Podcasts about sn1

Fyfie is live in Swindon with tonight's panel talking about the lunchtime KO vs Bradford and all the latest news from SN1.

Hannah joins us as we look ahead to hosting the league leaders, review the Colchester Collapse and recap another boring week at SN1

After a quiet week at SN1, the panel discuss the action coming up this weekend, and describe what FRI EAFC cards might look like.

Inspirational quotes are everywhere. There are some that may change your perception and get you to think differently. On this episode, the season one finale, we caught up with Nic Haralaumbus. Nic is form South Africa and has been starting and growing businesses ever since he was 16. He has written numerous books runs a podcast talking with founders and their failures and even runs a foundation to help others in SA start side hustles. During our conversation Nic shares his wisdom around business and life. He explains his Nicisms and drops some great quotes that may resonate with you. Enjoy.

Reducing friction for students is a big priority for campuses across the globe.  Allowing students to access information easily is a close second. How has technology changed this? On this episode we sat down with Dr. Steven Tolman. Dr. Tolman is teaching the next generation of university administrators. He is also the author of a research paper that highlights the benefit of scheduling automation on campus, specifically YouCanBook.me. We had a great time talking with someone just as passionate as us about the topic. Enjoy.

Nearly every part of human life, technology has impacted. Customer Success is no different. Many CSMs are spending a large amount of their time manually checking accounts and tabulating health metrics so they can make informed decisions and monitor managed accounts. On this episode we are joined by Philipp Wolf the co-founder and CEO of Custify a Customer Success platform. Philipp talks about how his tool can help save CSMs a massive amount of time as Custify streamlines the health metrics and outreach at scale. Philipp shares the habits of a successful CSM and what teams should consider when first starting a Customer Success department or team. Enjoy.

Managing others can be very tough. Be a successful leader is nearly impossible if you are not receptive to your team members. If you aren't listening effectively you cannot help them grow, your team does not win. On this episode we are joined by Aspen Padilla. Aspen is the Academic Coordinator for Chemeketa Community college. During her tenure with Chemeketa she has seen student success evolve and adapt to the changing times. She discusses her leadership philosophy and how her department works hard to break the stigma around seeking help for academics. Enjoy.

What does it take to have a high performing team? How can managers be better at providing feedback to help their team grow? On this episode we sit down with Dr. Sherry Walling. Sherry is an clinical psychologist, author, aerialist and CEO of Zenfounder. She has been around entrepreneurs and business leaders for a long time learning all of the things they deal with and how to help them navigate business and life changes. During our conversation Sherry shares insights into how leaders can mold high performing teams and the importance on having a physical hobby to rewire your brain. She also talks about her new book Touching Two Worlds tackles the difficult topic of grief and how to handle it.  Enjoy.

Victory over Hartlepool has changed the mood around SN1 and fans believe again. Noise at the CG, Team of the season, WSTFC and your questions + Forest Green Preview and Fyfie gets attacked???

How do you scale a business? On this episode Guillaume shares what he and the team at lempire have done in the last three and a half years to accelerate their growth. G talks about how to fire quickly for folks that aren't a good fit and why many business owners and start ups should do what they shouldn't and buck conventional thinking. This is a great episode with some amazing takeaways from all things management to getting started with video. Enjoy.

Spot a problem and fix it. This is the advice you hear from everyone who has ever started a company. Our guests Andrea Wildt and Samantha Anderl did exactly that. After starting a consulting business and working as freelancers they ran into a ton of obstacles. They decided to build a solution and Harlow was born. Harlow is an all one app designed to help freelancers streamline their workflows and simplify their life. Sam and Andrea talk about how the launch has gone, how they are building their company, and how they manage everything. Enjoy

YouCanBook.me would be nothing without our amazing customers. Everything we do is to serve them better. On this episode we sat down with Ted Daniels, one of the first YouCanBook.me customers. Ted shares his early experience with the platform and how CTO Keith Harris built a custom solution for him. As the technology specialist for College of Western Idaho Ted shares how he sources tools for his campuses and makes sure the choices they make are long term and not quick fixes.  Enjoy.

How much can your company stand to make by emerging into new markets? On this episode we sat down with Levent Yildizgoren to talk about how to make this happen. For over 30 years Levent and his team have helped businesses all over the world with localization to bring products to new points on the globe. Levent shares the common mistakes that companies make when it comes to localization and how to avoid them. He also shares more on his LINGO method for having a successful localization campaign. Enjoy.

Starting over can be difficult. Stepping away from something you have built from the start is never easy. On this episode Rand Fishkin the former CEO and founder of Moz talks about how he is doing things differently with his new venture, SparkToro an audience research platform. He shares how his team of three is able to do everything that has to get done and the processes they have in place to allow them the autonomy and freedom to work when and how they need to. The easiest process is something you can start today. We talk about Rand's book Lost and Founder and what makes a great leader. Enjoy.

This episode will get you pumped up! Deana talks about how to unlock success by having a strong support tribe, leaning into your gifts and having great people take care of the rest. She walks us through her Ready Fire Aim framework she uses with her clients to really kick life in the teeth. Essentially identifying your gifts, goals and gaps. Enjoy.

Behind every great company is a team of people scouring the globe for the best talent. These unsung heroes are helping build empires one new hire at a time. On this episode we sat down with Kevin Howard, the lead technical recruiter with TeleSign. Kevin shares what he has learned through his decade of recruiting. We also discuss the importance of a great candidate experience. Kevin even shares tips for job seekers on how to stand out and what to update on LinkedIn. Enjoy.

Since 2015 Alex Falcon Huerta has been embracing digital technology. She spotted early on that everything would be moving to the cloud and was years ahead of everyone. Fast forward nearly a decade and her fully remote accountancy company allows her to travel and work from anywhere. She has even co-founded an outsourcing accountancy company in Sri Lanka, SmartOffshore which provides a team of trained accountants to help companies remotely. During our discussion we talk about the benefits of working remotely, the power of asynchronous work and how teams can outsource and delegate to Get More Done. Enjoy

It was a quiet week news wise at SN1 so we covered a range of topics that we want your opinions on please so listen, reply and get involved.

It sounds counterintuitive: less time working, but getting more done. So many companies are exploring a 4 day work week. On this episode we learn how e-commerce OS Bolt has transitioned to a shortened week and how things have changed. Ian Leslie Senior Director of Retail Advocacy at Bolt shares more on how the platform itself was built to save merchants time and we discuss the "theater of work" and the benefits of the work life balance with a 4 day work week. Enjoy.

