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Sometimes you witness a passage of play in goalkeeping that simply makes the hairs on the back of your neck stand to attention. This weekend, Robert Sanchez and Matz Sels contributed to a "save off" that earned a point for their respective sides Chelsea and Nottingham Forest. Incredible goalkeeping in an incredible moment. For Liverpool, Czech 23-year-old Vitezslav Jaros made his Premier League debut when coming on as a second-half replacement for Alisson in the win over Crystal Palace. He did well, reopening the discussion on whether young or old is suited better to that No3 spot. Established Goalkeeper Coach, David Rouse - in for Richard Lee this week - gives his opinion on the above, as well as casting an eye over the best action from the EFL. Paul Nardi continues to enhance his reputation at QPR, Illan Meslier is the subject of 'Keeper Capers for the freak goal which saw Sunderland scrape a draw with Leeds and Connor Ripley stakes his claim for Performance of the Weekend thanks to his starring role in Port Vale's victory at Notts County. Lastly, we touch on the return of David de Gea. The Spaniard saved two penalties in Fiorentina's triumph over AC Milan, although remarkably two less than Paulo Gazzaniga managed in a week thanks to heroics in Girona's games with Feyenoord and Athletic Bilbao.
All right! We're ready to reveal our No. 3 picks from our Top 10 Horror Movies of 2022 right meow! So, here in Episode 113 of Jay of the Dead's New Horror Movies, you will hear Jay of the Dead, Dave “Dr. Shock” Becker, Mister Watson, Dr. Walking Dead Kyle Bishop, GregaMortis, Count Mackula, Ron Martin and Dave Zee reveal their No. 3 Horror picks from 2022. Also, Gillman Joel announces another FREE Horror Blu-ray give-away. Join us — it's fun! If you want to hear the previous episodes where we reveal our 10 through 5 picks for 2022, then you can find those episodes HERE! More Info: You can find our Top 10 episodes here! In these shows, you will hear from Jay of the Dead, Dr. Shock, Mister Watson, Dr. Walking Dead, GregaMortis, Mackula, Ron Martin and Dave Zee. Gillman Joel did not prepare a Top 10 list, but he still shows up here and there to award our free Horror Blu-ray give-aways! This 10-part episode series is must-listen Horror podcasting! Be sure to subscribe to Jay of the Dead's new Horror movie podcast on: Apple PodcastsSpotifyDeezer You are welcome to email our show at HauntingYourHeadphones@gmail.com, or call and leave us a voicemail at (801) 980-1375. You can also follow Jay of the Dead's New Horror Movies on X: @HorrorAvengers Jay of the Dead's New Horror Movies is an audio podcast. Our nine experienced Horror hosts review new Horror movies and deliver specialty Horror segments. Your hosts are Jay of the Dead, Dr. Shock, Gillman Joel, Mister Watson, Dr. Walking Dead, GregaMortis, Mackula, Ron Martin and Dave Zee! Due to the large number and busy schedule of its nine Horror hosts, Jay of the Dead's New Horror Movies will be recorded in segments, piecemeal, at various times and recording sessions. Therefore, as you listen to our episodes, you will notice a variety of revolving door hosts and segments, all sewn together and reanimated like the powerful Monster of Dr. Frankenstein!
This week, our goal was to "unmask the deception" in Aaron Solomon's 911 call (with the help of the brilliant Paul Maillardet from the Peter Hyatt Statement Analysis team). 911 calls are often a lifeline in emergencies, connecting distressed individuals with first responders who can provide assistance. However, some 911 calls require a trained ear to detect a lack of integrity or truth. Thanks to the diligent work of the Statement Analysis Team, major red flags have been brought to light in this episode. Why did police not pick up on these three years ago?SHOW NOTES:https://www.hyattanalysis.com/https://www.gofundme.com/f/help-get-justice-for-granthttps://www.change.org/p/please-help-me-investigate-the-mysterious-death-of-my-son-grant-solomonCONCLUSION NOTES:1. Did the caller prioritize Grant's plight? No 2. Did the caller facilitate the flow of information to help Grant? No3. Did the caller show empathy towards Grant? No4. Did the caller indicate for subtle blaming of the victim? Yes 5. Did the caller distance himself from Grant? Yes 6. Did the caller describe the attempts to save Grant? No 7. Did the caller ask for help in saving Grant? (instructions, guidance) No 8. Did the caller address Grant's current state to better help responders? No9. Did the caller indicate for candor in this call? No SOME NOTES ABOUT THE BEHAVIOR OF THE CALLER:He has a need to explain, repeatedly, that he does not know how this happened is unexpected while his son is in such danger. Constantly: blaming the car , blaming the victim, blaming the infinite possibilities, delaying by invoking God and not demanding help is not the way to save your son's lifeDISCLAIMER:The following podcast episode features commentary and insights from a team of statement analysts. We would like to stress that the information provided in this episode is intended for informational and educational purposes only. Accuracy of Information: The information presented in this podcast episode is based on the available evidence, reports, and public records. While efforts have been made to ensure accuracy, details may be subject to errors or omissions. Listeners are encouraged to conduct their own research as well.Opinion and Speculation: Throughout the podcast, there may be instances where opinions and/or speculation are expressed regarding certain events, individuals, or circumstances. These are the personal perspectives of the podcast hosts or guests and should not be taken as conclusive or factual statements.
With every goalkeeper (and subsequent goalkeeper coach) comes another story slightly different to the other. Lewis Price played in the Premier League with Derby, but never really believed he deserved to be there. He initially opted out of goalkeeping when a youth spell at Southampton went awry, inadvertently jumped back in with Ipswich, helped Luton reach Wembley in a two-game cameo and freely admits he spent large swathes of his career as either a No2 or No3 - an important role he was happy to perfect. Oh, and there's also the little detail of representing his country, Wales, 11 times. Currently Goalkeeper Coach at Oxford United, Pricey - who recently spent a year out of the game recovering from testicular cancer - gives an insight into how his unique approach to goalkeeping worked as a player, and how that wealth of experience is being passed on to the next generation.
Sense and sensibility Podcast No1 of the new season had 2 of us, podcast No2 had 3 of us and this week, podcast No3 we've got 4 (four) of us on it! Whatever next…? Following the victory over Aberdeen, we've got Eddie, Saint Anthony and Paul T on to discuss the game, where the club are at, signing gossip and the forthcoming game against Killie in the cup. This weeks' podcast is not as long as last week's marathon but it's still an hour of Celtic chat by middle aged Celtic fans - just what we all need on a regular basis. Enjoy…
Josh is joined by Rob Lee and, Guardian journalist, Ewan Murray to look back on a frantic Italian Open and win No3 for Adrian Meronk. They discuss the decisions Luke Donald has ahead of September and the challenges of the Marco Simone course. They chat about the resignations from the DP World Tour, a look ahead to the Soudal Open and Ewan plays his first game of Ponder the Pro.
Today we welcome back a guest who has lived two lives in boxing – firstly as an amateur and then a pro fighter, and for the last 34 years as a referee and judgeLast time we spoke with David Irving, we discussed his career as a fighter but today we'll be hearing about his three and a half decades as an official, with the Boxing Union of Ireland and also the WBCHis first fight as a ref was back 1989, Ray Close beating Seamus Casey at Ulster Hall. New Kids on the Block were top of the pops Don't Know Much by Linda Rondstat was No2, All Around the World by Lisa Stansfield was No3 but soon this new kid on the block knew quite a lot and was travelling around the world in his chosen profession.He's been the man in the middle for Irish fights of the year including Reynolds v Trainor (2013) and Carroll v Geraghty (2014) as well as the fairly controversial Fury v Rogan battle in Belfast back in 2012, when there was actually an attempt by the British board to remove him in advance of the event.Here he also tells us about receiving abuse and even threats during his time working as a referee, still finding a way to be fitter than some fighters 40 years on from his heyday as a boxer himself, and the fouls most favoured by your average Irish puncher. Spoiler alert: some fighters don't need to be told to hit the other guy 'in the ballix'. Hosted on Acast. See acast.com/privacy for more information.
Tridacna (Mördermuscheln): So hältst du sie richtig Auch wenn ihr Name gefährlicher klingt, als er tatsächlich ist, sind Tridacna (Mördermuscheln) bei Meerwasseraquarianern äußerst beliebt und weit verbreitet. Durch ihre schönen Farben und Formen bilden sie einen perfekten Kontrast zu den Korallen und Anemonen im Meerwasseraquarium. Tridacna gehören zu den Riesenmuscheln. Die größte bekannte Art ist die Große Riesenmuschel (Tridacna gigas). Hier ist der Name echt Programm, denn sie kann eine Länge von bis zu 1,40 m erreichen. Sind Tridacna, gefährlich? Nein, gefährdet Ihr Name beruht auf einem uralten Mythos: Angeblich schnappten Tridacna (Mördermuscheln) nach Tauchern und Tieren und hielten sie dann in der Tiefe fest. Von „Schnappen“ kann wirklich nicht die Rede sein, denn sie bewegen ihren Schließmuskel sehr langsam. Tridacna sind nicht gefährlich, sondern selbst massiv gefährdet. Seit langem leiden Tridacna-Arten unter anderem an der Überfischung und den Auswirkungen der immer stärker werdenden Umweltverschmutzung und sind vom Aussterben bedroht. Tridacna wurden durch das Washingtoner Artenschutzübereinkommen geschützt und dürfen nur noch mit einer entsprechenden Cites-Bescheinigung eingeführt werden. Der Großteil der im Handel erhältlichen Muscheln kommt inzwischen aus Muschelfarmen, in denen sie in großen Mengen nachgezüchtet werden. Tridacna im Meerwasseraquarium halten Schauen wir uns mal an, wie du Tridacna im Meerwasseraquarium richtig hältst. Im Meerwasseraquarium brauchen Tridcanen eine sehr starke Ausleuchtung, da sie sich unter anderem von Zooxanthellen, das sind einzelligen Symbiosealgen, ernähren, die in ihren Mantellappen eingelagert sind. Manche Arten können zusätzlich auch noch Plankton aufnehmen. Zudem ist eine mittelstarke Strömung für eine erfolgreiche Haltung von Tridacna erforderlich. Eine direkte und vor allem zu starke Strömung solltest du jedoch auf alle Fälle vermeiden. Denn ist die Strömung für die Mördermuschel zu stark, kannst du es schnell daran erkennen, dass sie sich nicht mehr ganz öffnet. Tridacna im Meerwasseraquarium - Feinde Wichtig bei der Haltung von Tridacna ist, dass man bereits vor dem Kauf weiß, von wem oder was eine Gefahr für die Muscheln ausgeht. So kommt es immer wieder vor , dass Tridacna von größeren Borstenwurmarten angefressen werden und dann in Folge der Schäden eingehen. Auch von bestimmten Fischarten geht eine erhebliche Gefahr für die Tridacna aus. Immer wieder kommt es vor, dass Putzerlippfische versuchen, die Mantellappen der Tridacna zu putzen und sie dabei so stark stressen, dass sie sich nicht mehr öffnet. Wer eine oder mehrere Tridacnen in seinem Aquarium pflegen möchte, sollte unbedingt auf die Haltung von Pinzettfischen verzichten. Denn Pinzettfische fressen Tridacnen. Eine weitere große Gefahr besteht im Sommer für die Tridacna. Besonders empfindlich reagiert die Tridacna auf Wassertemperaturen über 29 °C. Ab dieser kritischen Temperaturgrenze kommt es wie bei Korallen zum Ausbleichen. Das bedeutet, dass die Tridacna aufgrund des Hitzestresses ihre Zooxanthellen abwirft und dadurch im Anschluss langsam verhungert. Auch eine Überdosierung von Spurenelementlösungen kann für Mördermuscheln tödlich enden, da sie sehr empfindlich auf Schwermetalle reagieren. Eine weitere große Gefahr sind Algen, Glasrosen, Feueranemonen: Deshalb musst du unbedingt deine Tridacna davor schützen. Tridacna umsiedeln Muss die Tridacna einmal umziehen oder wird sie beim Kauf aus dem Händlerbecken entnommen, ist hier große Vorsicht angesagt: Die meisten Tridacna-Arten befestigen sich mit den sogenannten Byssusfäden auf dem Korallensand, Steinen oder auch der Bodenscheibe. Bei einer Umsiedlung, darf die Tridacna nicht gewaltsam entfernt werden. Sie muss dann ganz vorsichtig gedreht werden, bis sich die Byssusfäden von der Oberfläche gelöst haben. Werden die Byssusfäden hierbei beschädigt und kommt es dadurch zu einer Infektion, bedeutet dies häufig den Tod der Muschel. Tridacna kaufen Beim Kauf von Tridacna musst vor allem auf zwei Dinge achten. Die Muschel muss vollständig geöffnet sein, so dass ihre Mantellappen komplett über den Muschelschalenrändern liegen. Ist das nicht so, solltest du diese Muschel nicht kaufen. Ein weiteres wichtiges Kaufkriterium bei der Auswahl von Tridacna ist der Schließreflex. Den kannst du ganz einfach testen, indem du über der Wasseroberfläche mit der Hand über den Standort der Muschel streifst und dadurch einen Schatten erzeugst. Auf diesen Schatten reagiert die Tridacna mit einem Schutzreflex, indem sie sich kurz schließt und sich dann im Anschluss sofort wieder voll öffnet. Eine Ausnahme kann es hier bei größeren und eingewöhnten Tieren geben, die teilweise nicht mehr mit dem natürlichen Schließreflex auf Schatten reagieren, weil sie sich inzwischen an diese Schatten gewöhnt haben. Wenn die Tridacna bei einer direkten Berührung oder beim Herausnehmen aus dem Becken sich nicht komplett schließt, ist sie stark angeschlagen und lebt nicht mehr lange. Wenn das der Fall ist, solltest du von einem Kauf unbedingt absehen. Tridacna eingewöhnen Die Umgewöhnung einer Tridacna in dein Meerwasseraquarium erfolgt idealerweise wie bei Fischen langsam mit der bewährten Tröpfchenmtehode. Ist die Eingewöhnung nach rund 60 Minuten abgeschlossen, muss die Tridacna im Anschluss und das ist jetzt wichtig, unter Wasser aus der Transporttüte entnommen und in das Meerwasseraquarium eingesetzt werden. Schauen wir uns zum Schluß noch die optimalen Wasserwerte für die Haltung von Tridacnen an. Optimale Wasserwerte für Tridacna Mördermuscheln sind abhängig von optimalen Wasserwerten im Meerwasseraquarium: Nitrat > 5 Phopshat > 0,05 Besonders niedrige NO3– und PO4-Konzentrationen sind wichtig, um die für das Muschelgehäuse gefährlichen Bohralgen zu vermeiden. pH-Wert 8,2 Dichte 1,023 KH 6-8 Ca 420-450 mg/l Mg 1300-1400 mg/l Tridacna Fazit: Wenn du deine Tridacna vernünftig auswählst und ihr das entsprechende Milieu bietest, sind sie wunderschöne Pfleglinge, die dir lange Freude bereiten können. In Fachzeitschriften tauchen immer wieder Artikel auf, in denen von Exemplaren, die im Aquarium 25 bis 30 Jahre alt wurden, berichtet wird. Für die Haltung im Aquarium empfehle ich vor allem zwei Arten: Einmal die Tridacna squamosa und die Tridacna maxima. Beide Arten zählen zu den robusten Mördermuscheln und sind in der Regel gut zu halten. Von Tridacna gigas würde ich abraten, da diese deutlich zu groß für ein durchschnittliches Meerwasseraquarium werden kann. 