invented way back in the 19th century, but being revived for batteries that can be stationary.Support the show Support my podcast at https://www.patreon.com/thehistoryofchemistry Tell me how your life relates to chemistry! E-mail me at steve@historyofchem.com Get my book, O Mg! How Chemistry Came to Be, from World Scientific Publishing, https://www.worldscientific.com/worldscibooks/10.1142/12670#t=aboutBook

In which we learn about the beginnings of chemistry applied to art conservation, from the initial attempts by Edward Forbes, but especially when he hired Rutherford John Gettens. We discuss Harvard University's Pigment Collection, plus various analytical tools chemists use to examine art, both light-based and non-light-based. We talk of several institutions with strong chemical applications for art conservation. Finally we examine the problems of modern products--polymers--that need to be preserved, from toys to photographic film.Support the show Support my podcast at https://www.patreon.com/thehistoryofchemistry Tell me how your life relates to chemistry! E-mail me at steve@historyofchem.com Get my book, O Mg! How Chemistry Came to Be, from World Scientific Publishing, https://www.worldscientific.com/worldscibooks/10.1142/12670#t=aboutBook

Dear Listener,I have been posting episodes weekly for two and a half years. I need a short break. I promise I will be back very soon. I have many more episodes already written and recorded for you. Please stay tuned. Until then….brave the elements!Support the show Support my podcast at https://www.patreon.com/thehistoryofchemistry Tell me how your life relates to chemistry! E-mail me at steve@historyofchem.com Get my book, O Mg! How Chemistry Came to Be, from World Scientific Publishing, https://www.worldscientific.com/worldscibooks/10.1142/12670#t=aboutBook

Here we explore the history of unusual and uncommon isotopes of known elements on the periodic table. We discuss the (almost) true statement that all isotopes of an element react the same. Then we reach inside the atomic nucleus and hear of theories to describe nuclear structure and--hence--stability of various isotopes, beginning with Dmitri Ivanenko's work. We learn of the best model, shell structure, and its failings that appeared in the 1980s. Then we talk about half-lives, and how short can a half-life be and still be an atom? How short can a half-live be and still be at least a nucleus? We learn of proton-rich isotopes. Then we hear of the practical value of such research.Support the show Support my podcast at https://www.patreon.com/thehistoryofchemistry Tell me how your life relates to chemistry! E-mail me at steve@historyofchem.com Get my book, O Mg! How Chemistry Came to Be, from World Scientific Publishing, https://www.worldscientific.com/worldscibooks/10.1142/12670#t=aboutBook

In which I give a brief history of queer chemists. We talk of the rise of queer scientific associations, and the slog to acceptance of the Gay and Transgender Chemists and their Allies in the American Chemical Society, some current queer chemists around the world, and something of the challenge of queer chemists in the Britain.Support the show Support my podcast at https://www.patreon.com/thehistoryofchemistry Tell me how your life relates to chemistry! E-mail me at steve@historyofchem.com Get my book, O Mg! How Chemistry Came to Be, from World Scientific Publishing, https://www.worldscientific.com/worldscibooks/10.1142/12670#t=aboutBook

Science-fiction writers (and scientists) have been promoting molecular transistors since the 1950s, and we explore the history of why that hasn't happened yet. We start with the parallel sci-fi writer (and biochemist) Isaac Asimov's "molecular valves" and physicist Arthur von Hippel's "molecular engineering." We talk of military projects that failed, and theoretical ideas that take a lot of engineering to make them work.Support the show Support my podcast at https://www.patreon.com/thehistoryofchemistry Tell me how your life relates to chemistry! E-mail me at steve@historyofchem.com Get my book, O Mg! How Chemistry Came to Be, from World Scientific Publishing, https://www.worldscientific.com/worldscibooks/10.1142/12670#t=aboutBook

In this episode, I have a conversation with Professor David Perlmutter in the Communications Department at Texas Tech University, on the public's impressions of chemistry, and what value chemistry brings to the wider world.Support the show Support my podcast at https://www.patreon.com/thehistoryofchemistry Tell me how your life relates to chemistry! E-mail me at steve@historyofchem.com Get my book, O Mg! How Chemistry Came to Be, from World Scientific Publishing, https://www.worldscientific.com/worldscibooks/10.1142/12670#t=aboutBook

