Podcasts about ppy

Het woord van de afgelopen PPY! Er is een bijzondere move gaande in de kerk en onder de jongeren. De Heilige Geest beweegt op een bijzondere manier en Holy Spirit Breakthrough life is de focus!

Jij kan invloedrijk zijn door uit te stappen in gebed! God heeft geen junior heilige geest gestuurd voor mensen die onder de 18 zijn, geen medium Heilige Geest voor 18 tot 25 jarigen. Hij heeft 1 Geest gestuurd voor volwassenen, kinderen en iedereen die zich opent voor de Heilige Geest. De Volheid van God is voor jou; voor bidders. Bas neemt ons deze PPY mee in de 4G's van gebed. Ook een keer een PPY bijwonen? Join ons 18 februari om 20:00 uur in de Dome

“Ren je eigen race” Bas sprak erover op de PPY in oktober en aan tafel gaan ze door. Maakt sociale media het vandaag de dag toch moeilijker om je eigen race te rennen in een wereld die als een global village naar je toe komt? Hoe zie je, ‘ren je eigen race' in je eigen leven, welke uitdagingen komen erbij kijken en hoe ga je daarmee om? Get to know cool chick, Solange, 18 jaar en schuift aan. Jij bent uniek gemaakt en God heeft iets unieks voor jou! Ren je race met Hem. Enjoy! Timeline: 0:15 Maak kennis met Solange 3:20 Ren je eigen race 5:35 Hoe Mitchell zijn eigen race rent in zijn leven adhv een voorbeeld 9:11 is je eigen race rennen complexer in deze tijd met social media? 13:34 de sleutel selflove 14:30 getuigenis Solange over selflove en depressie 16:35 Hoe kun je omgaan met de druk van social media 19:40 je hebt drie spiegels. De spiegel van het woord, je badkamer en social media 22:00 Mitchell - Als je te veel op je omgeving gefocust bent 23:33 Jezelf vergelijken is iets natuurlijks 24:26 Het is geen wedstrijd 24:41 Gods woord praat maar de maatschappij ook 26:40 God stuurt mensen op je pad maar de duivel stuurt ook mensen op je pad. 33:07 “This is me” en een drip tip van Solange 35: 52 Sleutels 36:39 “ren je eigen race” gekoppeld aan “de eindsprint” 38:45 er zijn altijd hordes in het rennen van je eigen race 39:50 Blijf niet te lang bij het verleden.

We zijn van start met een nieuw seizoen! ‘Als jij de Bijbel opent, opent God hem voor jou.' De Bijbel kan een overwhelming boek zijn. Waar begin je, hoe steekt het boek in elkaar etc. En deze PPY geeft apostel ons een Bijbel overview - een roadmap om je Bijbel te lezen en beter te begrijpen. Hij legt het op zo een manier uit dat de Bijbel in hapklare stukjes naar je toekomt, je het in een ander daglicht gaat zien en het grijpbaar voor je wordt. Waardevolle uitleg die ons helpt om een baas van onze Bijbel te worden! In onze Bijbelbazen Highlight op Instagram vind je een visueel overzicht van deze uitleg. Hier kun je naar teruggrijpen als je je Bijbel leest; In welk boek ben ik, wat zegt het boek, waar valt het onder. Ga er actief mee aan de slag en wordt een #bijbelbaas

My next guest has some fantastic advice about finding yourself through dance. Please welcome the host of ‘Dance Bants' on KFTW: Jess Goodfellow!Jess Goodfellow started her training at Newtown High School of the Performing Arts.In 2015, she joined Sydney Dance Company's Pre Professional year and in 2016, she joined IT DANSA youth company in Barcelona, where she performed the repertory of Ohad Naharin, Alexander Ekman, Jyri Kylian, Nacho Duato, Akram Khan, Sidi Larbi and Rafael Bonachela.She has since worked as a freelance artist in Sydney with Sydney Experimental Arts Ensemble, Omer Backley-Astrachan, and Callum Mooney in their own show, Jeppee Peppee at the Flying Nun by Brand X.In 2020, she choreographed  her first work, ‘Human Drama', for Sydney Dance Company's PPY Revealed and she continues to work as an emerging choreographer in 2021 with Sydney Dance Company.In this conversation, we dived into the following:Having to choose between dance and gymnastics.Pre-professional course at Sydney Dance Company.Facing yourself.Dealing with setbacks.Role models in full-time.IT DANSA, and life in the company.Knowing why you dance.Horse technique.“Human Drama”, her piece for PPY.Jess' fantastic podcast: Dance Bants.Logo: @lawrencetandesignsAnimation: @cold_tea_artIntro track: melaniac. - we're just some motherf***ing kids