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Dafür muss du nur im Warenkorb im Rabattfeld die Zahl 10 eingeben. Rabattcode: 10 Profi-Beratung durch Markus Mahl: Da brauchst du Hilfe bei Einem Problem mit deinem Meerwasseraquarium? Hier kannst du die Beratung buchen: >>>>> Beratung durch Markus Mahl kostenlose Checklisten für dein Meerwasseraquarium : Hier findest du die kostenlosen Checklisten für dein Meerwasseraquarium: https://aktion.aquacura.de/Geschenk Hörbuch-Meerwasseraquarium: Erfahre alles war für ein Meerwasseraquarum wichtig ist in meinem Hörbuch "Meerwasseraquarium - Aquarium bauen und pflegen wie die Profis" Du kannst dir das Hörbuch sofort herunterladen und anhören wann und wo immer du möchtest. 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Summary Hello and welcome to episode #19! This is Ralph Sanchez and today I'll be talking the outcomes of two recent studies that investigated the potential use of Viagra and Cialis in the risk reduction for late-onset Alzheimer's disease (LOAD). I was in part inspired to provide an overview on these two recent studies as they are cautionary tales on how many studies do not include the interrelated factors that are essential in arriving to an integrated assessment and analysis that serves their very premise— which is, does this or that work in a potential solution to something else? Does Viagra or Cialis offer any proposed solution to the risk for LOAD and dementia? Well today, I'll be adding a great deal of information—the missing pieces to the puzzle as it were—with regard the pathways by which Viagra and Cialis may or may not work, and many other complimentary or natural alternatives that play a similar role in maintaining and optimizing a healthy cardiovascular and cerebrovascular system. First, let me provide a little insight as to the molecular pathways in which drugs like Viagra and Cialis function, and why they may be considered as repurposed drug candidates for the treatment or in the risk reduction for LOAD. Viagra (sildenafil) and Cialis (tadalafil) are Phosphodiesterase-5 inhibitors (PDE5is) which fall into a class of drugs that are normally prescribed to men to treat erectile dysfunction (ED), benign prostatic hyperplasia (BPH) and lower urinary tract symptoms (LUTS). PDE5is can have a profound effect on cardiovascular health and PDE5is mediate their benefits by inhibiting the breakdown of a molecule, cyclic GMP (cyclic 3′,5′ guanosine monophosphate). Cyclic GMP (cGMP) is an intracellular and second messenger molecule that modulates many downstream pathways, including significant effects in vasorelaxation—the ability of your blood vessels to dilate and expand as needed. The vascular effect that is enabled by PDE5i-induced vasodilation is a pivotal pathway in vascular homeostasis and a healthy heart-brain axis. And that vasodilation effect is how PDE5is improve and treat ED. There is a lot more to that vasodilation benefit mediated by PDE5i therapy which I'll get to here soon. So on to a brief description of the two recent studies on Viagra and Cialis, and so much more that was not included in those studies that will provide a crucial insight into how you can improve your vascular health and reduce your risk for LOAD. NIH Studies First, a recent (2021)National Institutes of Health (NIH) funded study reported a risk reduction benefit of 69% for Alzheimer's disease (AD) in users of Viagra (Sildenafil). The analysis simply compared Viagra users to those who did not take it, and the study was focused on a screen of drugs that could potentially be repurposed in the risk reduction for AD in aging individuals. In a similar and second NIH funded study published this year (2022) titled— Drug Repurposing for Effective Alzheimer's Medicines—(DREAM), the NIH analyzed data from Medicare beneficiaries that were treated with Viagra and Cialis. The NIH team compared people with pulmonary arterial hypertension (PAH) treated with Viagra and Cialis over those with PAH on another class of drugs (endothelin receptor antagonists) used to treat pulmonary hypertension. And note that PAH is a term that refers to high blood pressure in the blood vessels leading from the heart to the lungs Yes, PDE5is are also prescribed to patients to reduce blood pressure in PAH, and off-label use of PDE5 inhibitors (PDE5is) is used to treat cardiovascular diseases, Raynaud's disease and women with female sexual arousal disorder. The average age of patients included in the DREAM study “was 74 years (range 65–96 years), and 69% were women.” Notably, studies have shown that in women, "PDE5 inhibitor efficacy is estrogen dependent in female heart disease." The DREAM PDE5i study rationale for focusing on patients with PAH and treated with PDE5is, Viagra or Cialis, for the new study analysis over those individuals on another class of antihypertensive drugs was attributed to the odds that the two groups were "more likely to have people with similar characteristics". In comparing those two pulmonary hypertension groups in the DREAM study the research team concluded that they "observed no evidence for a reduced risk of Alzheimer's disease and related dementia with phosphodiesterase-5 inhibitors"—Viagra or Cialis. Bottom line, two differences in the design and outcomes as the Viagra study was favorable while the DREAM study was not. Fair enough. However, there is much more to this story that was not included in the two studies, which includes an important benefit for heart and brain health that is only in part mediated by PDE5i therapy. And we begin with nitric oxide— a vital molecule produced in your body and brain that not only impacts many potential benefits to your health, it can also be a component in deleterious oxidative stress reactions that are very damaging to your body and brain. Nitric Oxide Nitric oxide (NO) was first discovered in 1772 but it was not until 1987 that it was identified as an important signaling molecule that played a vital role in endothelium-dependent vasodilation in mammals. A few years later, in 1992, the journal Science nominated nitric oxide as the “Molecule of the Year” due to its role as a fundamental signaling agent in cardiovascular health and function. In the body and brain, NO can be synthesized by two distinct pathways. First, endogenous nitric oxide (NO) can be synthesized from the amino acid L. arginine (L-arginine-NO-synthase pathway) which is the initial upstream driver of cGMP activation in vasodilation. Remember that we started this overview by emphasizing the role of PDEis in blocking the degradation of cGMP. However, NO signaling is where cGMP activation begins. Additionally, another amino acid—L. citrulline—is metabolized from arginine and can be utilized in regeneration of arginine. Both amino acids are at the center of many studies which showcases their metabolism in vasodilation pathways. Nitric oxide may be also be derived from the intake and metabolism of foods rich in nitrate (nitrate–nitrite–nitric oxide pathway). Vegetables such as beets, celery, arugula and spinach, and fruits (e.g., strawberries) supply approximately 80%—85% of dietary nitrates in individuals that consume such foods regularly. Indeed, those foods are not only a terrific source of nitrate, they also are rich in many types of polyphenols which are key nutrients in protecting against oxidative stress pathways associated with nitric oxide metabolism. Many of you listening in or reading the transcript have likely become familiar with supplements using beets, or arginine and citrulline and other synergistic ingredients that have been heavily marketed to athletes as performance enhancers. In a clinical setting, these NO enhancing products are often used for ED and cardiovascular health support. Drugs (organic nitrates) are also well-known NO donors (e.g., nitroglycerin, amyl nitrite). Thus, NO can be produced from the precursors L. arginine and L. citrulline, or nitrates and nitrites that are either derived from foods, supplements and drugs. Another important understanding in all of this is that oral and gut bacteria convert dietary nitrate (NO3) to nitrite (NO2), and in the acidic stomach nitrite is further reduced to nitric oxide. NB, antiseptic mouthwashes inhibit nitrate to nitrite metabolism by eradicating oral bacteria, and proton pump inhibitors (PPIs) and antacids suppress stomach acid and nitrite to NO metabolism. To recap NO is an essential signaling and vasodilatory molecule secreted by vascular endothelial cells, which stimulates the production of cGMP (NO/cGMP Pathway) via activation of the receptor for cGMP— soluble guanylate (guanylyl) cyclase (sGC). Another important point about NO in women is that estrogen (E2) increases NO synthesis. Thus, the estrogen-NO dynamic is vital in vascular relaxation and endothelial-dependent vasodilation in women and should be included in any risk assessment for cardiometabolic and dementia risk in perimenopause or the earliest stage of menopause. In contrast, cardiovascular disease (CVD) risk factors such as excess belly fat, high blood pressure, insulin resistance and type 2 diabetes, glycation and chronic inflammation (inflammageing) disrupts endothelial function, promotes arterial stiffness, and blunts the synthesis of NO. Studies have shown that ED occurs in approximatelym35% to 75% of men with type 2 diabetes, and related studies have concluded that ED predicts future cardiovascular events. Additionally, CVD risk factors upregulate the formation of an arginine metabolite—ADMA (asymmetric dimethylarginine)—that inhibits vascular NO production (eNOS uncoupling). ADMA impairs vascular endothelial function and increases vascular oxidative stress (NO-ONOO cycle), and elevated ADMA has been linked to CVD in many studies. See image below. A useful assessment in analyzing the underlying factors associated with cardiometabolic disease such as atherosclerosis is the serum arginine/ADMA ratio which provides information on arginine bioavailability for production of NO. So, to summarize, the integrity of NO-sGC-cGMP Pathway is critical to signaling and vasodilation mechanisms that are essential to blood flow and vascular/endothelial homeostasis. Healthy endothelial function and NO levels is critical in the normal function of many vital organ systems including the cardiovascular and cerebrovascular system (neurovascular system), and the respiratory and renal systems. Indeed, a healthy endothelium is a fundamental cornerstone to living younger, longer. For a more thorough overview of the neurovascular system, please listen in to episode #16 titled: “Brain Detoxification-Part 1-The Role of the Blood Brain Barrier and The Glymphatic System” here on this channel. NO-PDE5i Brain Benefits But what about the role of PDE5is in all of this? Is there a role for PDE5i therapy in preventing cognitive decline? Would the PDE5i—sildenafil, or other PDE5 inhibitors, impart the same benefits on brain and cognitive health as healthy levels of NO does? Previous studies have shown that low dose sildenafil activates signaling pathways which suppresses the processing and generation of beta-amyloid and tau protein aggregates. Additionally, PDE5 inhibition mediated benefits include: induces cellular antioxidant levels, blunts neuroinflammation, and stimulates the production of new mitochondria (mitochondrial biogenesis) Now, is there a world where the combined therapy of NO and PDE5i therapy exists? Only a handful of recent studies have shown that supplemental citrulline or arginine therapy in combination with a PDE5 inhibitors could be a synergistic and therapeutic alternative to PDE5i monotherapy for severe ED and pulmonary hypertension. Overall, combination