We start with the first chemical conspiracy theory from 1996, "chemtrails." Then we move to another popular chemical hoax, "alkaline water" somehow being healthy for you. Related to that are the bizarre "hexagonal water" and water memory ideas. Other creative pseudochemical hoaxes are denial of global warming and the gasoline pill, creating fuel from non-fuel with merely a pill in your liquid. There is the fun cryogenically-cooled audio cable hoax (if you are into high-fidelity audio). There was the truly harmful radioactive bed scandal in Korea. Finally I offer some clues to detecting such hoaxes and scams.Support the show Support my podcast at https://www.patreon.com/thehistoryofchemistry Tell me how your life relates to chemistry! E-mail me at steve@historyofchem.com Get my book, O Mg! How Chemistry Came to Be, from World Scientific Publishing, https://www.worldscientific.com/worldscibooks/10.1142/12670#t=aboutBook

A new material, the MXene, discovered in 2010, is the topic of this episode. We hear of its creation and derivation at Drexel University in Philadelphia. Then we learn of ways to create single layers, variations in materials, and new methods of synthesis of MXenes. Finally, we discuss the practical uses of MXenes.Support the show Support my podcast at https://www.patreon.com/thehistoryofchemistry Tell me how your life relates to chemistry! E-mail me at steve@historyofchem.com Get my book, O Mg! How Chemistry Came to Be, from World Scientific Publishing, https://www.worldscientific.com/worldscibooks/10.1142/12670#t=aboutBook

We finally get to discuss what the term "aromatic compound" means in chemistry, from Michael Faraday's report in 1825 of a new organic compound (we call it benzene), to von Hofmann's first use in 1856 (without defining it) of the term "aromatic". We examine the ensuing controversies and definitions of "aromatic compound," how people modeled molecularly and diagrammatically what that meant, and current discussions over the word. My Patreon supporters may download a supplemental sheet with molecular structures of some aromatic compounds I mention in the episode.Support the show Support my podcast at https://www.patreon.com/thehistoryofchemistry Tell me how your life relates to chemistry! E-mail me at steve@historyofchem.com Get my book, O Mg! How Chemistry Came to Be, from World Scientific Publishing, https://www.worldscientific.com/worldscibooks/10.1142/12670#t=aboutBook

Aerogels, those feather-weight materials, have a century-old history. We begin with Samuel Kistler, the inventor of the first aerogels, and move forward through time with loss of interest in them, then revival of interest in the 1970s. We learn about gradual improvements in their fabrication over time. Then we talk of their fascinating properties, and then their uses.Support the show Support my podcast at https://www.patreon.com/thehistoryofchemistry Tell me how your life relates to chemistry! E-mail me at steve@historyofchem.com Get my book, O Mg! How Chemistry Came to Be, from World Scientific Publishing, https://www.worldscientific.com/worldscibooks/10.1142/12670#t=aboutBook

Artificial intelligence, or AI, can be applied to chemistry, too. Here we discuss a brief history of AI, especially for chemistry, beginning with Djerassi's DENDRAL program. We talk of the current problems in chemistry to which AI is being applied over the last couple of decades. We also examine what is not doable (yet) in chemistry with AI.Support the Show. Support my podcast at https://www.patreon.com/thehistoryofchemistry Tell me how your life relates to chemistry! E-mail me at steve@historyofchem.com Get my book, O Mg! How Chemistry Came to Be, from World Scientific Publishing, https://www.worldscientific.com/worldscibooks/10.1142/12670#t=aboutBook

In which we consider what, really, is a chemical bond. Lewis and Langmuir promoted the idea that bonding was sharing of electron pairs. Then we hear about Slater, Hellman, and Ruedenberg's discussion of how covalent bonding works. Kossel and Lewis also introduced ionic bonding. Finally Drude and Lorentz offered metallic bonding. But there are more chemical bonds: the hydrogen bond, the halogen bond, the mechanical bond, the van der Waals force, multi-center bonds, and metallophilic bonds.Support the Show. Support my podcast at https://www.patreon.com/thehistoryofchemistry Tell me how your life relates to chemistry! E-mail me at steve@historyofchem.com Get my book, O Mg! How Chemistry Came to Be, from World Scientific Publishing, https://www.worldscientific.com/worldscibooks/10.1142/12670#t=aboutBook

In which we talk about the fastest spectroscopy yet, attosecond spectroscopy, which can resolve electrons moving around atoms. The topic begins with Christian Spielmann in 1997, working to get shorter and shorter laser pulses, and continues with Ferenc Krausz. We discuss what you might be able to inspect using these short light pulses, such as how the shape of atomic orbitals oscillates after ionization, how you can change the opacity of a substance for a brief moment, and fluctuations of water structure.Support the Show. Support my podcast at https://www.patreon.com/thehistoryofchemistry Tell me how your life relates to chemistry! E-mail me at steve@historyofchem.com Get my book, O Mg! How Chemistry Came to Be, from World Scientific Publishing, https://www.worldscientific.com/worldscibooks/10.1142/12670#t=aboutBook