Today on the show we have Linda Gamblin, Head of training at Sydney Dance Company and the creator of pre professional year aka PPY aka the full time course I did! Linda had a huge career dancing with the Royal Ballet Company, Australian Ballet, Sydney Dance Company and the National Ballet of Portugal! Linda tells her story and we discuss the full-time course she developed that has now grown to have three coordinators and about 60 students! We also talk about Linda's breast cancer journey and the lessons she realised through this. It is an honour to have Linda on, she is one of the most inspiring people who has influenced me and so many people in my journey. Dance Bants is getting VERY pre professional. I also can't believe I could finally talk about full time with a real course director on my show. Catch us on Youtube if you prefer to watch the conversation @thedancebantsshow.

The background for how PPY got started. --- Send in a voice message: https://podcasters.spotify.com/pod/show/melaninempress/message

We horen en leren over gefocust op Jezus zijn op zondag/PPY, maar hoe uit dat zich in onze daily life? We proberen allemaal koers te houden en de beste keuzes te maken voor ons leven. Je gedachten en emoties kunnen soms alle kanten opschieten door bepaalde dingen, omstandigheden, afleidingen, verleidingen die voor de volle 100% je aandacht zouden willen, maar dat als je daaraan toegeeft je je eigen succes voorbij schiet! Waar focus je dan op met zoveel wat er om je heen gebeurt? Focussen is keuzes maken. Elke dag opnieuw. En de ene dag gaat het beter dan de andere, maar vergeet niet dat je een ‘work in progress' bent en dat er altijd ruimte is om weer bij te sturen. Don't punish yourself, or set yourself back, but take it step by step. In deze podcast vertelt o.a. onze nieuwe tafelgast, Ulrich over zijn leerproces, uitdagingen en het verleggen van zijn focus. Luister en leer hoe Christ- focused in the daily life eruit ziet.

De allereerste podcast van PPY! Identiteit, hoe vormt dat zich, hoe uit dat zich in ons dagelijks leven en wat moet je doen om de beste versie van jezelf te worden zoals God het bedoeld heeft? In deze pilot schuiven Bas, Mitchell, Safira en Jaëla aan tafel om hierover te praten. Accepteren waar je nu bent en weten dat je nog onderweg bent. Don't be too hard on yourself. Als je God blijft volgen en daarin de juiste keuzes blijft maken, kom je waar je moet zijn. Luister en laat ons weten wat je ervan vindt!