therapy was superior to monotherapies. No such combination studies that investigated PDE5 inhibitors with citrulline or arginine therapy in the risk for late-onset Alzheimer's disease (LOAD) have been undertaken. Bottom line, given the lack of research that includes the multiple pathways of NO metabolism and its role in endothelial function, the investigation into Viagra or any other PDE5i in the risk reduction for LOAD is grossly incomplete. And that answers the unfinished Viagra and Cialis story as a viable treatment for cognitive impairment or Alzheimer's as the NIH studies on Viagra and Cialis just did not go deep enough into interrelated mechanisms that intersect with the PDE5 enzyme. However, key nutrients, nutraceuticals and herbs are well-known NO precursors and PDE5 inhibitors, and they also protect against the upregulation of NO and the pro-inflammatory pathways and oxidative stress cascades associated with excess NO production. Without a doubt, dietary, nutrient and botanical/herbal extracts are vital interventions in an optimal heart-brain health protocol. More on that below after this brief overview on the glycocalyx. The Glycocalyx (preview) I must add that any overview on NO in vascular and endothelial health is incomplete without an overview on the glycocalyx—a gel-like thin protective layer covering present on endothelial cells which maintains the endothelial barrier. In fact, almost every cell in the human body, including bacteria, are covered by a glycocalyx layer. And yes, the role of a glycocalyx layer in bacteria is another story. The degradation of the endothelial glycocalyx layer in aging and cardiovascular disease significantly reduces endothelial cell production of NO, and collectively these interactions are a major and underlying factor in cardiovascular AND neurovascular disease. I have been closely following the emerging research with regard to the glycocalyx over the past 5 years, and the evidence that you cannot have a healthy-heart-brain axis without a vibrant endothelial glycocalyx is compelling. Case in point, the recent studies that have demonstrated the importance of the glycocalyx in vascular/endothelial health have established a new and critical insight into the treatment and potential reversal of atherosclerosis. Nutrition-Diet (preview) A host of nutrients, nutraceuticals and herbs are well-known NO precursors and PDE5 inhibitors. First, apart from arginine and citrulline, vitamin C, E and D are core nutrients in NO-mediated endothelium-dependent relaxation. Recently, vitamin K2-MK-7 studies have also been linked to enhanced NO-dependent endothelial function. Glutathione has been shown to be an essential and protective antioxidant in modulating NO reactivity and protecting against the damaging NO-ONOO cycle. Glutathione and glutathione-based enzymes detoxifies peroxynitrite (ONOO)—a reactive nitrogen species, and improves nitric oxide bioavailability and endothelial function. And, tetrahydrobiopterin (BH4) is a key enzymatic cofactor required for the synthesis of several neurochemicals—serotonin, dopamine and NO. Additionally, polyphenols and in particular flavonoids, are the most the most frequently reviewed and studied phenolic NO precursors and PDE5 inhibitors, and they support the integrity of the glycocalyx structure and function. So many nutrients to make a case for including the phytoestrogenic benefits of many flavanoids, but here is an abbreviated list of the most cited plant/herbal derivatives and nutrients: Resveratrol Quercetin Catechins, epicatechin (e.g.,green tea) Pine bark (Pycnogenol®) and grape seed extracts (GPSE) Isoflavones (e.g. genistein) Hawthorne (Crataegus species) Icariin (Epimedium brevicornum) Aged garlic extracts Pomegranate extracts Gingko biloba Black ginger (kaempferia parviflora) Xanthones (Anaxagorea luzonensis) And, all the nitrate/flavanoid-rich foods including beets, spinach/leafy greens, and celery, pomegranate, berries, cherries, citrus, garlic, dark chocolate and many others. Of course, a low-carbohydrate Mediterranean diet or Mind Diet lifestyle is rich in polyphenols and other heart and brain health nutrients. In addition, exercise training and caloric restriction promotes NO activity and endothelium-dependent vasodilation through activation of eNOS. Additional points covered in this episode's audio file… NO Synthesis (preview) Now, I'll briefly describe how NO is synthesized as there are principal pathways that illustrate key and elemental features of NO metabolism—good and bad. The NO-cGMP pathway is in part regulated by the activity of a family of enzymes—nitric oxide synthases that regulate nitric oxide (NO) synthesis. There are three NOS enzyme synthases—neuronal (nNOS), endothelial (eNOS), and inducible (iNOS). iNOS driven NO production is associated with immune system responses to various stimuli such as infections, and NO can either function as a regulator of such responses, or excessive production of NO by iNOS can upregulate those pathways in a destructive manner. Nitric Oxide-S-nitrosylation (preview) I want to add another important feature of NO metabolism with regard to the risk for LOAD. And that is the physiological and pathophysiological role of another NO reaction that takes place in the body and brain which is termed S-nitrosation, or S-nitrosylation. I was not planning on adding this to this episode, but a recent research study just published reported that a S-nitrosylation pathway was a risk factor in Alzheimer's disease in women. S- nitrosylation is the bonding of NO to sulfur compounds on amino acids such as cysteine. In a recent study finding reported on just a few days ago—December 14, 2022, the elevated S-nitrosylation modification of an immune system protein known as complement component C3 (SNO C3) was present at much higher (six-fold) levels in the brains of women who had died of Alzheimer's, compared to men who had died with the disease. The postmortem brain research that was conducted at Scripps Research and Massachusetts Institute of Technology (MIT) also reported that declines in estrogen, which normally serves as a neuroprotective hormone, was likely a strong factor in the generation of the SNO-C3 form of complement C3. Cured Meats (preview) Another key factor to weigh into this overview with regard to diet, nitrates, nitrites and NO, are cured meats. In fact, some of you may be anticipating this section of the overview by now as there is considerable concern and media dissemination of the potentially deleterious role of nitrates and nitrites used in various types of processed meat products such as bacon, sausages and other “deli meats”. In fact, many studies have explored the risk of nitrate and nitrite added to various foods as their metabolism under certain conditions can potentially convert into a toxic nitrosamines (N-nitroso compounds) That's it for this summary and as always, thank you for listening in or taking the time to read the summary . Please do listen in to hear the rest of the story. God bless and goodbye. BrainDefend® Ralph Sanchez, MTCM, CNS, D.Hom. https://www.TheAlzheimersSolution.com https://www.facebook.com/TheAlzheimersSolution/ https://www.linkedin.com/in/ralph-sanchez/ https://www.instagram.com/alzheimers_solution/ https://twitter.com/RalphSanchez
Do the Words: Boundaries and NO create Anxiety, afraid you'll make others' mad? Girl, someone is gonna be mad; it's either YOU or THEM. Tips to Staying True to You. In this episode, we talk about Boundaries:1. How to Establish Them2. What happens when you DON"T say No3. Tips to Becoming an Advocate for You, Your Family4. Consequences 5. TransformationOh, it's chopped full of actionable steps, resources, and all the goodness. Check it out. RESOURCES:Dr Henry Cloud: Boundaries & Necessary EndingsShelley Tyson:: IG Shelley C. Tyson: Cultivate Legacy PodcastEphesians 2:10Glennon Doyle: UntamedStacy Fayling: She Wakes Up PodcastLysa Terkeurst: Best YesStephanie's Bio:Stephanie Pletka is a motivational speaker, author of Living Your Best Life and radio show host of Motherhood Mindset on Faith Talk Radio 1360 in Phoenix. She produces a weekly podcast to help women navigate the messy parts of motherhood.Get ready for entertaining stories and 3 actionable steps to finding the goodness in the hard places. It's time to be encouraged to chase your dreams and write your story.Grab a copy of Living Your Best Life or download your audible for moms on the go.Subscribe to stephaniepletka.com for mom hacks, tips and upcoming events.@stephaniepletka IGSee omnystudio.com/listener for privacy information.
En el capítulo de hoy profundizamos en el abonado del acuario, concretamente del nitrato (NO3). El nitrato es uno de los macro-nutrientes que más consumen nuestras plantas. Se forma a partir de los desechos del acuario mediante un proceso conocido como ciclo del nitrógeno. La mayoría de los aficionados a los acuarios plantados suelen tener... (continúa leyendo)
It turns out that the juice from beets may lower blood pressure in a sustained and lovely manner. Beets, you see, besides being a colorful vegetable, contain a high level of Nitrate (NO3-). And this is absorbed by the body and converted into nitric oxide. Nitric oxide is that amazing molecule that relaxes blood vessels and improves blood flow. How Your Body Gets Nitric Oxide The conversion of nitrate into nitrite, which is then converted into nitric oxide is a fun pathway. When you eat your greens (yes even lettuce has nitrates) your intestines absorb it and then it is secreted back into saliva where those bacteria in your mouth digest the nitrate (NO3-) into nitrite (NO2-)
Kathleen opens the show drinking a Cosmic Cowgirl from Diebolt Brewing in Denver. She reviews her weekend in Denver filming her upcoming Amazon Original Special at the Paramount Theatre, which is one of her favorite places to do shows. She talks about eating breakfast at Sam's No3 and hanging out with her good friend and surprise opening act, the iconic George Wallace. “GOOD BAD FOOD”: In her quest for new and delicious not-so-nutritious junk food AND in continuing her search for the best Ranch, Kathleen samples Boulder Canyon Classic Sea Salt kettle chips, which she thinks have a terrific crunch. She then samples Dale's Wild West Elk Jerky, and she loves the salty taste. She finishes her tasting with Old El Paso Zesty Ranch Sauce, which she doesn't think tastes anything like Ranch but offers that it might be ok on tacos. QUEEN'S COURT: It has been a quiet week for the Court, but Kathleen shares that her friend Kathe saw Tanya Tucker in North Carolina last weekend and thinks that Queen Tanya's live show is better than ever.UPDATES: Kathleen gives updates on the opening of ABBA's Voyage avatar concert series in London, another Russian oligarch's super yacht is seized in a UAE creek, Anna Delvey defrauds another “friend,” Elon Musk has issued a back-to-the-office ordinance and “the children” revolt, and the world's oldest man celebrates his 113th birthday in Venezuela. “HOLY SHIT THEY FOUND IT”: Kathleen is amazed to read about the discovery in Alabama of the largest prehistoric cave drawings ever found in North America, and a 2,100 year old farmstead found “frozen in time in Israel. RUSSIAN SUPERYACHTS VANISHING FROM GLOBAL TRACKING: In maintaining her obsession regarding crushing the power of Russian oligarchs, Kathleen reads an article stating that superyachts linked to sanctioned Russian oligarchs are vanishing from global tracking systems in an attempt to avoid sanctions, according to an investigation by The Observer. PROTESTERS GONE WILD: Kathleen continues with her reporting on crazy protesters, reading about 2 recent protest actions: a French Open tennis protester ties herself to the Center Court net during the men's semifinal, and the Mona Lisa was smeared with cake in an apparent climate protest. MAN DRESSES AS COLLIE TO BECOME A DOG: Kathleen is baffled reading an article about a Japanese man who spent more than $15,000 to fulfill his dream of transforming into a four-legged animal. The man, known only by his Twitter username, Toco, spent 2 million Japanese yen, or about $15,700, to create a lifelike rough-collie costume that he could inhabit.POST OFFICE VACANCY IN ANTARCTICA: Kathleen thinks she knows a few Termites who would jump at the chance to take a job running the world's most remote post office in Antarctica. The post is at Port Leroy, and responsibilities include counting penguins and running the gift shop. MCDONALD'S AND STARBUCKS LEAVE RUSSIA: Kathleen reads announcements that McDonald's is leaving Russia, with the stores being sold and will continue to operate under a new proposed brand name called “Fun and Tasty.” She also reads that Starbucks is leaving the Russian market, following McDonald's move. GALLERY OWNER CHARGED WITH COUNTERFEIT ART SALES: Kathleen loves the fine art world, and is enthralled with an article about a Florida gallery owner who has been charged with selling fake Banksy, Warhol, and Basquiat paintings to rich Palm Beach buyers. AMERICA'S LAST HOWARD JOHNSON'S RESTAURANT CLOSES: Kathleen reads an announcement that the last surviving Howard Johnson's restaurant has closed, which was located in Lake George NJ. WHAT TO WATCH THIS WEEK: Kathleen recommends watching “Under the Banner of Heaven” on Hulu. SEE KATHLEEN LIVE: See Kathleen live on her “Do You Have Any Ranch?” Tour. Tickets available at kathleenmadigan.com/tour See Privacy Policy at https://art19.com/privacy and California Privacy Notice at https://art19.com/privacy#do-not-sell-my-info.