Instead of molecules that absorb light based on their molecular orbitals, this episode talks of nanostructures and their materials that refract light based on interference of light waves. We start with Robert Hooke who described this process in his book Micrographia. We continue through Isaac Newton and Lord Rayleigh. We discuss Eli Yablonovitch's photonic crystals. We mention various kinds of natural structural colorants in the living and non-living worlds, from minerals to insects to bacteria to plants. Then we list several attempts to synthesize structural colorants, and why they might prove useful.Support the Show. Support my podcast at https://www.patreon.com/thehistoryofchemistry Tell me how your life relates to chemistry! E-mail me at steve@historyofchem.com Get my book, O Mg! How Chemistry Came to Be, from World Scientific Publishing, https://www.worldscientific.com/worldscibooks/10.1142/12670#t=aboutBook

This episode concerns the phenomenon in organic chemistry of classifying a set of similar reactions by a single umbrella name. Most named reactions honor a person, but not always. We discuss the early history of named reactions from the 1870s onward. We then talk about the slant of named reactions towards white men, and away from other people, and even whether that can be a problem for minority and women chemists. Patreon supporters may download a supplemental sheet that sketches some of the reactions I mention in the episode.Support the Show. Support my podcast at https://www.patreon.com/thehistoryofchemistry Tell me how your life relates to chemistry! E-mail me at steve@historyofchem.com Get my book, O Mg! How Chemistry Came to Be, from World Scientific Publishing, https://www.worldscientific.com/worldscibooks/10.1142/12670#t=aboutBook

Polyfluoroalkyl substances, or PFAS, seem to be ubiquitous now in the environment and the news. In this episode I delve into why chemists found these compounds so fascinating and useful. Then I discuss some history of how the world finally learned how dangerous these compounds can be if used and disposed of improperly. Finally I talk of some possible methods chemists are currently researching on how to remove PFAS from the environment.Support the Show. Support my podcast at https://www.patreon.com/thehistoryofchemistry Tell me how your life relates to chemistry! E-mail me at steve@historyofchem.com Get my book, O Mg! How Chemistry Came to Be, from World Scientific Publishing, https://www.worldscientific.com/worldscibooks/10.1142/12670#t=aboutBook

Mechanochemistry, using purely mechanical processes to run a reaction, is much less known in the chemical world, but has been around since the ancient Greek Theophrastus described a mechanochemical process. We describe the history of mechanochemistry from then through its rediscovery by Michael Faraday, and the first systematic attempts to understand it by Mathew Carey Lea. He got into a dispute with Walthère Spring over "first rights" to publication. The 20th century was when mechanochemistry was examined in great detail, both in the Soviet Bloc and then by Westerners in the later part of the century. We talk of various topics in mechanochemistry.Support the Show. Support my podcast at https://www.patreon.com/thehistoryofchemistry Tell me how your life relates to chemistry! E-mail me at steve@historyofchem.com Get my book, O Mg! How Chemistry Came to Be, from World Scientific Publishing, https://www.worldscientific.com/worldscibooks/10.1142/12670#t=aboutBook

In which we learn of the history of graphite, its molecular structure, and electrical properties. Then we discuss the isolation of thinner and thinner layers of graphite through the mid-to-late 20th century. The first isolation of a single atomic layer of graphite, called graphene, was accomplished in 2004 by Andre Geim and Konstantin Novoselov, which set off a new flurry of chemical research, much like the discovery of buckminsterfullerene two decades earlier. Then we discuss the special properties of graphene, and what practical applications graphene has.Support the Show. Support my podcast at https://www.patreon.com/thehistoryofchemistry Tell me how your life relates to chemistry! E-mail me at steve@historyofchem.com Get my book, O Mg! How Chemistry Came to Be, from World Scientific Publishing, https://www.worldscientific.com/worldscibooks/10.1142/12670#t=aboutBook

With this episode, we complete our history of the discovery of the elements (up through writing this episode). We talk of elements 110 through 118, completing that row of the Periodic Table, and the various experiments that the major heavy-ion research facilities in Russia, Germany, the USA, and Japan, were doing. We begin to hear of collaboration between several groups as the difficulties of obtaining raw materials grow. The Joint Working Party, the final Decider for discovery, constantly intrudes to say "no, that's not good enough," till eventually it is.Support the Show. Support my podcast at https://www.patreon.com/thehistoryofchemistry Tell me how your life relates to chemistry! E-mail me at steve@historyofchem.com Get my book, O Mg! How Chemistry Came to Be, from World Scientific Publishing, https://www.worldscientific.com/worldscibooks/10.1142/12670#t=aboutBook