In this episode we sit down with time management pro Taly Matiteyahu. Hear about her journey from lawyer to co-founder of a voice-first dating app and how you can take the plunge to start your own business. Taly Matiteyahu went from being a lawyer, to a business operations expert, to a podcaster and the co-founder of a dating app. And who says we can't do it all?With so much on her plate, Taly is always finding ways to be more efficient and organized. Now she's sharing her experience to teach us how to start a side hustle and manage our time while being kind to ourselves along the way.Tune in (or read below) to learn why Taly swears by to-do lists, what inspired her voice-first dating app, and why we shouldn't wait for the mythical “right time” to start a business. 

How many times have you or someone on your team asked the same question twice? "How do I..." "Where is..." You wouldn't imagine the amount of time you spend repeating things like this. In this epsiode you will learn the importance of having a strong internal communication culture. Julia Soffa, Senior Manager, Internal Communications with Guru explains how she and her company make sure everyone is in the know. Julia also explains some productivity tips she uses to stay organized and she introduces us to the new initiative No Meeting Wednesday. This is a day each week that meetings are discouraged so Guru employees can focus on deep work without distractions. Enjoy.

You probably have something you should be doing right now, but you don't want to do it. Why do you think that is? According to our guest Eric Twiggs, it mostly likely is because you are afraid or there is some discomfort. Eric is a Procrastination Prevention Partner (say that three times fast!).  He works with CEOs and executives to help them understand why they procrastinate and helps them unlock their passion. In his book, THE DISCIPLINE OF NOW he lays out 12 principles to help everyone procrastinate less and Get More Done. We talk about all of that and he shares his tips on how to avoid procrastinating. Enjoy.

Support is often overlooked, but it really is the backbone of any great business. YouCanBook.me is customer focused and everyone including the CEO will spend a bit of time in support to not only help out, but to understand our customers better. On this episode we talk with YouCanBook.me's own Tiffany Darwish. Tiffany is the Customer Education Manager and helps our customers understand the tool. She also curates the robust knowledge base to help customers self serve. We talk about the importance of frictionless on boarding, how she was able to support over 22,000 paying customers with a team of two, and how working with a partner for support is changing the game.

On this episode we talk with author and recruiting consultant, Eric Harkins. He shares the core principles from his book, Great Leaders Make Sure Monday Morning Doesn't Suck. Essentially how companies and manager can build a culture that high performers want to be a part of. We also discuss his thoughts on the great resignation. Enjoy.

In this episode you will discover important strategies that drive a business forward. Procedures such as the importance of customer feedback to create a product or service that they really need, using automation to speed up repetitive chores, and developing a remote work culture that embraces the team spirit.Listen in as Peldi explains his thought processes on boosting productivity within his fully remote workplace and reveals the one important skill that everyone needs. He walks us through how he and the team at Balsamiq do more with less.

What is Kaizen and how can that help your team do more? On this episode we talk with Mark Graban an author, consultant and podcaster that helps teams in many industries build systems for continuous improvement. Mark shares the tips for teams to adopt a Kaizen culture and how to keep things on track. 

Do you feel you're always busy, but not finishing your To Do list? Do you have ambitions but feel you're on shaky ground when you try to achieve them? Do you want to know how to get more done, find your purpose and build solid foundations to hold you as you reach up for your goals?In this episode, coach, psychologist and author Ian Brooks shares his experiences of working with the biggest companies in the world - and reveals what they all had in common which was blocking them from fulfilling their potential. Now you can tap into his research to avoid making the same mistakes.

On this episode we chat with Mark Littlewood to learn how he stays productive despite his ADHD diagnosis, Business of Software's surprising approach to COVID, and why technology can be both our friend and foe.

On this episode learn how to hit the ground running with your new business. Discover the true goal of email marketing, a foolproof recipe for content creation, and how to combat your inner negativity. Does your business solve a profitable problem? Do you know how to find your ideal client? Tai will help you find out. As a school teacher turned entrepreneur, CEO of That Marketing Team Tai Goodwin focuses on empowering female entrepreneurs to build seven and eight figure brands. 

Do you know how to make your brand stand out in a crowded marketplace? It's time to step into the world of employer branding and learn how to nail the hiring process, improve your employer value proposition, and create a company culture that does the work for you. In this episode we talk with Sean Bestor the former head of global employer brand at Whole Foods Market and now running employer brand at Article. Sean talks about the importance of good internal communication and how to make things less transactional. Enjoy.

A life in sales can be brutal, but it doesn't have to be all that bad. On this episode we talk with Matteo Papaluca the head of global sales with BOOM, a platform that helps companies externalize the tasks of capturing amazing images for their websites and apps. We talk about how he reduced his hours in meetings each week by nearly half and how he keeps his team motivated and advice for new managers. Enjoy.

After 12 years of leading multi-billion-dollar initiatives in the corporate world, Shauna Vassell decided to become an entrepreneur. This happened after a severe case of burnout in 2016. Since then she has started consulting and built two businesses. Now she helps her clients scale their own businesses. We talk about how to avoid burnout and what to watch out for. We also discuss the challenges with delegation and how to use time blocking effectively. Enjoy.

Bob "The Teacher" Sparkins hosts a podcasts, webinars, is a speaker, an author, marketing guru and a full time dad. Bob fills us in on how he manages everything and provides insights into how to continue to do work you are great at. Within that he shares how you should be striving to get into a flow state, or the Michael Jordan feeling.  Enjoy.

Aaron Thompson joins us to talk about all things Customer Success. His group SuccessCOACHING has been helping CS teams level up. We talk about the importance of segmentation to help teams do more.  Also Aaron touches on the power of on-boarding to impact customer retention and renewal. Enjoy.

Bridget and Keith Harris have been building software solutions for the past two decades. They have solved problems for friends, family and colleagues along the way. Their latest success, YouCanBook.me is celebrating it's 10th anniversary. Being a bootstrapped company there is always a need to do more with less. Listen to Bridget and Keith share what it takes to build a company from the ground up. Enjoy.