Study finds Mediterranean diet improves depression symptoms in young men and women University of Technology, Sydney, May 9, 2022 Young adults with a poor diet saw a significant improvement in their symptoms of depression when they switched to a healthy Mediterranean diet, a new study shows. The 12-week randomized control trial, conducted by researchers from the University of Technology Sydney, was recently published in The American Journal of Clinical Nutrition. The study contributes to the emerging field of nutritional psychiatry, which aims to explore the effect that specific nutrients, foods and dietary patterns can have on mental health. The diet used in the study was rich in colorful vegetables, legumes and wholegrains, oily fish, olive oil and raw, unsalted nuts. The primary focus was on increasing diet quality with fresh wholefoods while reducing the intake of 'fast' foods, sugar and processed red mea. "There are lots of reasons why scientifically we think food affects mood. For example, around 90 percent of serotonin, a chemical that helps us feel happy, is made in our gut by our gut microbes. There is emerging evidence that these microbes can communicate to the brain via the vagus nerve, in what is called the gut-brain axis. To have beneficial microbes, we need to feed them fiber, which is found in legumes, fruits and vegetables," they said. Amaranth extract goes head to head with beet as nitrate source Arjuna Natural (India), May 6, 2022 A number of studies have established that nitrate, a nitric oxide metabolite, is beneficial for endurance during exercise. However, this bioavailability study, published in the journal Nutrition, was the first clinical trial to show that extract of amaranthus - one of the sources of nitrite in nature - can help athletes work out longer and harder. The researchers found that a single (2g) dose of amaranth extract was able to increase nitrate (NO3) and nitrite (NO2) levels in the body for at least eight hours. Until now, sports nutrition manufacturers have typically incorporated beetroot powder and juice into formulations in order to support nitrate levels. These findings give this market a new, more potent form of nitrate to work with, according to botanical extracts manufacturer Arjuna, whose interest in amaranthus stems from its traditional use in Indian medicine and cooking. By comparison, he said that amaranthus was a far more “potent” form of nitrate for sports nutrition applications. “It's standardised to 9-10% nitrate content, whereas most beet-based ingredients contain less than 2% nitrate,” he told NutraIngredients. Arjuna attributes this to its patent production process, which extracts 9,000mg per 100g of nitrate from the leaves of the amaranthus species. Another advantage over its beet-based counterparts is that it doesn't contain any reducing sugars and oxalates. Study identifies exact amounts of extra vitamin C for optimal immune health University of Otago (New Zealand), May 6, 2022 If you are carrying a few extra kilos in weight, an extra apple or two per day might make a difference in boosting your immune system and helping ward off COVID-19 and winter illnesses. New University of Otago research has identified, for the first time, exactly how much extra vitamin C humans need to ingest, relative to their body weight, to maximize their immune health. The study has found that for every 10 kilograms of excess weight a person carries, their body needs an extra 10 milligrams of Vitamin C daily, which will help to optimize their immune health. "Previous studies have already linked higher body weight with lower vitamin C levels," says lead author Associate Professor Carr. "We know obesity is a risk factor for getting COVID-19 and that obese patients are more likely to struggle to fight it off once infected. We also know that vitamin C is essential for good immune function and works by helping white blood cells fight infection. The results from this study therefore suggest that increasing your vitamin C intake if overweight might be a sensible response. Pneumonia is a major complication of COVID-19 and patients with pneumonia are known to be low in vitamin C. The study determined how much vitamin C is required for people of higher body weight compared to a starting base weight of a 60 kilogram person consuming the average New Zealand dietary vitamin C intake of 110 milligrams per day, which most people achieve from a balanced diet. Vitamin A deficiency is detrimental to blood stem cells German Cancer Research Center, May 5, 2022 Many specialized cells, such as in the skin, gut or blood, have a lifespan of only a few days. Therefore, steady replenishment of these cells is indispensable. They arise from so-called "adult" stem cells that divide continuously. In addition, there is a group of very special stem cells in the bone marrow that were first discovered in 2008 by a research team led by Andreas Trumpp, who is a division head at the DKFZ and director of HI-STEM. These cells remain in a kind of dormancy most of the time and only become active in an emergency such as bacterial or viral infections, heavy blood loss, or in the wake of chemotherapy. Once their work is done, the body sends its most potent stem cells back to sleep. The scientists assume that this protects them from dangerous mutations that may lead to leukemia. The scientists have now identified retinoic acid, a vitamin A metabolite, as a crucial factor in this process. If this substance is absent, active stem cells are unable to return to a dormant state and mature into specialized blood cells instead. This means that they are lost as a reservoir. This was shown in studies with specially bred mice. "If we feed these mice on a vitamin A deficient diet for some time, this leads to a loss of the stem cells," said Nina Cabezas-Wallscheid, who is the first author of the publication. "Thus, we can prove for the first time that vitamin A has a direct impact on blood stem cells." Exposure to wildfires increases risk of cancer McGill University (Quebec), May 9, 2022 A new study from McGill University finds higher incidence of lung cancer and brain tumors in people exposed to wildfires. The study, which tracks over 2 million Canadians over a period of 20 years, is the first to examine how proximity to forest fires may influence cancer risk. "Wildfires tend to happen in the same locations each year, but we know very little about the long-term health effects of these events. Our study shows that living in close proximity to wildfires may increase the risk of certain cancers," says Scott Weichenthal, at McGill University. The study shows that people living within 50 kilometers of wildfires over the past 10 years had a 10% higher incidence of brain tumors and 4.9% higher incidence of lung cancer than people living further away. Curcumin improves intestinal barrier function: modulation of intercellular signaling Virginia Commonwealth University, May 5, 2022 Studies from Virginia Commonwealth University Describe New Findings in Curcumin improves intestinal barrier function According to news, research stated, "Association between circulating lipopolysaccharide (LPS) and metabolic diseases (such as type 2 diabetes and atherosclerosis) has shifted the focus from high-fat high-cholesterol containing Western- type diet (WD)-induced changes in gut microbiota per se to release of gut bacteria-derived products (e.g., LPS) into circulation due to intestinal barrier dysfunction as the possible mechanism for the chronic inflammatory state underlying the development of these diseases. We demonstrated earlier that oral supplementation with curcumin attenuates WD-induced development of type 2 diabetes and atherosclerosis."T The research concluded: "The major site of action of curcumin is, therefore, likely the intestinal epithelial cells and the intestinal barrier, and by reducing intestinal barrier dysfunction, curcumin modulates chronic inflammatory diseases despite poor bioavailability." Videos: 1. Brazil's Lula proposes creating Latin American currency to ‘be freed of US dollar' dependency (part 2) (10:00) 2. Elon Musk Blasts Soros 'Dark Money Groups' Threatening Twitter Advertisers (14:13)
my-fish.org – Aus Freude an der Aquaristik (Aus Freude an der Aquaristik Podcast)
In der heutigen Solo-Episode geht es um das Thema “Der Stickstoffkreislauf im Aquarium – Ammonium (NH4), Nitrit (NO2) und Nitrat (NO3)”. Dass ein Aquarium erst einlaufen muss, erfahren wir Aquarianer direkt beim ersten Aquarium. Zwei bis drei Wochen ohne Fische, heißt es, damit sich die wichtigen Bakterien bilden können und später das notwendige Gleichgewicht im Wasser vorliegt. Aber was genau passiert in dieser Zeit und wofür wird es gemacht? Der sogenannte Stickstoffkreislauf sorgt dafür, dass der Abbau der Ausscheidungen der Fische und die anfallende Arbeit mit dem Stoffwechselprodukt Ammonium reibungslos vonstatten geht. Das bedeutet, dass Ammoniak zu Nitrit und dann zu Nitrat umgearbeitet wird, welches von den Wasserpflanzen aufgegessen werden kann. Der Überschuss ist harmlos und kann bis zum Wasserwechsel im Aquarium verbleiben und mit dem Austausch entfernt werden. Wie aber sieht dieser Stickstoffkreislauf im Detail aus? Was kannst du tun, wenn dieser gestört ist und was hat es mit NH4, NO2 und NO3 im Detail auf sich? Dieses und einiges mehr erfährst du in der heutigen Episode. ________________________________ Wenn du zufrieden warst, freuen wir uns über eine Bewertung. Kennst du jemanden, der ebenfalls eine interessante Erfolgsstory hat? Schreib uns eine Email an podcast@my-fish.org . ________________________________ Erwähnte Links und Begriffe in der Episode AQUaddicted erklärt den Stickstoffkreislauf: https://my-fish.org/aquaddicted-video-tipp-der-naehrstoffkreislauf-nitrat-nitrit-ammonium/ Ratgeber: Die Wasserzusammensetzung: https://my-fish.org/anfanger-einstieg/der-my-fish-anfanger-einstieg/die-wasserzusammensetzung/ Kids Ratgeber: Alles rund ums Wasser: https://my-fish.org/kids/weiches-oder-hartes-wasser-die-wasserwerte-im-blick-%E2%80%A8/ Zusätzliche Bilder und die vollständigen Shownotes findest du unter www.my-fish.org/episode320
Tension grows between allies and rivals alike… just not the same kind. As the Erenhall plot is set into motion, Zinkus and Celia craft a plan of their own. Transcript can be found here: https://docs.google.com/document/d/1dW_UnW7izbaabXdWhps_6OcdaKSH2yRcI8BpegqQ3ek/edit If you loved the episode, come chat with us on Twitter, Instagram, Facebook, and tiktok @forgetmenotspod. Additionally take a second to rate, review, and subscribe. If you want to help keep this ship afloat support us on ko-fi @forgetmenotspod. We will be doing personal shoutouts for anyone who donates! Content Warnings: This episode features discussion of depression and anxiety related to academics and is heavier than most of our episodes. Please take care of yourself as you listen! Other content warnings include: Academic stress Expulsion from school Self deprecation Arguing Violence on school property Ornithophobia Magical curse with disease-like spread Mentions of: imprisonment, death SFX: crowds screaming, distorted mechanical vocals, explosions, breaking glass, electrical zapping The Team: Cady Bailey: creator, lead writer and co producer Gaby McDonald: editor, sound designer, and co producer Molly Borowiak: writer. This episode starred: Rory Eggleston as Zinkus McGee Cady Bailey as Celia Nunally Ashley Ericson as Retta Mendenhall Mac Gagne as Iroya Meldin Molly Borowiak as Gisella Sylstara Aidan Iannarino as Corwin Notely and Tyvold Erenhall Adam Lambert as Dorian Alder Tess Redman as The Mechanical Waiter and Madame Decourtaire Sophie Caplin as Carlotta Mendenhall Mallory Hillary as The Attendant With additional audio from Cameron Sterling, Ashley Ericson, Gaby McDonald, and Cady Bailey Music in this episode Halvorsen Passacaglia for Violin and Viola from musopen.org https://musopen.org/music/19768-passacaglia-for-violin-and-viola/ Brahms Clarinet Trio in A minor, Op. 114 performed by Paul Pitman Michael Arnold and Bang Eun Lee https://musopen.org/music/6756-clarinet-trio-in-a-minor-op-114/ Danzi Wind Quintet Op 67 No3 in E-flat Major, 4 Allegretto performed by the Soni Ventorum Wind quintet https://freemusicarchive.org/music/Soni_Ventorum/Franz_Danzi_Wind_Quintet_Opus_67 Tchaikovsky- Swan Lake performed by Kassia https://youtu.be/vAeRzW98IFw Sounds used in this episode: Zapsplat heel pack “Opening and Closing Curtains” by 211003 https://freesound.org/people/21100375/sounds/593139/ “Garden” by richwise https://freesound.org/people/richwise/sounds/497422/ “Crowdpanic” by belthazarus https://freesound.org/people/belthazarus/sounds/435716/ (crowd screaming) “Drum4” by zerolagtime https://freesound.org/people/zerolagtime/sounds/106603/ “Metal Drag Short” by belanhund https://freesound.org/people/belanhud/sounds/543625/ “enticelle-spark” by therover https://freesound.org/people/therover/sounds/549878/ “Bike, chain spinning, fast 02-01” https://freesound.org/people/InspectorJ/sounds/484470/ “Foley_Impact_Metal_Long_Mono” by Nox_Sound https://freesound.org/people/Nox_Sound/sounds/569555/ “Crowd in panic” IENBA https://freesound.org/people/IENBA/sounds/491405/ “drum9” by zerolagtime https://freesound.org/people/zerolagtime/sounds/106609/ “Woman scream of joy111” by GabrielaUPF https://freesound.org/people/GabrielaUPF/sounds/220295/ “Welder sparks good detail1 short weld” by kyles https://freesound.org/people/kyles/sounds/453689/ “Stepping on a can” by mars_98 https://freesound.org/people/mars_98/sounds/445044/ “glass_tinkling_211106-120037_pitch” but genel https://freesound.org/people/genel/sounds/611674/ “Steam Hiss” by jesabat https://freesound.org/people/jesabat/sounds/119741/ “Locker slam1” by chripei https://freesound.org/people/chripei/sounds/393659/ “Tearing, Newspaper B” by InspectorJ https://freesound.org/people/InspectorJ/sounds/415766/ “RippingCloth5” by klangkonserve https://freesound.org/people/klangkonserve/sounds/172629/ “Fluorescent lights shutting down” by FreqMan https://freesound.org/people/FreqMan/sounds/25864/ “Running Past” by edwar64896 https://freesound.org/people/edwar64896/sounds/250940/ (crowd running past) As well as previously credited sounds
Another MOM for David de Gea and a quite ridiculous 100 clean sheets for Ederson in just 212 Man City outings. All the reaction from the weekend's goalkeeping goodness is rounded up in the following audio, including a look at top-flight clubs currently without a recognised No3. As we've seen with Southampton hastily signing Willy Caballero on a short-term deal last week, opting against an established back-up could prove costly.