Taylor Wells and Paulette met in Nantucket during the Nantucket Yoga Festival while Taylor was teaching and Paulette was soaking up the sun and the vibe. Taylor blew Paulette away and the two have been friends and sisters ever since. ✨ Happy SuperMom of 5✨ ✨Graduate of Brown University and Columbia University.✨ ✨Founder of 5 Prana Power Yoga Studios✨ ✨Author✨ ✨Entrepreneur✨ ✨United Nations Yoga Peace Ambassador✨ ✨Founder of Prana Restaurant - the first raw vegan restaurant in Newton Massachusetts✨ ✨Juice PLUS+ Sales Coordinator✨ ✨Law of Attraction Mindfulness based Coach✨ ✨Law of Attraction Mindfulness based Therapist✨ ✨Scout and Cellar Consultant✨ ScoutandCellar.com/TaylorWells TaylorWells.me TaylorWells.JuicePlus.com BostonHerald.com Taylor Wells, M.A., M.Ed., RYT Founder of Prana Power Yoga™, Author & Entrepreneur Taylor speaks, teaches, and inspires at conferences all over the world, including The Nantucket Yoga Festival, The Young Presidents’ Organization, Prana Fest, Women’s Wellness, Longevity Now, The Yoga Chant Fest, and Yoga for Peace. She is an author, entrepreneur, and founder of Prana Power Yoga™ (5 studios in Massachusetts and New York), United Nations Yoga Peace Ambassador, Law of Attraction & Mindfulness Based Therapist, Law of Attraction & Mindfulness Based Coach, Boston Herald Columnist, Boston Herald Blogger, Master Yoga & Spiritual Teacher, Creator and sole writer of Super-mom.com, Wellness, and Healthy Lifestyle Activist with Juice PLUS+. A graduate of Brown University (A.B.) and Columbia University (M.A., M.Ed.), Taylor trained over 100 yoga teachers a year in her renowned Prana Power Yoga™ Teacher Training Program in both Massachusetts and New York and taught 25 times a week at all of her PPY locations for 16 years. She is a happy Super-mom of five, including twin nine-year-old boys, and resides in her happy place, Barrington, Rhode Island. Taylor’s best-selling book—Create The Best Life Ever: Real Life Stories to Get Inspired, Inspiration Card Deck, and DVDs are available at TaylorWells.me, Amazon.com and selected stores. --- This episode is sponsored by · Anchor: The easiest way to make a podcast. https://anchor.fm/app --- Send in a voice message: https://anchor.fm/thriving-in-chaos/message Support this podcast: https://anchor.fm/thriving-in-chaos/support

Today on the show I feel privileged to be speaking with Jonathan Baha’i the President and Michael Maloney the Director of Intelligence for Peerplays. The Peerplays Blockchain Standards Association (PBSA), is a non-profit organization dedicated to the advancement of provably-fair gaming. Peerplays is the world’s first peer-to-peer betting platform built entirely on top of a live blockchain AND according to BTC Media, the Peerplays token known as PPY is “the first ‘dividend playing’ crypto-currency ever designed. The Peerplays network, features native smart contracts powered by Graphene and a built-in digital asset exchange. The asset exchange allows users to choose which cryptocurrency they would like to use to make wagers. The Peerplays API gives users the option to choose what currency values are displayed in, including USD, EUR or a number of crypto-tokens. CREDITS & VALUABLE LINKS: https://www.peerplays.com/ TRANSCRIPTIONS: Great news listeners! Our transcription page is now live on the website thanks to the continuing hard work of one of our loyal listeners who is also a consultant to the show. These Professional transcriptions are provided each week by one of our fans who can be found at: http://diaryofafreelancetranscriptionist.com Ode To Satoshi Ode to Satoshi lyrics & melody by John Barrett Copyright 2014 RJM Publishing - BMI Nashville. Lead Vocal, Harmony Vocals, Harmonica, Snare Drum: John Barrett Harmony vocals: John Barrett, Connie Sinclair and Lij Shaw Guitar: Jonathan Brown Mandolin: Ben Miller Bass Guitar: Michael Rinne Initial tracks recorded by Mark Thornton of Sidekick Sound Studios, Madison, TN. All other tracks Recorded, Mixed and Mastered at The Toy Box Studio, Nashville, Tennessee Engineer: Lij Shaw. Assistant to engineer: Don “The Don” Bates Produced by John Barrett & Elijah “Lij” Shaw Special thanks to Alan Baird for his dobro, guitar and mandolin playing on many of the shows. Now that’s some pickin man! Thanks also to Alex Munoz Guijarro for his excellent pedal steel playing on many of our shows. Interviews for this episode were recorded and edited by John Barrett at The Tree House Studio - Nashville, Tennessee. All shows are produced by John Barrett with the moral support of his trusty sidekick Maxwell Rascalnikov CoyoTe Rex, aka Max. Questions or Comments? Email me to say Howdy!: howdy@bitcoinsandgravy.com Visit theWebsite: BitcoinsAndGravy.com Bitcoins and Gravy Tipping Addresses: Bitcoin: 14RbXduu2sXKNHtKtRVAx8xQyGAubjY1dA Litecoin: LgqYgxLTBPgr8C1JGLLJVLK4ZN1fveprAp And if you don’t feel like contacting me, just kick back, relax and enjoy the show. I hope you enjoy listening to my guests as much as I enjoy talking with them!