Ajahn Sujato discusses SN1.13 Devatasamyutta Sutta. "Like many of these discourses, here the Buddha repeats a god's verses with a subtle twist towards the Dhamma." Sutta Central. Click here to read the SN1.13 on Sutta Central.   To find and download specific Sutta Classes visit our BSWA DeeperDhamma Podcast and type the sutta title you want into the search box. Audio teachings are available to download from our BSWA Podcast (Dharma talks and guided meditations) and BSWA DeeperDhamma Podcast (retreats and suttas). Videos can be viewed on our BSWA Youtube Channel and YouTube playlists. Books and articles are available on our website here.

In this video we'll be helping you decide which way a reaction will go with certain conditions (SN1, SN2, E1, and E2) Timestamp: (0:49) - Nucleophilicity and Basicity (rows) (1:13) - Nucleophilicity and Columns (2:00) - Reagent acting as nucleophile only (2:25) - Reagent acting as a strong base only (2:44) -Reagent acting as strong base / strong nucleophile (3:20) -Reagent acting as weak base/ weak nucleophile (3:47) -Reagent acting as nucleophile only (primary or secondary substrate) (4:09) -Reagent acting as nucleophile only (tertiary substrate) (4:20) -Reagent acting as a strong base only (primary, secondary, or tertiary substrate) (4:39) -Reagent acting as strong base / strong nucleophile (primary substrate) (5:04) -Reagent acting as strong base / strong nucleophile (secondary substrate) (5:13) -Reagent acting as strong base / strong nucleophile (tertiary substrate) (5:28) -Reagent acting as weak base/ weak nucleophile (primary or secondary substrate) (5:36) -Reagent acting as weak base/ weak nucleophile (tertiary substrate) (6:00) -Regiochemistry/Stereochemistry for SN1 (6:13) -Regiochemistry/Stereochemistry for SN2 (6:22) -Regiochemistry/Stereochemistry for E1 (6:29) -Regiochemistry/Stereochemistry for E2

In this video we'll be comparing all the reactions (SN1, SN2, E1, and E2). Timestamp: (0:00) - Intro (0:33) - Rate Law differences (1:12) - Base/Nucleophile differences (2:33) - Substrate differences (4:07) -Solvent differences (4:53) -Stereochemistry differences (6:02) -Rearrangement differences

I dette afsnit snakker Hasse og Lasse at Hubble igen er oppe og køre, om den nye passager som skal med Jeff Bezos i rummet, Virgin Galtic's flyvetur i rummet, en mulig kandidat til en kommende SN1 og meget mere.     Billeder fra Zhurong af dens faldskærm: https://www.space.com/china-mars-rover-zhurong-parachute-photos  

In this video, we'll be comparing SN1 and SN2 reactions. (0:00) Intro (0:49) -Definition (Nucleophile, Electrophile, Leaving Group, Substrate) (1:13)- SN1 Rate Law 1:28- SN2 Rate Law (1:36)- SN1 two-part reaction (1:55) -SN2 concerted reaction (2:20) -SN1 nucleophile (2:43)- SN2 nucleophile (3:18)- SN1 substrate (3:51)- SN2 substrate (4:21)- SN1 solvent (4:34)- SN2 solvent (4:47)- SN1/SN2 leaving group (5:40)- SN1 stereochemistry (6:04)- SN2 stereochemistry (6:22)- SN1 rearrangement (6:43)- SN2 rearrangement Check out the visual aspect here on our YouTube: https://youtu.be/4XlJZokd5Dc Music from Tunetank.com danyvin - Pretty Lofi (Copyright Free Music) Download free: https://tunetank.com/t/1ugo/3741-pretty-lofi

In this episode, we'll be going over SN1 reactions and factors affecting it. (0:00) - Intro (0:24) -Definitions (Nucleophile, Electrophile, Leaving Group, Substrate) (0:40) - General SN1 reaction (1:05) -SN1 reaction - Headless Horseman Reaction (2:08)- Strength of Nucleophile (2:27)- Steric Effects of Electrophile (3:03)- Solvent 3:16- Leaving Group (3:42)- Hydride Shift (5:22)- Methyl Shift (5:48)- Stereochemistry (6:20)- SN1 Summary Sheet Check out the visual portion of this episode on our youtube: https://youtu.be/cr7salBKHPw

Ep.290: Total Sport's Ryan Walker joins me for a quick Summer update with Swindon Town's ownership battle ongoing and a few new faces arriving to SN1.

Southern California is home to some of the world's most incredible innovations and accomplishments. But who are the change agents responsible for it all? Each week, Giselle Fernandez will take a deep dive into the philosophies and motivations of these people, who are creating an impact throughout the community. LA Stories Unfiltered is the companion podcast to the weekly television series on Spectrum News 1 and gives you an even more in-depth look at the stories and lives of change makers in SoCal.  Listen starting Monday, March 8th.

Episode 6 Sn1. Abrázame Muy Fuerte by Juan Gabriel mindful music translation to teach a mindful way to stop and savor a piece of musical art. Friends don't let friends miss out on Mexican hits. Juan Gabriel is a gorgeous human who I heard about growing up and this song is very meaningful to me. Hope it brings meaning to you listening

This course give you the Complete discussion of on nucleophilic Substitution reaction of Alkyl halide where you will get everything related to understanding of this chapter including terms such as nucleophile, base, leaving group, its nature, strength, concepts, mechanism and stereochemistry of reactions, comparison of SN1, SN2, E1, E2 with details of it. What you'll learn This course is giving you complete understanding of the chapter "Nucleophilic Substitution and elimination reactions of alkyl halide from the book of Solomons, Fryhle & Snyder Introduction of Alkyl halide Concept of Nucleophilic Substitution Reaction Concept of Nucleophile Concept of Leaving Groups Kinetics of a nucleophilic substitution reaction SN2 Mechanism of SN2 Reaction Concept of SN1 Reaction Mechanism of SN1 Reaction Carbocation Stereochemistry of SN1 Reaction Factors affecting rates of SN1 and SN2 Reaction Summery of SN1 Ans SN2 Reaction Organic synthesis and functional group transformation Elimination Reaction of alkyl halide Concept of E2 Reaction Concept of E1 Reaction How to determine whether substitution or elimination reaction to take place Overall Summary Are there any course requirements or prerequisites? This course give complete information of the topic so there is no prerequiresites. here I will discuss starting from ground level. Who this course is for: Current organic chemistry students, or students about to start organic chemistry who are looking to get ahead Homeschool parents looking for extra support with organic chemistry Chemists Chemical engineers Professionals working in chemical, petrochemicals, pharmaceuticals, cosmetics, oil and gas industries Anyone who seeks to broaden the sphere of his knowledge and discover the fascinating world of organic chemistry Anyone who wants to study organic chemistry for fun after being away from university for a while IIT JEE Aspirants NEET Aspirants