Heidi J. Ellsworth visits with Ben Rucka, District Manager with Malarkey Roofing Products about the important trend of using roofing materials to battle smog. All Malarkey shingles include 3M™ Smog-Reducing Granules. These granules, which blend inconspicuously into the shingle's color, contain a photocatalytic coating which, when activated by the UV rays of the sun, creates the energy needed to begin the process of breaking down dangerous, inhalable gas (NO2) into a water-soluble nitrate salt solid (NO3), a plant usable form of nitrogen that washes away with rainwater as a mild fertilizer. Ben and Heidi discuss the importance of the new science of roofing and how Malarkey shingles help actively reduce emission-based air pollution equivalent to planting 2 trees per roof.
Các chu trình nitơ (chu kỳ sinh học hoặc quá trình nitrat hóa) là quá trình quan trọng nhất trong hồ cá. Khi chúng ta nói về nó, chúng ta đề cập đến sự hình thành của các khuẩn lạc vi khuẩn có lợi (vi khuẩn nitrat hóa) chuyển đổi amoniac (NH3) thành nitrit (N02-) thành nitrat (NO3-) . Về cơ bản, đây là cách tự nhiên để tái chế chất dinh dưỡng.. Xem chi tiết tại: https://nuoitep.com/thuy-sinh/moi-thu-ve-vinh-sinh-trong-be-ca-tep-cua-ban.html
Các chu trình nitơ (chu kỳ sinh học hoặc quá trình nitrat hóa) là quá trình quan trọng nhất trong hồ cá. Khi chúng ta nói về nó, chúng ta đề cập đến sự hình thành của các khuẩn lạc vi khuẩn có lợi (vi khuẩn nitrat hóa) chuyển đổi amoniac (NH3) thành nitrit (N02-) thành nitrat (NO3-) . Về cơ bản, đây là cách tự nhiên để tái chế chất dinh dưỡng.. Xem chi tiết tại: https://nuoitep.com/ru/%d1%82%d1%83%d0%b8-%d1%88%d0%b8%d0%bd%d1%8c/moi-thu-ve-vinh-sinh-trong-be-ca-tep-cua-ban.html
In Ep183 I introduced you to the 7 brand messages that build influence and impact. In brand message No3. I spoke about the importance of sharing your “Creation Story” When you share your “creation story” it brings context and meaning to your brand. You can do this by letting your community know: Who are you? Where did you come from? Why do you do what you do? In this episode I'll share the essential ingredients of an effective “creation story”. You'll learn where to tell your story and how long it should be….and loads more. Nailing your creation story will super charge your marketing! Enjoy the show. Thanks for all you do. Keep saving lives. Angus See omnystudio.com/listener for privacy information.
Puntata in vista dell'estate: meno di un'ora, con tante ragazze e a tema spiaggia. Quali sono i giochi che vi portereste sul bagnasciuga quest'anno? Ce ne parlano Vania, Laura "Nymeria" e Noemi "No3". Conduce Salvatore "sava73". Regia di Michael "volmay".
Nitric oxide benefits your heart and enhances performance. Interestingly, nitric oxide levels are increased by a dietary substance that's often demonized as a cancer and cardiovascular disease-causing compound: nitrate. Nitrate, found in some vegetables and processed meats, looks like it offers much more benefit than risk. Here's what you need to know about nitrate (NO3), nitrite (NO2), and nitric oxide (NO). What are nitrate, nitrite, and nitric oxide? In health and nutrition circles, nitrates and nitrites often have a bad reputation. No doubt, you've heard that processed and cured meats are bad because they contain preservatives, including nitrates and nitrites. Unfortunately, they're demonized based on correlation, not causation. Many studies associate processed meats with an increased risk of heart disease and cancer. However, correlation does not prove causation. The studies cannot prove that the processed meat causes heart disease and cancer. They only show that people who eat a lot of such foods get cancer and heart disease more often. It could be other factors in their diet and lifestyle. Before refrigeration, curing meats allowed people to eat a much healthier, higher-protein diet than they could have if they couldn't have preserved meat. Interestingly, a significant amount of research shows that nitrate-rich vegetables offer health benefits. Yet, your body responds to nitrate in processed meats just as it does in vegetables. I'm not suggesting people skip vegetables altogether and eat Jack Link's jerky every day. I only point it out so that those who make nutrition recommendations to the public don't mislead people into believing jerky is poison while beetroot is a superfood. Nitrate metabolism When you eat nitrate-rich foods, your salivary glands and bacteria on your tongue convert nitrate (NO3) to nitrite (NO2). As NO2 moves through your digestive tract, your stomach converts some nitrite to nitric oxide (NO). Most nitrite gets absorbed as-is and enters your circulation, where other enzymes convert nitrite to NO. Nitric oxide, then, plays an essential role in: vasodilation, which enhances blood flowmuscle contractionangiogenesismitochondrial respirationmitochondrial biogenesisglucose uptakecalcium balance, which affects muscle contraction You can also increase nitric oxide levels by supplementing with the amino acids l-arginine or l-citrulline. Nitrate consumption The acceptable daily intake (ADI) is 3.65 mg/kg body weight. However, some studies use almost double that amount when looking at the ergogenic benefits. About 80% of nitrate consumption comes from vegetables, but they can be found in everything from leafy greens to lunch meat. The following are common dietary sources of nitrates: Dietary Nitrate SourcesBaconBeef, turkey, elk, or other jerkyBeetrootBolognaCorned beefGrainsHamHotdogsLeafy greens (lettuce, spinach)Lunch meatMustard greensNutsOilseedsSalamiSausageTubers Health Benefits Contrary to popular belief, nitrate consumption is safe and even essential for health. The following are the most well-known health benefits of nitrate consumption and increased NO levels. Improved endurance Nitrates, such as those found in green leafy vegetables, beetroot, or beef jerky, dilate blood vessels, increasing blood flow and lower blood pressure. The decreased pressure may relieve symptoms of angina pectoris and congestive heart failure. A 2007 study (Larsen et al.) assessed the effect of sodium nitrate supplementation on cycle performance. Supplementation reduced oxygen demand during exercise, which means the study men could do the same amount of work while expending less energy. In a 2009 study (Larsen et al.), a group of men consumed a beetroot supplement or a placebo. Beetroot contains a high concentration of nitrate. Supplementation again reduced oxygen consumption like in the previous study. Also,
久違的『Pei你認識食品業』!今天特別邀請到之前在美國功夫茶麻州總部做行銷和PR的Bella,來跟我們聊聊在美國手搖飲內部工作的內容,會遇到什麼挑戰,怎麼在美國當地做行銷。這集節目也會讓我們更認識美國功夫茶這個品牌,還會介紹一些內行人的菜單,我很喜歡這集的內容,一起來聽聽看吧! Bella推薦的飲料: No1. Rosehip Milk Tea (薔薇果奶茶) No2. Pina Colada Slush (鳳梨椰香冰沙) No3. Oolong Milk Tea with Wow Bubble (烏龍奶茶加黑糖珍珠) 聽完真的好想喝! Instagram: @peipeitalks Website: peipeitalks.com Powered by Firstory Hosting
On February 18, 2021, my friend + art instructor, Naomi Conner of NVE Art Studio, joined me and my CAMP community for an Artist Chat. We talked about where to find inspiration, when it's okay and when it's NOT okay to copy other artists' work, and how to share your creativity with the world especially when you are terrified to put yourself out there. Support the show (https://www.paypal.me/joannetlauzon)
los diseñadores Maximiliano Interian, Lola Lolisima, Luis Sánchez Piñata nos acompañan en nuestro programa No3 de Mano A Mano, no te lo puedes perder #Carnaval2021 #CarnavalEnCasa #Quintana Roo #Al Aire #ManoAmano
If you haven't drunk the Kool-aid and worked out at an F45, sweating and gasping for air, you're missing out on the workout of the generation. We're talking high-intensity interval training, or HIIT. Some say it's awful and vow never to do it again. Others get quickly addicted and claim it's the best thing they've ever done for their bodies, turning back to steady-state cardio to keep their energy balance in check. So who's right?In this episode of Wellness: Fact or Fiction, we dive into:1. What exactly constitutes steady-state cardio vs high-intensity interval training2. What each type of cardio does biologically3. Which type of cardio burns fat most efficiently4. Why a blend of both high- and low-intensity exercise is the best system of cardiovascular training.Have questions / comments? Come stalk us on Social Media!Podcast: @wellnessfactorfictionSal: @thefitfoodieblogShauna: @shaunashauna_References:Fallahi, A., Gaeini, A., Shekarfroush, S., & Khoshbaten, A. (2015). Cardioprotective Effect of High Intensity Interval Training and Nitric Oxide Metabolites (NO2 (-), NO3 (-)). Iranian journal of public health, 44(9), 1270–1276.Foster, C., Farland, C. V., Guidotti, F., Harbin, M., Roberts, B., Schuette, J., Tuuri, A., Doberstein, S. T., & Porcari, J. P. (2015). The Effects of High Intensity Interval Training vs Steady State Training on Aerobic and Anaerobic Capacity. Journal of sports science & medicine, 14(4), 747–755.Keating, S. E., Johnson, N. A., Mielke, G. I., & Coombes, J. S. (2017). A systematic review and meta-analysis of interval training versus moderate-intensity continuous training on body adiposity. Obesity reviews : an official journal of the International Association for the Study of Obesity, 18(8), 943–964. https://doi.org/10.1111/obr.12536Why Should You Do HIIT Cardio — and What Is It? A Trainer Explains. POPSUGAR Fitness Australia. (2021). Retrieved 7 January 2021, from https://www.popsugar.com.au/fitness/What-HIIT-Cardio-45876316.Sal's book recommendations:The One Minute Workout, Martin Gibala
Which end is in sight for Colorado restaurant owners? The end of the pandemic, or the end of their business? Colorado restaurant owners speak out about their business, employees, and the costly effects from the pandemic. We asked four Colorado restaurant owners the same four questions. Their answers tell us a lot about their determination, business model, and what they hope the future brings! These unprecedented times for restaurant and bar owners call for new ideas, pivoting, and more work than ever. Please help us support our local businesses and food and beverage community! Share this video if you love Colorado restaurants! Special thanks to Alex Armatas with Sam's No3, Erik Peterson with Bull and Bush Brewery, Chef Kevin Morrison with Tacos Tequila Whiskey and Fish N Beer, Jared Leonard with AJ's Pit Bar-B-Q, The Bud Long Hot Chicken, Grabowski's Pizzeria, and Campfire Evergreen
Exploration geologists are often faced with a situation where they are asked to find the Holy Grail with a small budget. In the past, potential deposits are often missed due to a lack of funding or poor targeting techniques. CSIRO has been providing solutions to the mineral exploration industry for many decades. The whole concept of understanding the weathering profile or regolith is the key to many discoveries. In this episode of Coffee with Samso, I speak to Ryan Noble who is the Principal Research Scientist for CSIRO. He works for the mineral resource business unit. Ryan shares with us the concept of using bore water to vector into potential mineralisation geology. This technique is being used with Moho Resources Limited (ASX: MOH). Ryan is working with Moho Resources on the Emperor Springs Gold Project in Queensland, Australia. About Ryan Noble: Current activities: Ultrafine fraction soils for mineral exploration, active/smart sampling for exploration, gas geochemistry for exploration through cover, commercialisation of UltraFine+, continental-scale hydrogeochemistry, rapid and field-portable sampling and analysis for greenfields mineral exploration, role of fungi in the transformation of gold. Past President of the Association of Applied Geochemists (Chair Awards and Medals Committee), Executive Board member of Earth Science Western Australia, Member of Geoconferences WA subcommittee. Sept 2011 -June 2014 Stream Leader (Education and Analytical Services) Responsibilities: Manage projects and project leaders, reporting, project delivery and the stream budget. Run seminars, Interns, promotion activities and develop Advanced Characterisation services. Aug 2011 - Oct 2014 Research Team Leader Responsibilities: Manage Aqueous Geochemistry research team members (5-8) for capability development and deployment, annual performance, HSE and routine approvals. Research Scientist and Laboratory Manager Projects: Uranium hydrogeochemistry, biogeochemistry and mechanisms of metal migration in soils, evolution of SO4 and NO3 related to sulfide weathering, monitoring techniques for carbon capture and storage in soil and groundwater, micro- and nano-crystal formation to simulate natural metal enrichment zones in soils and saprolite, regional hydrogeochemical mapping, hydrogeochemistry near trace metal-rich soils and rocks, predictive modelling of lithology using plant and soil chemistry, hydropedology of the WA wheat belt including studies on acid water and acid sulfate sediments, development and assessment of novel approaches to soil characterisation by soil partial extractions, reactive transport modelling of trace metal mobility related to saprolite weathering reactions. Skills: Laboratory management, General soils, regolith and water laboratory techniques, Ion Chromatography, Infrared Mineral Analyzer (ASD), C and S combustion analyzer, Scanning Electron Microscopy.