In which we discuss the entry of People of Color into chemistry, mostly in the USA. We start with the first Black to get an Ph.D. in Chemistry in the USA, St. Elmo Brady, and work forward through the 1940s through the 1960s. We discuss various organizations to assist people of color in chemistry (and other sciences), such as NOBCChE, SACNAS, AISES, and the Society for Asian Scientists and Engineers. We examine a similar problem in the United Kingdom which has no independent assistance organization for People of Colour.Support the Show. Support my podcast at https://www.patreon.com/thehistoryofchemistry Tell me how your life relates to chemistry! E-mail me at steve@historyofchem.com Get my book, O Mg! How Chemistry Came to Be, from World Scientific Publishing, https://www.worldscientific.com/worldscibooks/10.1142/12670#t=aboutBook

In which we talk of a huge problem currently plaguing chemistry (and science in general), the "paper mill," in which researchers pay to get their name attached to others' publications, or they write fraudulent publications and pay to get them in print. We hear of a Chinese firm discovered to be such a broker, possible reasons why chemists would fake research, and specific examples of chemical fraud. One insidious problem is faked crystallographic data on molecular structures, uploaded to repositories. Finally we learn of some ways to identify paper mills.Support the Show. Support my podcast at https://www.patreon.com/thehistoryofchemistry Tell me how your life relates to chemistry! E-mail me at steve@historyofchem.com Get my book, O Mg! How Chemistry Came to Be, from World Scientific Publishing, https://www.worldscientific.com/worldscibooks/10.1142/12670#t=aboutBook

Here we discuss all sorts of kits chemists use to build models of different molecules. We start with the pre-molecule set built for John Dalton, and then we hear of August von Hofmann's set for lecture demonstrations. We talk of John Dewar's brass constructions, and then to Tinkertoy-like setups in the 20th century. Plastic first appears in molecular-model kits by the 1950s, and we continue through the later 20th-century. If you become a Patreon subscriber, you may download a supplemental sheet which shows some 20th-century kits, including a lecture demonstration kit I don't discuss in this episode!Support the Show. Support my podcast at https://www.patreon.com/thehistoryofchemistry Tell me how your life relates to chemistry! E-mail me at steve@historyofchem.com Get my book, O Mg! How Chemistry Came to Be, from World Scientific Publishing, https://www.worldscientific.com/worldscibooks/10.1142/12670#t=aboutBook

Our history of LEDs continues with the entry of LEDs into commercial lighting. We talk of different ways to get white light out of LEDs, and materials for white-light LEDs. We briefly discuss color temperature because there are different kinds of white. Then we hear of the publication of an article in 2000 that consolidated thinking about home usage for LEDs, and why LEDs have advantages over other lamps. We mention ways geometrically to optimize LED construction to maximize the amount of light emitted. Finally, we note the development of second-generation emitting compounds in red, green, and blue that pushed LEDs over the finish line to make them practical for home usage.Support the Show. Support my podcast at https://www.patreon.com/thehistoryofchemistry Tell me how your life relates to chemistry! E-mail me at steve@historyofchem.com Get my book, O Mg! How Chemistry Came to Be, from World Scientific Publishing, https://www.worldscientific.com/worldscibooks/10.1142/12670#t=aboutBook

This episode gives a basic review of geochemistry, starting with pioneers such as Christian Friedrich Schönbein, Frank Wigglesworth Clarke, and thence into the 20th century, especially Victor Goldschmidt. We hear about the development of geochemical societies around the world, then we talk about various subfields of geochemistry. The question of "what's inside the Earth" is still a very active one, and we discuss ways to simulate the pressure inside the Earth, and likely constituents of the Earth's core.Support the Show. Support my podcast at https://www.patreon.com/thehistoryofchemistry Tell me how your life relates to chemistry! E-mail me at steve@historyofchem.com Get my book, O Mg! How Chemistry Came to Be, from World Scientific Publishing, https://www.worldscientific.com/worldscibooks/10.1142/12670#t=aboutBook

Even though the potential for using microwaves to do chemistry was there since 1946, it wasn't until the late 1970s that the first use of microwaves in the chemistry laboratory appeared. This episode covers the development of microwave chemistry from moisture analyzers to significant study of reactions, and then finally laboratory-standard microwave ovens appeared. We mention the controversy between Gregory Dudley and Oliver Kappe as to whether there were some special properties of microwaves that made reactions speed up. We talk of the reasons that chemists now preferentially zap their reactants with microwaves over traditional chemical methods.Support the Show. Support my podcast at https://www.patreon.com/thehistoryofchemistry Tell me how your life relates to chemistry! E-mail me at steve@historyofchem.com Get my book, O Mg! How Chemistry Came to Be, from World Scientific Publishing, https://www.worldscientific.com/worldscibooks/10.1142/12670#t=aboutBook