NHL Picks and Predictions for Tuesday, August 4, 2020: In this episode of Puck Time, The Prez, and his panel of expert hockey handicappers look at the NHL games for today and preview the action on the ice from a sports betting perspective. The boys wrap up the show with the "Last Minute of Play" where they go over the entire NHL slate, including free hockey picks for tonight.NHL Games for Tuesday, August 4, 2020Panthers vs. Islanders, Noon ET NBCSN, SN, fuboTVCoyotes vs. Predators, 2:30 p.m. ET NHLN, SN1, fuboTVBlue Jackets vs. Maple Leafs, 4 p.m. ET NBCSN, SN, fuboTVFlames vs. Jets, 6:45 p.m. ET NHLN, SN, fuboTVHurricanes vs. Rangers, 8 p.m. ET NBCSN, fuboT

NHL Picks and Predictions for Tuesday, August 4, 2020: In this episode of Puck Time, The Prez, and his panel of expert hockey handicappers look at the NHL games for today and preview the action on the ice from a sports betting perspective. The boys wrap up the show with the "Last Minute of Play" where they go over the entire NHL slate, including free hockey picks for tonight.NHL Games for Tuesday, August 4, 2020Panthers vs. Islanders, Noon ET NBCSN, SN, fuboTVCoyotes vs. Predators, 2:30 p.m. ET NHLN, SN1, fuboTVBlue Jackets vs. Maple Leafs, 4 p.m. ET NBCSN, SN, fuboTVFlames vs. Jets, 6:45 p.m. ET NHLN, SN, fuboTVHurricanes vs. Rangers, 8 p.m. ET NBCSN, fuboT

Spaceflight news— Rocket Lab completes successful demonstration of mid-air capture. (rocketlabusa.com) (youtube.com) (spacenews.com) — Tim Dodd published a great interview with Peter Beck (youtu.be)Short & Sweet— Mars helicopter has been attached to NASA rover. (nasa.gov)— Starliner gets a second flight test. (spacenews.com)— Long March Fails to loft Nusantara Dua (spacenews.com) (spaceflightnow.com)— Masten Space Systems wins lunar lander award from NASA. (spacenews.com)Questions, comments, corrections— Chris Hofmann: It’s not LOX vents that have flares, it’s Methane.— Ben Hallert and Chris Hofmann: Grasshopper didn’t explode, that was F9R dev (twitter.com/chairboy/)— Ben Hallert: “Starpopper” was the same thing as SN1. (twitter.com/chairboy)— Eric Blood via email: worm logo (PDF: nasa.gov)— Apollo 13: Home Safe viewing party — April 14, Tuesday at 7 p.m. Eastern — Join us on Discord and Watch2Gether! (discordapp.com) (watch2gether.com)This week in SF history— 16 April 1965: first five-engine test stand firing of S-IC at MSFC (nasa.gov) (heroicrelics.org) (wikipedia.org)— Next week in 1971: Like Jar-Jar and an off-cast 620C

Join the fan chat on Discord! Link: https://discord.gg/FupzWf Musk's Top Concern Now Is SpaceX Getting to Mars Before He Dies Link: https://www.bloomberg.com/news/articles/2020-03-09/elon-musk-worries-spacex-won-t-get-to-mars-before-he-dies While others worry about economies slipping into recession and markets melting down, Elon Musk's biggest concern is that his rocket company SpaceX may fail to accomplish its foundational mission -- getting to Mars -- before he dies. “If we don't improve our pace of progress, I'm definitely going to be dead before we go to Mars,” Musk said Monday at the Satellite 2020 conference in Washington. “If it's taken us 18 years just to get ready to do the first people to orbit, we've got to improve our rate of innovation or, based on past trends, I am definitely going to be dead before Mars.” In November 2018, he told Recode that closely held SpaceX was aiming to get to Mars in 2024, and told Axios that there was a 70% chance that he personally would go. Confidential Tesla and SpaceX documents were leaked online after one of their suppliers was hacked Link: https://www.businessinsider.com/tesla-spacex-documents-leaked-online-after-supplier-hacked-2020-3 Tesla and SpaceX documents have been leaked online after one of their suppliers was hacked, TechCrunch reported. A representative for the supplier, Visser Precision, confirmed to Business Insider that company data had been accessed or stolen in a "criminal cybersecurity incident." The representative said "business is operating normally" while the company investigates the incident. Security experts told TechCrunch that the DoppelPaymer ransomware was responsible for the hack. DoppelPaymer demands a ransom in exchange for declining to publish the stolen files, and so far, nondisclosure agreements involving Tesla and SpaceX have been posted on a public website, according to TechCrunch's report. SpaceX moving on to Starship SN2 prototype after SN1 bites the dust in test Link: https://www.space.com/spacex-starship-sn1-prototype-test-failure-sn2-next.html Elon Musk seems to be taking SpaceX's recent Starship setback in stride. On Friday night (Feb. 28), the second full-size prototype of SpaceX's Mars-colonizing Starship vehicle, a variant known as the SN1, was destroyed during a pressurization test. Musk didn't immediately tweet about Friday night's incident. But the billionaire entrepreneur posted a few items early Monday morning (March 2) that suggest he's not dwelling on the SN1's demise. "So … how was your night?" read one tweet, which accompanied a video of the prototype's death. This was followed by "It's fine, we'll just buff it out," and then another tweet that said, "Where's Flextape when you need it!?" And in yet another Monday-morning tweet, Musk said that SpaceX has shifted its focus to the next prototype iteration, the SN2, which is already under construction. "We're stripping SN2 to bare minimum to test the thrust puck to dome weld under pressure, first with water, then at cryo. Hopefully ready to test in a few days," Musk wrote. DAREDEVIL 'MAD' MIKE HUGHES FAILED TO DEPLOY BACKUP CHUTES... May Have Blacked Out Link: https://www.tmz.com/2020/03/02/daredevil-mad-mike-hughes-fatal-rocket-crash-backup-parachutes/ "Mad" Mike Hughes may have blacked out and that's why he failed to deploy backup parachutes moments before his fatal rocket crash ... TMZ has learned. Mike's rep, Darren Shuster, tells TMZ ... the daredevil's launch got off to a terrible start when his parachute got snagged by a ladder next to the rocket. Mike needed a ladder because he didn't wanna be lifted into it, as they had initially prepared. When the parachute got snagged, Mike's ground control crew radioed Mike and ordered him to deploy his backup parachute. There were 2 backups on the rocket. Problem was ... the ground crew never got a response from Mike. Shuster tells us Mike's crew believes he may have blacked out with the rocket taking off at around 500 MPH. Shuster believes if Mike blacked out, it could very well explain why he never deployed his backup chute. The timing for deploying the backup chutes was also critical ... Mike would have had to deploy the backup before he hit his apex because if he was descending at too high of a speed, it would have ripped a hole in the chute. But, Mike never got the chance. Show Stuff The Dark Horde Podcast: https://www.spreaker.com/show/the-dark-horde The Dark Horde, LLC – http://www.thedarkhorde.com Twitter @DarkHorde or https://twitter.com/HordeDark TeePublic Store - Get your UBR goodies today! http://tee.pub/lic/2GQuXxn79dg UBR Truth Seekers Facebook Group: https://www.facebook.com/groups/216706068856746 UFO Buster Radio: https://www.facebook.com/UFOBusterRadio YouTube Channel: https://www.youtube.com/channel/UCggl8-aPBDo7wXJQ43TiluA To contact Manny: manny@ufobusterradio.com, or on Twitter @ufobusterradio Call the show anytime at (972) 290-1329 and leave us a message with your point of view, UFO sighting, and ghostly experiences or join the discussion on www.ufobusterradio.com For Skype Users: bosscrawler