Martyn brings you the first "Time Capsule" where he aims to transport us back to the memorable events of our banding past. Steve Stewart of The Cory Band, recollects his part in another dominant ensemble of its time, Desford Colliery Band. A National win from a No3 draw was their fourth Albert Hall victory in a row, and one of the banding feats still talked about to this day.
As a Mum of 2 and another on the way, Dr. Laura Lenihan knows the anxieties and everyday concerns we go through as parents – but as a GP she has knowledge, information and insight into what we all need to know.In this episode we talk about how she balances her own anxieties as a mum knowing the risks and things that can wrong and how she is helping parents through her Instagram and website Dr Laura GP from antenatal info to the corona virus, contraceptive options to bringing your babies temperature down – she is giving everymum access to key information so we can feel more empowered and follow the right medical advice.With only a few months left until baby No3 we talk about being outnumbered, her pregnancy wellbeing, skincare for tired eyes and balancing medicine and motherhood.Join our everymum community today, and follow everymum on Facebook and Instagrameverymum the podcast is proudly supported by WaterWipes See acast.com/privacy for privacy and opt-out information.
Jared Kushner's North Korea doctrine sucks, and Kim Jong Un's job is way too easy these days. What universities can do to cope with Chinese influence. India tries (and fails) to get a far-right alliance to whitewash Kashmir. Trump continues to channel the Biff Tannen school of imperialism and the Pod has a fever-dream about a smarter, sinister Ted Cruz presidency. Also this episode: An Assistant Secretary of State learns the wrong lesson from Van Jackson's first book - not everything is a bluff. Van's Predictions1) Will the RCEP trade deal come into force by 2020? | No2) Will India lift the state of emergency in Kashmir by the end of 2019? | No3) Will Russia, China, Europe remain party to the JCPOA through 2020? | Yes4) Will America fully withdraw from the Paris Agreement in 2020? | Yes, but it won't matter.Notes and Sources:Huffington Post: "What if the World Treated the U.S like a Rogue State?" https://www.huffpost.com/highline/article/sanctions/(Note: Huffington Post, not Buzzfeed)Aaron Stein tweet on Trump & Oil: https://twitter.com/aaronstein1/status/1192191364055875584Ryan Evans tweet on Boomers: https://twitter.com/EvansRyan202/status/1192196752318894091Ezra Klein tweet on American Constitutionalism: https://twitter.com/ezraklein/status/1191857312543064064?s=21ChinaFile – ‘How Should Universities Respond to China's Growing Presence on Their Campuses?' http://www.chinafile.com/conversation/how-should-universities-respond-chinas-growing-presence-their-campusesVan's Recommended Lefty Websites:Dissent - https://www.dissentmagazine.orgThe New Republic - https://newrepublic.com/The Baffler - https://thebaffler.com/n+1 - https://nplusonemag.com/
8个足球场大小的博物馆!你期待吗? 欢迎收听成都市成华区人民政府官方政务电台成华新闻早知道,一起进入今天的成华快讯 博物馆是城市的一面镜子,是城市的灵魂,它储存着城市文明的基因,凝聚着城市文化的精髓,凸显着城市历史的纵深。 而在历史文化深厚的成华区,一座高大上的崭新博物馆即将和公众见面!这就是成都自然博物馆。去年底,改项目向全球征集概念性设计方案,目前已经完成全球征集概念性设计方案专家评审工作。 据小编了解,成都自然博物馆计划建于成都市成华区成华大道十里店路以东,二仙桥东三路以北,成都理工大学西侧,总建筑面积大约相当于8个足球场。该博物馆将参考英国自然历史博物馆、美国自然历史博物馆以及上海自然博物馆、重庆自然博物馆等著名博物馆展陈内容设计。项目建成后将填补成都市没有自然博物馆的空白。 是不是很期待呢?小编给你剧透一个! 虽然最终设计方案还未出炉,但可以确定的是,成都自然博物馆将以文化教育为主线、科普教育为核心、地学展陈为特色、典藏建设为基础、应用技术为纽带,科学性与思想性相融合、相贯通,打造成都市文化地标。 博物馆外观设计理念参考了合川马门溪龙、DNA分子、太阳神鸟等元素,体现出博物馆新老建筑融合统一,象征时间、空间、宇宙以及传承本土文化的特色。博物馆的效果图,小编贴在这条声音的文本里了,你喜欢吗? 展品的内容计划设置“演化乐章”,即宇宙、地球、环境、生命演化过程、“生命画卷”即多姿多彩的现代生命世界、“文明史诗”,即人类文明兴衰与愿景、“时空漂移”,即互动体验零距离,四大模块,展现地球诞生及其生命演化,展示物种与其自然环境的适应发展,阐述天地自然与生命和人类活动的关系。 至于大家最关心的展品吗?可能就括始祖鸟、恐龙骨架、剑齿虎头骨、陆地和海洋的现代动植物标本,以及各种各样的矿物、岩石、宝玉石、陨石。 博物馆内还计划通过艺术和技术相结合的方式设计展项,比如通过AR技术、全息技术、4D影院、球幕或VR影院等技术手段让“展品说话”、让“化石复活”。 此外,博物馆还计划提供小朋友最感兴趣的零距离互动体验,例如学习小型化石模型的制作方法,认识不同的矿物、岩石、宝玉石或古生物,认识不同脊椎动物的牙齿等等。 除了这个将要闪亮登场的自然博物馆,咱们成华还有哪些好耍又能增长知识的好地方?小编给你一一介绍一下。 NO.1成都工业文明博物馆 成都工业文明博物馆是西南首座工业博物馆,集工业文明史展示和文化产业为一体,利用旧厂房改造而成的主题式公园博物馆。这里以场景、图片、文字、实物、雕塑等手法,重点展示了上世纪50-80年代成都工业走过的风雨历程,是成都历史的珍贵积淀。 NO.2成都大熊猫博物馆 成都大熊猫博物馆分为大熊猫的分布,大熊猫的历史记载,大熊猫的生活奥秘,大熊猫的科学研究,大熊猫的保护和大熊猫保护的前景规划等几项。目前已建成了大熊猫馆、蝴蝶馆和脊椎动物馆三大相对独立又有机联系的展馆。同时还有较为完善的配套服务设施,形成了以展示人类对大熊猫的认识研究、保护拯救为主题,展示大自然的生物多样、宣传保护大自然多样性的综合性博物馆。 NO3.报纸博物馆 位成华区于华林二路25号圣灯街道综合文化活动中心内的报纸博物馆,是西南地区唯一一家对外开放的民间公益性报纸博物馆,也是成华区首家民办博物馆。 展馆藏品涵盖了清代、民国、解放初期、文革及改革开放以来各个时期的报纸。该馆创办人介绍,在这些收藏品中,清代道光年间的《京报》于2010年4月被中国报业协会集报分会评为首批“中国集报精品”;同治、光绪年间的《申报》及光绪、宣统年间的《政治官报》、《益闻报》、《汇报》、《点石斋画报》、《外交报》和康有为主办、梁启超主笔的《时务报》以及民国初年的《政府官报》、《光复报》等孤品、精品都非常珍贵。 成华区的这些博物馆,伫立在时光的背景里,为“文旅成华”默默贡献着自己的底蕴,是“天府文化”积淀中的一部分,你喜欢哪一个呢?
Elizabeth A. Povinelli discusses four axioms of critical theory in response to her presentation, "Toxic Assets the the Extimacy of Existence," from Frontier Imaginaries Ed.No3 at e-flux. In conversation with journal editor Stephen Squibb. Read Elizabeth A. Povinelli in e-flux journal: "Geontologies: The Concept and Its Territories" from issue 81, April 2017 "Geontologies: The Figures and the Tactics" from issue 78, December 2016
Vivian Ziherl discusses her curatorial platform Frontier Imaginaries on the occasion of TOXIC ASSETS: Frontier Imaginaries Ed.No3 at e-flux, Columbia University, and UnionDocs in October 2017. In conversation with journal editor Brian Kuan Wood. Watch day one of TOXIC ASSETS on e-flux film & video Read Vivian Ziherl's essay "The Fourfold Articulation" in e-flux journal #81, April 2017
Reconnexion Âmique : "Connexion avec les enfants d'aujourd'hui" No3 avec Magali Magdara. Dans la continuité des séances de Reconnexion Âmique, nous vous proposons, Stéphane et moi, un nouveau programme qui peut se vivre indépendamment ou à la suite. La 1ère étape des reconnexions âmiques consistait à contacter les êtres qui composent et sécurisent notre corps, ce partenaire conscient et aimant. La 2ème nous réconciliait avec notre Ombre, cette merveilleuse et mésestimée initiatrice. La 3ème nous rapprochait de notre Unité. Cette phase nous transporte au sein des nouvelles grilles que notre planète a mis en place dans son processus d'ascension. Chaque grille résonne sur les vibrations des nouveaux enfants qui nous accompagnent et continuent de s'incarner auprès de nous. Ces êtres s'ancrent en Conscience, rayonnant dès leur naissance leur Compétence. Ils sont là pour nous aider à retrouver notre Responsabilité et notre Joie. Vous en avez un aperçu dans le livre « Les vagues des nouveaux enfants » de Qala Sri'ama que vous pouvez trouver sur internet. Ce que portent les enfants, nous l'avons tous en nous puisque nous disposons tous des mêmes Compétences. En nous connectant à eux, nous allons réveiller progressivement notre potentiel pour ensuite choisir ce que nous en ferons – ou pas. Il s'agit simplement d'activer cette facette qui participe à notre êtreté. Le rythme sera d'environ une séance gratuite mensuelle, suivie d'une consolidation sur libre participation. Avant la séance, buvez un verre d'eau et installez-vous confortablement. Nous sommes ensemble pour le meilleur. Vos questions sont les bienvenues avant de débuter le voyage. Vous êtes invités à partager vos expériences, vos ressentis et vos interrogations dans le groupe Facebook dédié : https://www.facebook.com/groups/1594573677518074/ Magali : http://www.guerisseuse-d-ame.com/ Stéphane : http://stephane-colle.com Toutes les séances gratuites de Reconnexion Âmique depuis le début se trouvent ici : http://legrandchangement.tv/video_tag/reconnexion-amique/ Toutes les séances de consolidation sont disponibles en replay à faire autant de fois qu'il vous plaira et se font sur la base de votre libre contribution. Elles ne sont pas indispensables, à vous de sentir si ça vous appelle : http://www.legrandchangement.com/categorietm1.asp?i_catego=68800
Discotheque 51 Promo Mix - Just a little sample of the kind of music and vibe you will find on 11th November 2017 at Unit 51, Aberdeen. Horse Meat Disco Norman Jay (MBE) Bobby Cooper Tee In January 2017 Unit 51 kicked off its heritage series, promising 4 massive parties taking you back to the golden era of clubbing so get ready as we throw party No3 in our heritage series Horse Meat Disco Norman Jay (MBE) Bobby Cooper Tee
【抜粋 of the お悩み】⇒「本当に好きな人(同性)がいるけれど、 気になっていた異性から食事に誘われ … 続きを読む No3:男とも女とも付き合ってみるか悩む19歳のリスナー様へ
上期打赏累计最高榜首:惜缘随缘不攀缘 NO2:连上30天快活似神仙NO3:七七第十感谢一如既往收听支持的亲们/(ㄒoㄒ)/~~ 么么哒,无论打赏还是不打赏,都是我最珍贵的小伙伴~ 公众微信账号:NJ早安 新浪微博@NJ早安 QQ群:122009、227028824、342171953
上期打赏累计最高榜首:惜缘随缘不攀缘 NO2:连上30天快活似神仙NO3:七七第十感谢一如既往收听支持的亲们/(ㄒoㄒ)/~~ 么么哒,无论打赏还是不打赏,都是我最珍贵的小伙伴~ 公众微信账号:NJ早安 新浪微博@NJ早安 QQ群:122009、227028824、342171953
上期打赏累计最高榜首:惜缘随缘不攀缘 NO2:连上30天快活似神仙NO3:七七第十感谢一如既往收听支持的亲们/(ㄒoㄒ)/~~ 么么哒,无论打赏还是不打赏,都是我最珍贵的小伙伴~ 公众微信账号:NJ早安 新浪微博@NJ早安 QQ群:122009、227028824、342171953
Rod and Karen are joined by Justin and Phonte Coleman to discuss skits in hip hop, recording for Black Dynamite, The Walking Dead aka DeyWalking then we let Phonte go and we discuss Ben Carson, a news anchor prank, Patricia Arquette, Chris Brown had a break baby, NO3 club, black man fan club, HBO online, BallerAlert, beer for a on year old, deer dad, shoplifting ultimatum, penis cake, penis chewer and sword ratchetness. Twitter: @rodimusprime @SayDatAgain @TBGWT @phontigallo Email: theblackguywhotips@gmail.com Blog: www.theblackguywhotips.com Voice Mail: 704-557-0186 Guest Website: http://theforeignexchangemusic.com/ Sponsors: www.shadowdogproductions.com And they're on Twitter: @ShadowDogProd www.adamandeve.com And they're on Twitter: @adamandeve Code: TBGWT