#106: With enough passive income to meet your living expenses, you can potentially quit your job. GRE’s Business Developer John Collins just quit his job. He tells us how it feels. Keith brings you the show from Ontario, Canada today. Want more wealth? Visit GetRichEducation.com and 1) Subscribe to our free newsletter, and 2) Find turnkey real estate investing opportunities. Listen to this week’s show and learn: 02:38  How close are you to quitting your job? The PPY. 05:42  A metaphor about life being the journey, not the destination. 07:40  If the Dow Jones rises from 19,000 to 20,000 points, that’s NOT a gain! 10:41  With zero financial education, stocks are better than real estate. With some education, real estate is better. 12:08  Monthly property management statements. 15:50  The jet pilot. 19:12  GRE’s John Collins quit his job that paid $100K-$200K per year. 22:47  Overcoming fear of leaving the job. 24:32  Nothing dispels fear like education; social connections. 28:48  Altering your life structure. 32:35  Do you still know when it’s “Payday” at your employer? 36:40  Feel of the “corporate-ocracy.” 39:09  With more passive income, here’s how you’ll begin thinking differently than your co-workers. 41:15  Entrepreneurship is not for everybody. “Turnkey job.”   Resources Mentioned: Book: “Pivot” by Jenny Blake CorporateDirect.com NoradaRealEstate.com RidgeLendingGroup.com GetRichEducation.com

#100: How to measure your wealth, a fun retrospective of the first 100 episodes, and a visit from GRE’s Business Developer John Collins. Want more wealth? Visit www.GetRichEducation.com and 1) Subscribe to our free newsletter, and 2) Receive Turnkey RE webinar opportunities. Listen to this week’s show and learn: 03:25  Let’s measure your wealth. Right now. Here’s how. 06:12  Favorite GRE mantras and catchphrases. 09:16  How to increase your wealth. Determine your “PPY” and convert equity to cash flow. 13:02  Traffic and commuting. Appreciate what you’ve already got while you expand. 17:58  A memorable look back at some noteworthy GRE episodes. 28:31  GRE’s John Collins appears. 33:07  Real estate’s advantages and five profit centers. 34:16  Awareness of outdated investment paradigms.   35:05  Nearly every dollar you spend is related to real estate. 37:40  If you wait until you’re old to be gratified, did you win? 38:50  Sabbaticals. 43:30  Exposure to fresh ideas multiplies you in “unthought of” ways.   Resources Mentioned: CorporateDirect.com RidgeLendingGroup.com NoradaRealEstate.com GetRichEducation.com

Early FAFSA and Prior-Prior Year (PPY) is officially here and challenges and opportunities for this recruitment cycle abound. In this episode of Admissions Live, we will demystify what PPY means for students, parents, and recruiters. Louis Hirsh, chair of NACAC's Admissions Practices Committee and member of NACAC's Steering Committee on Admissions Practices, will talk strategies, counseling, and NACAC compliance for upcoming travel season and beyond.

Early FAFSA and Prior-Prior Year (PPY) is officially here and challenges and opportunities for this recruitment cycle abound. In this episode of Admissions Live, we will demystify what PPY means for students, parents, and recruiters. Louis Hirsh, chair of NACAC’s Admissions Practices Committee and member of NACAC’s Steering Committee on Admissions Practices, will talk strategies, counseling, and NACAC compliance for upcoming travel season and beyond.