Join the fan chat on Discord! Link: https://discord.gg/FupzWf Musk's Top Concern Now Is SpaceX Getting to Mars Before He Dies Link: https://www.bloomberg.com/news/articles/2020-03-09/elon-musk-worries-spacex-won-t-get-to-mars-before-he-dies While others worry about economies slipping into recession and markets melting down, Elon Musk's biggest concern is that his rocket company SpaceX may fail to accomplish its foundational mission -- getting to Mars -- before he dies. “If we don't improve our pace of progress, I'm definitely going to be dead before we go to Mars,” Musk said Monday at the Satellite 2020 conference in Washington. “If it's taken us 18 years just to get ready to do the first people to orbit, we've got to improve our rate of innovation or, based on past trends, I am definitely going to be dead before Mars.” In November 2018, he told Recode that closely held SpaceX was aiming to get to Mars in 2024, and told Axios that there was a 70% chance that he personally would go. Confidential Tesla and SpaceX documents were leaked online after one of their suppliers was hacked Link: https://www.businessinsider.com/tesla-spacex-documents-leaked-online-after-supplier-hacked-2020-3 Tesla and SpaceX documents have been leaked online after one of their suppliers was hacked, TechCrunch reported. A representative for the supplier, Visser Precision, confirmed to Business Insider that company data had been accessed or stolen in a "criminal cybersecurity incident." The representative said "business is operating normally" while the company investigates the incident. Security experts told TechCrunch that the DoppelPaymer ransomware was responsible for the hack. DoppelPaymer demands a ransom in exchange for declining to publish the stolen files, and so far, nondisclosure agreements involving Tesla and SpaceX have been posted on a public website, according to TechCrunch's report. SpaceX moving on to Starship SN2 prototype after SN1 bites the dust in test Link: https://www.space.com/spacex-starship-sn1-prototype-test-failure-sn2-next.html Elon Musk seems to be taking SpaceX's recent Starship setback in stride. On Friday night (Feb. 28), the second full-size prototype of SpaceX's Mars-colonizing Starship vehicle, a variant known as the SN1, was destroyed during a pressurization test. Musk didn't immediately tweet about Friday night's incident. But the billionaire entrepreneur posted a few items early Monday morning (March 2) that suggest he's not dwelling on the SN1's demise. "So … how was your night?" read one tweet, which accompanied a video of the prototype's death. This was followed by "It's fine, we'll just buff it out," and then another tweet that said, "Where's Flextape when you need it!?" And in yet another Monday-morning tweet, Musk said that SpaceX has shifted its focus to the next prototype iteration, the SN2, which is already under construction. "We're stripping SN2 to bare minimum to test the thrust puck to dome weld under pressure, first with water, then at cryo. Hopefully ready to test in a few days," Musk wrote. DAREDEVIL 'MAD' MIKE HUGHES FAILED TO DEPLOY BACKUP CHUTES... May Have Blacked Out Link: https://www.tmz.com/2020/03/02/daredevil-mad-mike-hughes-fatal-rocket-crash-backup-parachutes/ "Mad" Mike Hughes may have blacked out and that's why he failed to deploy backup parachutes moments before his fatal rocket crash ... TMZ has learned. Mike's rep, Darren Shuster, tells TMZ ... the daredevil's launch got off to a terrible start when his parachute got snagged by a ladder next to the rocket. Mike needed a ladder because he didn't wanna be lifted into it, as they had initially prepared. When the parachute got snagged, Mike's ground control crew radioed Mike and ordered him to deploy his backup parachute. There were 2 backups on the rocket. Problem was ... the ground crew never got a response from Mike. Shuster tells us Mike's crew believes he may have blacked out with the rocket taking off at around 500 MPH. Shuster believes if Mike blacked out, it could very well explain why he never deployed his backup chute. The timing for deploying the backup chutes was also critical ... Mike would have had to deploy the backup before he hit his apex because if he was descending at too high of a speed, it would have ripped a hole in the chute. But, Mike never got the chance. Show Stuff The Dark Horde Podcast: https://www.spreaker.com/show/the-dark-horde The Dark Horde, LLC – http://www.thedarkhorde.com Twitter @DarkHorde or https://twitter.com/HordeDark TeePublic Store - Get your UBR goodies today! http://tee.pub/lic/2GQuXxn79dg UBR Truth Seekers Facebook Group: https://www.facebook.com/groups/216706068856746 UFO Buster Radio: https://www.facebook.com/UFOBusterRadio YouTube Channel: https://www.youtube.com/channel/UCggl8-aPBDo7wXJQ43TiluA To contact Manny: manny@ufobusterradio.com, or on Twitter @ufobusterradio Call the show anytime at (972) 290-1329 and leave us a message with your point of view, UFO sighting, and ghostly experiences or join the discussion on www.ufobusterradio.com For Skype Users: bosscrawler