出所:声の図書室 http://teabreakt.studio-web.net/No3-akutagawa-1/Trokko-momiyamahisao.mp3
出所:声の図書室 http://teabreakt.studio-web.net/No3-akutagawa-1/Un-momiyamahisao.mp3
出所:声の図書室 http://teabreakt.studio-web.net/No3-akutagawa-1/sanemonnotsumi-momiyamahisao.mp3
出所:声の図書室 http://teabreakt.studio-web.net/No3-akutagawa-1/Momotaro.mp3
出所:声の図書室 http://teabreakt.studio-web.net/No3-akutagawa-1/Rasyoumon-momiyamahisao.mp3
出所:声の図書室 http://teabreakt.studio-web.net/No3-akutagawa-1/shiro-momiyamahisao.mp3
出所:声の図書室 http://teabreakt.studio-web.net/No3-akutagawa-1/Sousyun.mp3
出所:声の図書室 http://teabreakt.studio-web.net/No3-akutagawa-1/Aguninokami.mp3
出所:声の図書室 http://teabreakt.studio-web.net/No3-akutagawa-1/Kumo%20no%20ito.mp3
This is the second in a three-part presentation that provides a rather broad coverage of the management practices recommended for bermudagrass. This presentation covers bermudagrass fertilization for high yields and discusses issues with nitrate (NO3) accumulation in bermudagrass. This presentation also highlights some of the latest research on the subject at the University of Georgia and the USDA-ARS station in Tifton. (georgiaforages021.mov)
出所:小金洋子の読み語り作品集 http://teabreakt.studio-web.net/No3-akutagawa-1/yabunonaka-all-kogayaneyoko.mp3
Fakultät für Biologie - Digitale Hochschulschriften der LMU - Teil 03/06
The major role in global net CO2 fixation plays photosynthesis of green plants, algae and cyanobacteria, but other microorganisms are also important concerning autotrophy; i.e. autotrophic microorganisms can be found in most bacterial groups (Eubacteria) and there are even numerous representatives within the Archaea. CO2 fixation is not only one of the world’s most important biogeochemical processes and responsible for the buildup of organic compounds which are needed for biological functions (e.g. cell growth or nutrition of heterotrophic organisms); ultimately all ecosystems are based on inputs of carbon and energy provided by autotrophic organisms which can be found in almost all environments. While the importance of CO2 fixation on the surface is known, there is almost no information about autotrophic processes in the subsurface. The widespread opinion is that subsurface communities are dominated by heterotrophic microorganisms, but it is unlikely that all subsurface biomass depends on the limited amounts of organic carbon imported from the surface or on pollution dumping. Groundwater systems comply with all requirements for autotrophic growth processes (electron donors e.g. H2, S2O3 2- and electron acceptors e.g. NO3-, O2 are available as well as plenty of inorganic carbon), so autotrophic microorganisms could significantly contribute to the carbon flux in at least some of those systems. In summary, the existence and the role of chemolithoautotrophic CO2 fixation in the terrestrial subsurface is hardly known. To date, five CO2 fixation pathways are described, i.e. the Calvin-Benson-Bassham cycle (Calvin cycle), the reductive tricarboxylic acid cycle, the reductive acetyl CoA pathway, the 3-hydroxypropionate cycle and the 3-hydroxypropionate/4-hydroxybutyrate CO2 fixation pathway, with the Calvin cycle being the most intensively studied and probably the most abundant one. A sixth fixation pathway was just recently discovered. Objective of this thesis was to prove the CO2 fixation potential within the microbial communities in different groundwater ecosystems by means of functional gene analysis (cbbL, cbbM and acl genes) and to link this potential with in situ autotrophic activities as evaluated by different isotope and fatty acid approaches (FISH-MAR and PLFA analysis). Furthermore enrichment cultures under obligate chemolithoautotrophic conditions were started to get an idea about the diversity of those communities. The detection of the cbb genes in a contaminated and a pristine aquifer proved the occurrence of CO2 fixation potential being present in the bacterial communities of those ecosystems. Concerning the tar-oil contaminated aquifer, the majority of all retrieved cbb sequences was closely related to the cbbL and cbbM sequences belonging to the genus Thiobacillus, indicating that this genus might be of importance in groundwater ecosystems. This hypothesis is further supported by the results retrieved in the investigation at the organically poor site, the Testfield Scheyern. Here, most cbbM sequences detected were also closely related to the cbb sequences of Thiobacillus ssp.. The successful labelling of bacterial cells deriving from the tar-oil contaminated aquifer via fluorescent in situ hybridization (FISH) indicated considerable bacterial activity in this aquifer, but the detection of radiolabeled cells failed. 13C-labelled CaCO3 was exposed together with sterile sediment in the same aquifer. Cell counts suggested a successful colonization of the exposed sediments, but PFLA concentration was low. However, the incorporation of 13C-carbon into two of the detected fatty acids was a direct hint for bacterial CO2-uptake. Successful enrichment cultures out of both investigated aquifers proved the actual occurrence of autotrophs in those ecosystems. In total four new chemolithoautotrophic bacterial strains could be isolated, one of them, belonging to the genus Thiobacillus, was further characterized. It was an obligate chemolithoautotrophic strain, using the Calvin cycle for CO2 fixation. It was described as a new species, Thiobacillus thiophilus D24TN sp. nov..
出所:ネットで聴く日本と世界の名作 http://teabreakt.studio-web.net/No3-akutagawa-1/torokko-ishihideyuki.mp3
出所:“朗読の森”をお散歩。。 http://teabreakt.studio-web.net/No3-akutagawa-1/kumonoito-all-okazakichikako.mp3 & […]
出所:声の花束(こえたば) http://teabreakt.studio-web.net/No3-akutagawa-1/koe-sousekisanbounoaki-kobayashikikue.mp3 &nbs […]
出所:声の花束(こえたば) http://teabreakt.studio-web.net/No3-akutagawa-1/koe-majyutsu-all-morichisato.mp3
出所:声の花束(こえたば) http://teabreakt.studio-web.net/No3-akutagawa-1/koe-nezumikozo-all-guarnet.mp3
出所:声の花束(こえたば) http://teabreakt.studio-web.net/No3-akutagawa-1/koe-torokko-satokatsumi.mp3
出所:声の花束(こえたば) http://teabreakt.studio-web.net/No3-akutagawa-1/koe-Kumonoito-koenohanataba.mp3
出所:声の花束(こえたば) http://teabreakt.studio-web.net/No3-akutagawa-1/koe-Piano-senomariko.mp3
出所:声の花束(こえたば) http://teabreakt.studio-web.net/No3-akutagawa-1/koe-mikan-kitagawataeko.mp3
出所:声の花束(こえたば) http://teabreakt.studio-web.net/No3-akutagawa-1/koe-sousekisanbounofuyu-kobayashikikue.mp3 &nb […]
出所:声の図書室 http://teabreakt.studio-web.net/No3-akutagawa-1/Majyutu.mp3
出所:声の花束(こえたば) http://teabreakt.studio-web.net/No3-akutagawa-1/koe-hina-all-matsushimatokiko.mp3
出所:声の花束(こえたば) http://teabreakt.studio-web.net/No3-akutagawa-1/koe-rasyoumon-all-kawananagisa.mp3
出所:声の花束(こえたば) http://teabreakt.studio-web.net/No3-akutagawa-1/koe-yabunonaka-all-kawananagisa.mp3
出所:声の花束(こえたば) http://teabreakt.studio-web.net/No3-akutagawa-1/koe-toshisyun-all-kawananagisa.mp3
出所:音連れ 飯島晶子です http://teabreakt.studio-web.net/No3-akutagawa-1/soumon-iijimaakiko.mp3
出所:声の図書室 http://teabreakt.studio-web.net/No3-akutagawa-1/kyouryomu-momiyamahisao.mp3
出所:声の図書室 http://teabreakt.studio-web.net/No3-akutagawa-1/Karenosyou.mp3
出所:声の図書室 http://teabreakt.studio-web.net/No3-akutagawa-1/Aruhino%20Ooishikuranosuke.mp3
出所:“朗読の森”をお散歩。。 http://teabreakt.studio-web.net/No3-akutagawa-1/okazakichikako-torokko.mp3
出所:一語千夢 One-word 1000 dreams http://teabreakt.studio-web.net/No3-akutagawa-1/mikan-all-saran.mp3
出所:ザ・架け橋 Story Telling http://teabreakt.studio-web.net/No3-akutagawa-1/otominoteisou-all-kitaharamitsutko.mp3
出所:“朗読の森”をお散歩。。 http://teabreakt.studio-web.net/No3-akutagawa-1/okazakichikako-mikan.mp3
出所:Blog 表現よみ作品集 http://teabreakt.studio-web.net/No3-akutagawa-1/hana-all-watanabetomoaki.mp3
出所:早耳ネット「音のボランティアサービス」 http://teabreakt.studio-web.net/No3-akutagawa-1/hana-all-kawabesatoko.mp3
出所:早耳ネット「音のボランティアサービス」 http://teabreakt.studio-web.net/No3-akutagawa-1/yabunonaka-all-hayamajunshiro.mp3 […]
出所:一語千夢 One-word 1000 dreams http://teabreakt.studio-web.net/No3-akutagawa-1/hitokurenotsuchi-all-saran.mp3 &n […]
出所:早耳ネット「音のボランティアサービス」 http://teabreakt.studio-web.net/No3-akutagawa-1/houkyouninnnoshi-all-ookakuni.mp3   […]
出所:早耳ネット「音のボランティアサービス」 http://teabreakt.studio-web.net/No3-akutagawa-1/torokko-all-miyazakifujiko.mp3   […]
出所:早耳ネット「音のボランティアサービス」 http://teabreakt.studio-web.net/No3-akutagawa-1/hayamimi-Toshi_full-nagainamiko.mp3 […]
出所:一語千夢 One-word 1000 dreams http://teabreakt.studio-web.net/No3-akutagawa-1/otominoteisou-all-saran.mp3   […]
出所:一語千夢 One-word 1000 dreams http://teabreakt.studio-web.net/No3-akutagawa-1/aruhinooishikuranosuke-all-saran. […]
出所:早耳ネット「音のボランティアサービス」 http://teabreakt.studio-web.net/No3-akutagawa-1/hayamimi-tabakotoakuma-all-misakinorit […]
出所:Reading Percussion の帰還 http://teabreakt.studio-web.net/No3-akutagawa-1/aruahonoissyo-all-kuni.mp3
出所:ザ・架け橋 Story Telling http://teabreakt.studio-web.net/No3-akutagawa-1/inutofue-all-masukawakazuko.mp3 […]
I had never heard of this piece until I recently purchased the book Anthology of Romantic Piano Music published by Alfred and edited by Maurice Hinson. I instantly fell in love with the melody. The canon at measures 40-55 is a bit tricky and I should have given it quite a bit more study and practice, but it is what it is :) This recording was completed at my home on my studio upright. I hope you enjoy it.