Bacteria constantly need to monitor their environment and adapt the bacterial group-coordinated behaviour to changing habitats like nutrition alterations or host variations. Commonly cell-cell communication via acyl homoserine lactones (AHLs)is used to synchronise the behaviour of a bacterial population dependent on cell size. This process is referred to as quorum sensing (QS) and predominantly occurs in Gram-negative bacteria. The typical QS system consists of a LuxI-synthase that synthesises AHLs, and a LuxR-type receptor, which then responds to these AHLs. Upon AHL-binding, the LuxR-type receptor regulates the expression of different target genes and thus influences several processes, like biofilm formation, virulence, antibiotic production or cell-cell interaction. Interestingly, many proteobacteria possess additional LuxR homologs, but lack a cognate LuxI-type synthase. Those LuxR-type receptors are referred to as LuxR orphans or LuxR solos and can expand the regulatory QS network. Photorhabdus species are insect pathogenic bacteria, living in symbiosis with entomopathogenic nematodes. They all possess an exceptionally high number of LuxR solos, but lack LuxI homologs and therefore do not produce AHLs. The function of these LuxR solos, their role in cell-cell communication and the identification of their cognate signalling molecules in Photorhabdus species is the main focus of this work. In this thesis a novel signalling molecule used for QS could be identified for the first time in P. luminescens. This novel QS molecule is an α-pyrone named photopyrone (PPY) and produced endogenously by the photopyrone synthase (PpyS). The PPYs are specifically recognized by the LuxR solo regulator PluR, which then activates expression of the pcf (Photorhabdus clumping factor) operon leading to cell clumping of P. luminescens cells. Moreover, the PpyS/PluR quorum sensing system and its induced cell clumping contribute to the overall toxicity of P. luminescens. Furthermore, a second novel signalling molecule sensed by a LuxR solo of Photorhabdus species could be identified besides PPYs. The insect and human pathogenic bacteria P. asymbiotica lacks a PpyS homolog as well as a LuxI homolog, but harbours a pcf operon and a homologue to PluR, which is named PauR. The signalling molecule sensed by the LuxR-type receptor PauR could be identified, which is neither an AHL nor a PPY. PauR recognises a 2,5-dialkylresorcinol (DAR) produced by the DarABC pathway. Upon binding of the cognate signalling molecule, Summary XII PauR activates expression of the pcf operon. This also leads to cell clumping in P. asymbiotica. Furthermore, the DarABC/PauR QS system also contributes to the overall pathogenicity of P. asymbiotica against Galleria mellonella insect larvae. A bioinformatics approach revealed a high number of LuxR solos present in P. temperata and P. asymbiotica like in P. luminescens. Thereby, several conserved motives of amino acids could be identified, which are potentially important for signalbinding and -specificity. Variations in these amino acid motifs are assumed to reflect the overall variety of signals that can be sensed by LuxR solos. Furthermore, the specificity of the two LuxR solos PluR and PauR towards their cognate signalling molecules, PPYs and DARs, respectively, was analysed. Thereby, it could be shown that the previously identified conserved amino acid motives in the signal-binding domain (SBD), the TYDQCS-motif of PluR and the TYDQYI-motif of PauR, are essential but not sufficient for ligand-binding. Similar as for AHLs, it was unclear how the signalling molecules PPYs and DARs can cross the bacterial cell membrane. In the last part of this thesis the import mechanism for the Photorhabdus-specific signalling compounds PPYs and DARs were identified. Initial evidence could be provided that the membrane-integrated transporter FadL is mainly involved in the import of these hydrophobic compounds, and that they are not transported via simple diffusion across the cell membrane, which is assumed for AHLs. In conclusion, the data that is compiled presents two LuxR solos of Photorhabdus species adapted to sense and respond to novel non-AHL signalling molecules used for QS. Therefore, this thesis reveals that cell-cell communication via LuxR-type receptors goes far beyond AHL-signalling in nature.