To start of March of 2020, we are going to discuss the Balance. The balance of life as a human being, science, and making human life interplanetary. In all three of these, failure plays a major role. When you view failure through the right lens, things can change for you.  In this episode, we discuss how I had a reminder of how failure can be viewed to make you better, if you can only separate yourself from the emotion of it. Our latest attempt at 3D printing the Mandalorian Helmet didn't have the results we wanted, but it reminded me failure is part of the journey. It's also something SpaceX has figured out as a way to develop space technology more rapidly than ever before, like the Starship and Falcon 9. 3D Printing Organs: https://singularityhub.com/2019/05/07/new-progress-in-the-biggest-challenge-with-3d-printed-organs/ 3D Printing Houses: https://youtu.be/gVUlbpZS0Rc Made In Space - ISS First 3D print in Space: https://madeinspace.us/capabilities-and-technology/additive-manufacturing-facility/ Footage of SN1 anomaly by SPadre: https://youtu.be/GenS0_BvGPU Progress of Mandalorian helmet:  Part 1: https://vm.tiktok.com/gP3Hv6/ Part 2: https://vm.tiktok.com/g5Bf2V/ (it went viral!) Part 3: https://vm.tiktok.com/g5kGA5/  Part 4: https://vm.tiktok.com/g5eJu8/ (36 hours in...disaster strikes)

Boca Chica, Texas. 28 de febrero de 2020. El prototipo de Starship explota por segunda vez debido a un mal montaje de los tanques de combustible líquido. Elon promete que seguirán adelante con prototipos más avanzados. Mientras tanto, el Falcon Heavy, nuestro cohete favorito sigue adelante con nuevas misiones, entre ellas una de 2022 para llevar una misión de la NASA al asteroide Psyque para analizar su composición de hierro y níquel. Por último, nuestro héroe de Pretoria estuvo en un simposio de las Fuerzas Aéreas de EE.UU. hablando del futuro de la guerra. Elon Musk says ‘the fighter jet era has passed’ SpaceX Is Taking Over the Tiny Village of Boca Chica La explosión del SN1 en vídeo Elon Musk on Twitter: We’re stripping SN2 to bare minimum to test the thrust puck to dome weld under pressure, first with water, then at cryo. Hopefully, ready to test in a few days.”r SpaceX’s Falcon Heavy is getting a giant cloak for key military missions NASA Awards Launch Services Contract for the Psyche Mission Over 30 OneWeb satellites delivered from Florida to Baikonur spaceport Stealth (2005) la película de Jessica Biel que comentamos ELON está presentado por Matías S. Zavia (@matiass) y Álex Barredo (@somospostpc). Su tema original está compuesto por Nahúm García (@nahum). — Alojado en Cuonda (@cuonda)

由于疫情影响，优信二手车在上周末给部分员工的致信中表示，需从3月1号起停工待岗。不过，在此期间，优信二手车将按照各地政策支付员工的最低生活保障，并负担员工的基本社保和住房公积金。此前36氪曾对优信降薪等决策进行独家报道。 芒果超媒披露业绩快报，2019年，公司实现营业收入125.23亿元，同比增长29.63%；实现归属于上市公司股东的净利润11.57亿元，同比增长33.62%。芒果TV运营主体湖南快乐阳光互动娱乐传媒有限公司实现营业收入81.09亿元，同比增长44.63%。广告业务、会员业务、运营商业务均实现较快增长，其中会员业务增幅超过100%。 3月5号起，网易严选在APP众筹栏目发起原创支持计划，以支持原创商家共度时艰，并将计划命名为“春天”，希望帮助平台内原创商家摆脱疫情带来的困境，主要通过众筹方式成功为他们提供畅通的销路及用户支持。 复星集团董事长郭广昌在复星官方微信公号宣布，集团紧急调拨第一批发往日本的3.6万件防护物资，包括能够进入医院“红区”的口罩、护目镜，以及防护服、鞋套、手套，医用外科口罩等，支援日本抗击疫情。此外，通过合作伙伴，以最快的速度将当地所需的医疗产品送往韩国，助力韩国抗击疫情。同时，复星也通过欧洲的团队紧急调配了5000个能够进入医院“红区”的口罩，支援意大利米兰，为意大利送去最需要的防护物资。 据路透社报道，三星并不是唯一一家受到新冠肺炎疫情困扰的韩国科技巨头。韩国显示面板制造商LG Display位于韩国龟尾市的一家智能手机显示屏工厂暂时停止生产，因工厂附近有一名银行员工的新冠病毒检测结果呈阳性。LG Display预计工厂将于3月3号恢复生产，但没有透露停产将对该公司的智能手机显示屏产量造成怎样的影响。 谷歌表示，针对目前不断发展的新冠病毒情况，支持组织方推迟GDC 2020的决定。本次线上活动将于3月16号开始，进行为期2天的线上直播。公司内的许多团队将会展示最新成果。根据安排，主要包括Android游戏开发、Google Cloud，而有关于Stadia的内容将会在隔日举行。 SpaceX星际飞船原型SN1，在上周五的一次压力测试中发生爆炸。根据拍摄的视频，SpaceX上周早些时候将SN1原型移动到德克萨斯州博卡奇卡工厂附近的发射台上。然而，这个原型产品在液氮压力测试中发生爆炸。SpaceX创始人及CEO埃隆·马斯克此前曾表示，完善星际飞船需要许多这样的测试原型。