Fakultät für Chemie und Pharmazie - Digitale Hochschulschriften der LMU - Teil 01/06
1. Development and establishment of the high-pressure high-temperature synthesis as a broad approach to nitridophosphates. In this thesis for the first time a broad access to nitridophosphates was developed and therefore the basis for a systematic investigation of this class of compounds was established. It was shown, that under high-pressure conditions (> 3 GPa) using a belt or Walker module crystalline nitridophosphates can be obtained by reaction of phosphorus(V) nitride with alkaline or earth alkaline azides at temperatures of 1200-1600 °C. Thus the possibilty to suppress eliminiation of N2 from nitridophosphates, which occurs at 800 °C under atmospheric pressure, was proved by use of high-pressure conditions. Thereby the maximum temperature in synthesis of nitridophosphates was approximately doubled. A raise of the maximum temperature during the synthesis leads to much better crystallization conditions. Hence the main problem in synthesis of crystalline nitridophosphates, which consists of bad crystallisation conditions due to limited maximum reaction temperature, was solved and the number of the crystallographically well characterized ternary phosphorus(V) nitrides was doubled from nine to eighteen. Especially the number of highly condensed nitridophosphates (molar ratio P : N > 1 : 2) could be raised from three to nine and a second modification of the binary phosphorus(V) nitride P3N5 was obtained. Consequently the high-pressure high-temperature synthesis can be seen as the first widely applicable approach to nitridophosphates. Due to the hermetically sealed reaction cell precise modulation of the P-N framework by systematic variation of the P3N5 : azide molar ratio in the starting materials. Moreover under high-pressure conditions the reaction time was reduced dramatically compared to conventional synthesis. While using conventional methods several hours or days are needed for quantitative reactions, reactions under high pressure conditions succeed in 5-15 min. At the beginning of the work the apparatus for the high-pressure experiments did not exist within the laboratory equipment of our research group. The success of the first experiments (synthesis of NaP4N7, KP4N7, RbP4N7, CsP4N7), which were performed in cooperation with Evers, significantly contributed to the aquisition of the 1000 t-press installed by Huppertz, and the introduction of the multianvil high-pressure technique at the University of Munich (LMU). 2. NaP4N7, KP4N7, RbP4N7, and CsP4N7. The nitridophosphates NaP4N7, KP4N7, RbP4N7, and CsP4N7 were synthesized by reaction of P3N5 with the respective alkaline azide in the molar ratio MN3 : P3N5 = 3 : 4 (M = Na, K, Rb, Cs) at approximately 40 kbar and 1300 °C using a belt module. NaP4N7 (C2/c, a = 1233.45(4), b = 852.30(3), c = 513.97(1) pm, b = 102.572(2)°, Z = 4, Rp = 0.0772, wRp = 0.1077, RF = 0.0718) crystallizes isotypic to CaAl4O7 in a three-dimensional network structure of corner-sharing PN4 tetrahedra with Na + ions in the channels. According to the formula ¥ 3 [(P [4] 4 N 5 [2] N 2 [3] ) - ] N [2] - and N [3] -bridges exist in a molar ratio 5 : 2. KP4N7 (Pnma, a = 1222.72(2), b = 984.25(2), c = 466.24(1) pm, Z = 4, Rp = 0.0865, wRp = 0.1113, RF = 0.0821), RbP4N7 (a = 1231.07(2), b = 989.46(1), c = 468.44(1) pm, Z = 4, Rp = 0.0350, wRp = 0.0462, RF = 0.0589), and CsP4N7 (a = 1242.91(3), b = 997.63(3), c = 471.33(2) pm, Z = 4, Rp = 0.0524, wRp = 0.0646, RF = 0.0494) crystallize isotypic to the mineral barylite BaBe2Si2O7 in a three-dimensional network structure from corner-sharing PN4 tetrahedra with the alkaline ions in the channels. According to the formula ¥ 3 [(P [4] 4 N 5 [2] N 2 [3] ) - ] N [2] - and N [3] -bridges exist in a molar ratio 5 : 2. Using the obtained crystallographic data of MP4N7 (M = Na, K, Rb, Cs) MAPLE and CHARDI calculations as well as calculations based on the bond-length bond-strength concept were carried out and discussed. The radiographically obtained results were confirmed. The compounds were characterized by IR- and 31 P-MAS NMR-spectroscopy (d = -23.5, -25.0 (NaP4N7); -0.4, -1.7 (KP4N7), -19.6, -28.2 (RbP4N7), -21.6, -31.9 ppm (CsP4N7)). Thermogravimetric examinations under inert gas conditions revealed the thermal decomposition temperature of the compounds, which is about 850-900 °C. 3. Rb3P6N11 and Cs3P6N11. The nitridophosphates Rb3P6N11 and Cs3P6N11 were synthesized by reaction of P3N5 with the respective alkaline azide in the molar ratio MN3 : P3N5 = 3 : 2 (M = Rb, Cs) using a Walker module at approximately 35 kbar and 1300 °C. Rb3P6N11 (P4132, a = 1049.74(1) pm, Z = 4, Rp = 0.0979, wRp = 0.1077, RF = 0.0612) and Cs3P6N11 (P4132, a = 1065.15(1) pm, Rp = 0.0487, wRp = 0.0618, RF = 0.0812) crystallize isotypic to K3P6N11 in a three-dimensional network structure of corner-sharing PN4 tetrahedra with the alkaline ions in the channels. According to the formula ¥ 3 [(P 6 [4] N 9 [2] N 2 [3] ) 3- ] N [2] - and N [3] -bridges exist in the molar ratio 9 : 2. Using the obtained crystallographic data of M3P6N11 (M = Rb, Cs) MAPLE and CHARDI calculations as well as calculations based on the bond-length bond-strength concept were carried out and discussed. The radiographically obtained results were confirmed. The compounds were characterized by IR- and 31 P-MAS NMR-spectroscopy (d = -7.4 (Rb3P6N11), -8.9 ppm (Cs3P6N11)). Thermogravimetric examinations under inert gas conditions revealed the thermal decomposition temperature of the compounds, which is about 850-900 °C. Temperature-dependant powder X-ray investigations revealed that Rb3P6N11 shows no thermal expansion between room temperature and 540 °C.4. NaPN2. The nitridophosphate NaPN2 was synthesized by reaction of P3N5 with NaN3 in the molar ratio NaN3 : P3N5 = 3 : 1 using a Walker module at approximately 35 kbar and 1300 °C. NaPN2 (I 4 2d, a = 497.21(2), c = 697.60(3) pm, Z = 4, Rp = 0.0502, wRp = 0.0649, RF = 0.0788) crystallizes isotypic to LiPN2 in a three-dimensional network structure of corner-sharing PN4 tetrahedra with the Na + ions in the channels. According to the formula ¥ 3 [(P [4] N 2 [2] ) - ] N [2] -bridges exist exclusively. Using the obtained crystallographic data of NaPN2, MAPLE and CHARDI calculations as well as calculations based on the bond-length bond-strength concept were carried out and discussed. The radiographically obtained results were confirmed. The compound was characterized by IR- and 31 P-MAS NMR-spectroscopy (d = -15.0 ppm). Thermogravimetric examinations under inert gas conditions revealed the thermal decomposition temperature of the compound, which is about 900 °C. 5. CaP2N4 and SrP2N4. The nitridophosphates CaP2N4 und SrP2N4 were obtained by reaction of Ca(N3)2 and Sr(N3)2 with P3N5 (molar ratio M(N3)2 : P3N5 = 3 : 2) at 35 kbar and 1300 °C in a Walker module. A structure model could be obtained from X-ray powder data. CaP2N4 (P6322, a = 972.11(1) pm, c = 785.90(1) pm, Z = 8, Rp = 0.059, wRp = 0.079, RF = 0.174) and SrP2N4 (P6322, a = 987.44(1), c = 785.90(1) pm, Z = 8, Rp = 0.075, wRp = 0.098, RF = 0.115) crystallize isotypic in a network structure from corner-sharing PN4 tetrahedra with the alkaline earth ions within the channels. Perpendicular to [001] layers from condensed P6N6 sechser rings exists which are linked by P4N4 vierer rings and further P6N6 sechser rings forming the network structure. According to the formula ¥ 3 [(P [4] N 2 [2] ) - ] N [2] -bridges occur exclusively. Using the obtained crystallographic data of CaP2N4 and SrP2N4, MAPLE and CHARDI calculations as well as calculations based on the bond-length bond-strength concept were carried out and discussed. The radiographically obtained results were confirmed. The compounds were characterized by IR- and 31 P-MAS NMR-spectroscopy (d = -20.0, -15.9, -5.2, -3.6, - 2.6 (CaP2N4), -27.8, -23.4, -17.1, -15.5, -14.1 ppm (SrP2N4). Thermogravimetric examinations under inert gas conditions revealed the thermal decomposition temperature of SrP2N4, which is about 900 °C. CaP2N4 was stable up to 1000 °C. 6. g-P3N5. The synthesis of g-P3N5 was successfully carried out at 110 kbar and 1500 °C. In contrast to a-P3N5, which is exclusively build up from PN4 tetrahedera, g-P3N5 forms a three-dimensional network structure from PN4 tetrahedra and tetragonal PN5 pyramids. The tetragonal PN5 pyramid is a formerly unknown structural building unit. In the crystal- structure of g-P3N5 (Imm2, a = 1287.20(5), b = 261.312(6), c = 440.04(2) pm, Z = 2, Rp = 0.073, wRp = 0.094, RF = 0.048) rods of trans edge-sharing PN5 pyramids are condensed via vertice forming layers. These layers are linked by chains of corner-sharing tetrahedra. According to the formula ¥ 3 [P ] 4 [ 1 P ] 5 [ 2 N ] 2 [ 1 N ] 3 [ 4 ] N [2] and N [3] bridges occur in the molar ratio 1 : 4. Using the obtained crystallographic data of g-P3N5, MAPLE and CHARDI calculations as well as calculations based on the bond-length bond-strength concept were carried out and discussed. The radiographically obtained results were confirmed. The compound was characterized by IR- and 31 P-MAS NMR-spectroscopy (d = -11.9, -101.7 ppm). Thermogravimetric examinations under inert gas conditions revealed the thermal decomposition temperature of the compound, which is about 900 °C. The Vickers hardness was determined with a value of 9.7 GPa. 7. Hexaaminodiphosphazenium-bromide, -nitrate, and -toluenesulfonate. It was shown, that the hexaaminodiphosphazenium-salts [(NH2)3PNP(NH2)3]Br, [(NH2)3PNP(NH2)3] [NO3], and [(NH2)3PNP(NH2)3][CH3C6H4SO3] are accessible by anion exchange in water using [(NH2)3PNP(NH2)3]Cl as starting material. The structures of these compounds were obtained from single crystals, which were obtained from an acetonitrile solution in a temperature gradient ([(NH2)3PNP(NH2)3]Br: P 1 , a = 596.2(1), b = 744.5(1), c = 1114.4(1) pm, a = 108.78(1), b = 104.18(1), g = 90.64(1)°, R1 = 0.048, wR2 = 0.104; [(NH2)3PNP(NH2)3][NO3]: P 1 , a = 550.9(1), b = 796.3(1), c = 1115.7(1) pm, a = 94.45(1), b = 99.55(1), g = 101.53(1)°, R1 = 0.033, wR2 = 0.095; [(NH2)3PNP(NH2)3][CH3C6H4SO3]: P21/c, a = 804.1(1), b = 596.1(1), c = 3218.7(3) pm, b = 94.59(1)°, R1 = 0.052, wR2 = 0.136). The compounds crystallize in structures with discrete [(NH2)3PNP(NH2)3] + -ions and the corresponding anions. [(NH2)3PNP(NH2)3]Br is isotypic to [(NH2)3PNP(NH2)3]Cl. Between the ions many hydrogen bonds exist. In [(NH2)3PNP(NH2)3]Br the [(NH2)3PNP(NH2)3] + -ion occurs in a staggered conformation, while in [(NH2)3PNP(NH2)3][NO3] an ecliptic conformation is preferred. In [(NH2)3PNP(NH2)3][CH3C6H4SO3] the gauche-conformation exists. It was shown by Extended Hückel calculations, that no significant rotation barriers exist between the conformations. The compounds were characterized by IR and 31 P NMR-spectroscopy (d = -15.0 ppm). The thermal behaviour of the compounds was examined by thermogravimetry.