One of the important transformations of alcohols to esters is the reaction with acetic anhydride catalysed by 4-(dimethylamino)pyridine (DMAP) in the presence of an auxiliary base like triethyl amine. Although this is a widely used reaction, several questions left unaddressed until now: the reaction mechanism of the latter transformation was not completely conceived. Since Steglich and Litvenencko found DMAP in 1969 independently as nucleophilic catalyst, there was hardly any effort to search for new nucleophilic catalysts of higher catalytic efficiency than DMAP or 4-(pyrrolidinyl)pyridine (PPY). All chiral nucleophilic catalysts are based on these structural motifs and due to their lack of catalytic efficiency, there are hitherto no examples for kinetic resolution experiments of tertiary alcohols described. In this dissertation, the following goals were achieved: With computational methods, the reaction pathway of tert-butanol with acetic anhydride in the presence of DMAP was explored. Based on these results a fast computational tool was developed to screen for more efficient nucleophilic catalysts. The best candidates were synthesised, the catalytic efficiency quantified and the best catalysts applied in the synthesis of esters. The reaction mechanism of the acetylation of tert-alcohols was explored by calculating the nucleophilic and base catalysed reaction pathway of tert-butanol with acetic anhydride in the presence of DMAP at B3LYP/6-311+G(d,p)//B3LYP/6-31G(d) level of theory. In the course of this study, a nucleophilic and base catalysed reaction pathway with DMAP as catalyst was found. The energetically lowest transition state of the base catalysed reaction pathway is 37.9 kJ mol-1 higher in energy then the energetically lowest transition state in the rate-determining step of the nucleophilic reaction path. The combination of kinetic measurements with the calculation of the nucleophilic reaction path reveals that no triethyl amine is involved in the rate-determining step of nucleophilic reaction pathway. This shows clearly that nucleophilic catalysis is the preferred and that the acetate anion is deprotonating the alcohol in the rate-determining step. Furthermore, the results of the recalculation of the nucleophilic reaction path with a different catalyst show that a higher stabilisation of the transient acylpyridinium cation has a pivotal influence on the overall reaction rate of the ester formation. Therefore, relative acetylation enthalpies (ΔH298) were calculated at B3LYP/6-311+G(d,p)//B3LYP/6-31G(d) level of theory by using an isodesmic reaction approach. In this way a large number of new nucleophilic catalysts were screened and numerous promising candidates were synthesised which have a larger negative ΔH298 value then DMAP (-82.1 kJ mol 1). The catalytic effiency of the new nucleophilic catalysts was quantified by a test reaction using 1 equiv. of 1-ethynylcyclohexanol, 2 equiv. of acetic or isobutyric anhydride and 3 equiv. triethyl amine. The conversion of 1-ethynylcyclohexyl acetate or -isobutyrate was monitored by 1H NMR spectroscopy. Pyrido[3,4-b]pyrazine- and pyrido[3,4 b]quinoxaline-derivatives show the best catalytic effiency. Especially (rac) 5,10-diethyl-5,5a,6,7,8,9a,10-octahydropyrido[3,4 b]-quinoxaline (DOPQ) shows equal to better catalytic efficiency then 6,6-tricyloaminopyridine (TCAP), which was hitherto the best nucleophilic catalyst. DOPQ can be synthesised very efficiently in a four step protocol starting from commercially available 3,4-diaminopyridine and cyclohexane-1,2-dione with an overall yield of 45 % while TCAP is only available in a five step synthesis with an overall yield of 8-13 %. The synthesis of DOPQ starts with the Schiff-base formation of 3,4-diaminopyridine and cyclohexane-1,2-dione. Reduction with LiAlH4 yields the cis-configured octahydro[3,4-b]quinoxaline, which can be alkylated without the use of any protecting group in the presence of acetic anhydride in pyridine and subsequent reduction with LiAlH4/AlCl3 to yield DOPQ. The structure of the latter compound was confirmed by X ray single crystal structure. The new catalysts were applied to an enhanced Gooßen esterification to transform sterically hindered acids to their tert-butyl esters. The reaction mechanism was explored by monitoring the substrate, intermediate and product conversions with 1H NMR spectroscopy. With this enhanced reaction protocol, it was possible to transform 1-phenylcyclohexane carboxylic acid into the tert-butyl ester under high concentration conditions at room temperature in the presence of 5 mol% DOPQ within 270 min while with the standard DCC/DMAP protocol only the anhydride of the carboxylic acid is formed. With this very mild method, it was possible to convert a variety of substrates into their tert-butyl- and benzyl esters, which are not accessible with any other method starting from the free carboxylic acid. In the case of chiral substrates no lose of stereochemical information was detected. Combination of high concentration conditions and new catalysts provide attractive reaction times of a few minutes instead of several hours with the Gooßen protocol.