Hi, I’m Stewart Spinks and welcome to Episode 77 of my podcast, Beekeeping Short and Sweet.Who’d have thought we’d be extracting honey so soon, the Summer season has flown by and I’m heading into the honey room to get set up to extract the Summer supers over the weekend? Listen on for a rundown of my extraction set up and how I extract from over sixty colonies in a room that measures just 3 metres square.Check Out my Patreon Page HEREEquipment discussed in today's Podcast:Stainless Steel TablesScalesApimelterBrush UncapperExtractorDouble Strainer100kg Settling TankHoney CreamerBottling MachineBefore we head into the honey room I wanted to say a big thank you to Craig from Jedburgh, one of our Patreon supporters who very kindly drove down to Norfolk this week to spend a few days helping out and inspecting bees. Craig is new to beekeeping and has been absorbing all or my videos and podcasts on Patreon and offered to lend a hand for a few days so not wanting to turn away any help I swapped around the workload a little so we could get over to the workshop and clean up the rather large stack of frames and boxes that needed cleaning instead of extracting honey. A lot of the boxes are left over from the early season oilseed rape extraction where we had to cut out the comb and honey as it had granulated in the frames and couldn’t be extracted in the normal way. This leaves lots of frames that need to be roughly scrapped and tied into bundles before being boiled and cleaned ready to take fresh foundation in the Spring next year before going back out onto the hives. We also scrape out the supers and scorch them lightly as part of our ongoing disease management and this also entails removing frame runners and either washing them before replacing or if they’re too badly damaged we replace them. I think I might have mentioned before that I’m switching my super frames over to Manley frames, these are the straight, wide sided frames instead of the more traditional SN1’s or SN4’s, SN1’s are the narrow straight sided frames for supers and SN4’s are the Hoffman style spacing. It’s interesting that there are so many different types of frames that you could use and each beekeeper no doubt has a favourite. The same applies to the frame runners in the supers, I’ve always used castellated runners with set spacing for ten frames although I have tried eleven and nine frame runners. The point here is you start of using frames with foundation that have eleven frames meaning the frames are placed closer together and hopefully the bees draw out the foundation perfectly straight before progressing to ten frame runners and finally nine frame runners thereby getting more honey per frame which ultimately means less frames to extract.The trouble with this is if you have more than a few supers it can get a bit confusing when you think you’ve got ten frame spacing and it’s eleven or nine. Add to that the need to get everything organised and in it’s prope

The next-gen Roadster may be closer to production than we think, Elon gets Model 3 SN1 for his birthday, Model X finally fulfills the promise of its original prototype, and more! If you enjoy the podcast and would like to support it, please check out my Patreon at www.patreon.com/teslapodcast and consider a pledge. Every little bit helps! Don't forget to leave a message on the Ride the Lightning hotline anytime with a question, comment, or discussion topic for next week's show! The toll-free number to call or Skype is 1-888-989-8752. And if you're buying a Model S or Model X, use this referral code in order to get $1,000 off your car (plus free unlimited lifetime Supercharging) and give me a chance to win a Tesla! http://ts.la/gordon1872  

A huge week in Talking Tesla Nation! The Model 3! SN1 arrived on Saturday, Tesla board member Ira Ehrenpreis was in line to receive the first car, but passed its rights to Elon Musk as a 46th birthday present. Other big EV news is that Volvo announced that all Volvos will have some electric motor, hybrid or full EV from 2019. In Battery news, TESLA energy is about to install the world's biggest battery backup in the world, by a factor of 3 (130 MWH) in 100 days...or forfeit about 50 million! Lots of other renewable energy, autonomous driving, and EV discussions this week.Support the show (https://www.patreon.com/talkingtesla)

SN1 on Friday We unpack Elon’s recent tweets about Model 3 progress. The news that the Model 3 has passed all regulatory requirements, the first car is scheduled to be produced later this week, and the delivery event is happening Friday July 28th at Tesla Fremont. We try to make sense of it all, how the ramp compares to the S and X and what is still to come.

In this episode, we examine the SN1 reaction from a couple of different points of view.  We also go to the virtual whiteboard to clear up a misconception on the reaction and discover a website with some fun chemistry stuff like organic chemistry tetris.  As always, you can find more help at organic chemistry.  

Bridged pentavalent carbon structures can be intermediates or transition states of cation rearrangement during SN1 reactions, and short-lived ion pairs explain net stereochemical inversion. The different perspectives of preparative organic chemists and mechanistic organic chemists on reaction yields are illustrated by a study designed to demonstrate that molecular rotation can be rate-limiting in viscous solvents. “Electrophilic” addition to alkenes is the reverse of E2 or E1 reaction, and its mechanisms can be studied by analogous techniques. The NIST Webbook provides thermochemical data to help understand the relative stability of isomeric alkenes. Complete course materials are available at the Open Yale Courses website: http://oyc.yale.edu This course was recorded in Spring 2011.

Preliminary X-ray analysis of molecules that have been designed to favor a carbon with five bonds seemed to suggest the possibility of a pentavalent intermediate in SN2 reactions, but further analysis of these structures showed just the opposite. Boron, however, can be pentavalent in such an environment. E2, SN1 and E1 mechanisms compete with the SN2 reaction. Factors controlling E2 eliminations are illuminated by kinetic isotope effects, stereochemistry, and regiochemistry. The competition between E2 and SN2 mechanisms influence the design of synthetic schemes, including those in which carbon nucleophiles play an important role. SN1 and E1 reactions involve carbocation intermediates and thus the possibility that the carbon skeleton will rearrange. Complete course materials are available at the Open Yale Courses website: http://oyc.yale.edu This course was recorded in Spring 2011.

One of the main challenges in photochemical energy conversion is the design of charge separating units which are able to generate a long lived charge separated state, and to couple efficiently to an energy storage state. In part I of this work the energy conversion efficiency of a photochemical unit inspired by bacterial photosynthesis is investigated. The developed model is based on non-adiabatic multi step electron transfer to generate a trans-membrane potential gradient. Upon optimization with multi objective genetic algorithms, the biological strategies for high quantum efficiency in photosynthetic reaction centers are derived, which have to suppress loss channels such as charge recombination. The concepts of bacterial photosynthesis are extended to the design of artificial photochemical devices. The unified model consists of a charge separation unit and an energy storing system whereby the coupling between both units is assured by thermal repopulation according to the principle of detailed balance. The complete photosynthetic unit is characterized by the respective current-voltage relation and an upper limit for the overall energy efficiency is derived under AM1.5 global conditions. Such a realistic chemical solar energy conversion system can reach efficiencies, which are comparable to the limits of an ideal single-junction solar cell. In Part II of this work the reactive dynamics of two surrounding controlled photoreactions is investigated on a microscopic scale. In general the effect of the surrounding can be classied into intramolecular contributions, like steric or electronic effects, and intermolecular contributions like the solvent or the embedding in an enzyme. Both limiting cases are examined on the basis of two generic photoreactions. The Dewar DNA lesion follows quantitatively from the 6-4 lesion by UV-A/B irradiation and constitutes the stable end product of continuous solar irradiation. Here the detailed mechanism of the formally 4π-sigmatropic rearrangement is presented, which predicts that only in the (6-4) dinucleotide the Dewar is exclusively formed from an excited valence state, but not in the free base 5-methyl-2-pyrimidinone (5M2P) nor with a sliced backbone. The mechanism is elucidated by the analysis of conical intersections which show, that the photochemical deactivation of T(6-4)T is strongly in influenced by the confinement in the dinucleotide, leading to T(Dewar)T formation, whereas in 5M2P the photophysical protection is ensured by a conical intersection seam. The implementation of the ONIOM-method into the non-adiabatic mixed quantum classical dynamics allows to follow the formation of the T(Dewar)T lesion as well as the competing photophysical relaxation. C=O-vibrations are identied as unambiguous spectroscopic probe of the 4π-sigmatropic rearrangement for highly sensitive UV/VIS pump - IR probe experiments which were successful in following the reaction in real time. As a second photoreaction the ultrafast phototriggered reaction of benzhydryl cations with methanol is investigated. The mechanism of the laser induced generation of highly reactive benzhydryl cations from the precursor molecule diphenylmethyl chloride is derived by quantum chemical and quantum dynamical methods. For the competing reaction channels of ion pair and radical pair formation the interaction of different electronic states leads to ultrafast bond cleavage. The homolytic bond cleavage as a parallel reaction-channel is already accessible in the FC region by the participation of lone-pairs of the Cl-leaving group. Based on ab initio data a system Hamiltonian is derived which is suitable to describe the multidimensional dissociation process in a reduced reactive coordinate space. Quantum dynamical calculations show that bond cleavage induced by a Fourier limited femtosecond laser pulse provides the ion pair despite its higher potential energy and the existence of conical intersections. The subsequent bimolecular bond formation, which constitutes the second part of the SN1 reaction, is investigated by on-the-fly molecular dynamics simulations in a micro-solvation approach. The calculated solvation correlation function and time resolved UV/VIS spectra are compared to recent experimental findings. By the detailed microscopic description the assignment of the spectral features to different molecular events is possible. The results show that the rising spectral signature of the generated benzhydryl cations is not directly correlated with the bond cleavage, a fact that has to be considered in the interpretation of the signal for a complete understanding of the reaction mechanism.

SN2 reaction; SN1 reaction; elimination reactions and Zaitsev's rule; E2 reaction and cyclohexane conformation; E1 reaction; summary of reactivity; synthesis practice

SN1 and SN2

Friedel-Crafts-Alkylierungen und mechanistisch verwandte Reaktionen wie tert-Alkylierungen von Silylenolethern oder Alkoxyalkylierungen von Allylsilanen und Enolethern werden üblicherweise von Lewis-Säuren in inerten Lösungsmitteln induziert. Führt man solche Reaktionen in wässrigen oder alkoholischen Lösungen durch, verwendet man Brönsted- oder nicht hydrolysierbare Lewis-Säuren, um kleine Gleichgewichtskonzentrationen von Carbokationen zu erzeugen. Basische oder auch neutrale wässrige oder alkoholische Lösungen wurden für solche Umsetzungen bislang als ungeeignet angesehen, da Wasser und Alkohole intuitiv als starke Nukleophile eingeschätzt werden, die die Intermediate von SN1-Reaktionen sofort abfangen und pi-Nukleophilen keine Möglichkeit lassen, mit den kurzlebigen Carbokationen zu reagieren. Auf der Basis von Reaktivitätsskalen (Lineare-Freie-Energie-Beziehung lg k (20°C) = s(E + N); Mayr, Patz 1994) wurde in dieser Dissertation eine neue Variante zur Durchführung von Friedel-Crafts-Alkylierungen, Hoaglin-Hirsch-, Hosomi-Sakurai- oder Mukaiyama-Reaktionen mit SN1-aktiven Alkylierungsmitteln ohne Lewis- oder Protonensäurekatalyse entwickelt, die gegenüber den etablierten Verfahren prägnante ökologische und ökonomische Vorteile bietet. Eine große Bandbreite von Benzolderivaten, Heteroarenen und (Silyl-)Enolethern konnte durch Benzhydryl-, Benzyl- sowie Allyl-Kationen alkyliert werden, die solvolytisch in wässrigen oder alkoholischen Lösungsmitteln unter milden Reaktionbedingungen (neutraler bis schwach basischer pH, Raumtemperatur) generiert wurden.

Benzhydrylium ions, which have previously been characterized as reference electrophiles in the Mayr group, have been employed for the construction of general nucleophilicity and electrophilicity scales. The kinetics of the reactions of benzhydrylium ions with 15 n-nucleophiles in water and DMSO were measured to yield the N- and s-parameters. Most of the nucleophiles have closely similar slope parameters indicating that the reactions of most n-nucleophiles approximately follow Ritchie's constant selectivity relationship. The different slope parameter for water is recognized as the main reason for deviations from the Ritchie relationship reported in 1986. The rates of the reactions of benzhydrylium ions with solvent mixtures of variable composition have been determined. From plots of the first-order rate constants (log k) versus E of benzydrylium ions, the solvent nucleophilicity parameters are derived. This allow the systematic design of Friedel-Crafts reactions with solvolytically generated carbocations. Rate constants for the reactions of laser flash photolytically generated benzhydrylium ions with chloride and bromide anions have been determined in various solvents and compared with literature data. The rate constants for the ionization of benzhydryl halides and for the reactions of benzhydrylium ions with halide anions and with solvent are combined to give complete free energy profiles for solvolysis reactions. The first SN1 reaction, where ionization and trapping of the carbocation by the solvent could directly be observed, is reported.

Competition experiments have been performed to determine the relative reactivities of 23 alkyl chlorides toward allyltrimethylsilane in the presence of catalytic amounts of ZnCl2.The krel scale spans over 11 orders of magnitude from 1-adamantyl chloride (least reactive) to bis(p-methoxyphenyl)methyl chloride (most reactive compound). A fair correlation between the alkylating ability and the SN1 reactivity in solvolysis reactions is found, thus providing a quantitative basis for our long-standing working hypothesis that Lewis acid-catalyzed additions of alkyl halides to CC multiple bonds only yield 1:1 products if the reactants ionize faster than the products. Trityl chlorides do not follow this correlation and are 105 times less reactive than predicted from their SN1 reactivities.