Podcasts about emitter

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Best podcasts about emitter

Latest podcast episodes about emitter

Reasons to Believe Podcast
Star, Cells, and God | Metal-Free Stars and Deceptive AIs

Reasons to Believe Podcast

Play Episode Listen Later Aug 28, 2024 56:33


Join Hugh Ross and Jeff Zweerink as they discuss new discoveries taking place at the frontiers of science that have theological and philosophical implications, including the reality of God's existence. Metal-Free Stars Using the James Webb Space Telescope (JWST), a team of 15 astronomers discovered a galaxy (RXJ2129-z8HeII) with a measured redshift that corresponds to a distance of 13.16 billion light-years. This measurement implies that astronomers are seeing it just 630 million years after the big bang creation event. The newly discovered galaxy's features include two unique features: a bright ultraviolet continuum with an extremely steep spectral slope and a strong helium emission line. These newly found features, combined with a discovery made a few months earlier of an ionized gas cloud in the halo of another galaxy that contains only hydrogen and helium, affirms a fundamental prediction of the biblically predicted big bang creation model. That prediction claims that before any stars form the elemental composition of the universe will, by mass, be composed of 75.33% hydrogen, 24.67% helium, and a trace amount of lithium. These discoveries provide yet more evidence that the more we learn about the universe, the more evidence we accumulate that a God beyond space and time created the universe and exquisitely designed it so that humans could live and thrive.  Links and Resources:  A Strong He II ƛ640 Emitter with Extremely Blue UV Spectral Slope at z = 8.16: Presence of Pop III Stars? Possible Population III Signatures at z = 10.6 in the Halo of GN-z11

GUNS Magazine Podcast
#245- New Hotness: Closed-Emitter Pistol Optics

GUNS Magazine Podcast

Play Episode Listen Later Aug 10, 2024 33:12


Confused about the difference between open- and closed-emitter red dot optics? In this episode, AmericanCOP.com Editor Eric Gelhaus shares helpful tips on how to pick the best optic for your particular situation and gun. EPISODE SPONSORS The GUNS Magazine Podcast is presented by Riton Optics. Riton Optics has a solution for your optics needs, but the very latest from Riton is the 3 Tactix lineup of pistol red dots. The 3 Tactix PRD, MPRD, and EED marry with the RMR, RMSc and ACRO footprint, respectively, and offer the features you need for that EDC or competition pistol. Learn more about the 3 Tactix Red Dots or the entire lineup at www.ritonoptics.com and use code GUNS24 for 15% off at checkout. The GUNS Magazine Podcast is supported by HIVIZ Shooting Systems. HIVIZ® Shooting Systems is the designer, engineer and manufacturer of high-quality and innovative sights for handguns, shotguns, and rifles. From the unique molded LitePipe technology to their patented LiteWave H3® Tritium/Fiber-Optic sights and new FastDot H3®, HIVIZ continues to advance the art of shooting. See what you've been missing at www.hivizsights.com. -- Have a topic idea or guest you'd like to see in a future episode? Let us know in the comments or email podcast@gunsmagazine.com. Never miss an episode! Subscribe to our YouTube channel or sign-up for our newsletter (https://gunsmagazine.com/newsletters) to get the GUNS Magazine Podcast delivered straight to your inbox each week.

Fossil vs Future
WHAT ABOUT CHINA? The largest emitter of greenhouse gases or the driver of the green transition?

Fossil vs Future

Play Episode Listen Later Jul 30, 2024 37:11


China is often called out for its excessive contribution to global greenhouse gas emissions, predominantly due to its huge reliance on coal power. However, at the same time it is the world leader in renewable energy generation and has a rapidly expanding electric vehicle industry. In this episode, James and Daisy discuss China's centrality to global climate action. Is China slowing down its use of fossil fuels? Should we be concerned about our high dependence on China for minerals and other resources? What can we learn from China's approach to transition? SOME RECOMMENDATIONS:China Dialogue was founded by Isabel Hilton, an international journalist, in 2006. It is an independent non-profit committed to accurately portraying China's development impacts across the Global South through geopolitically even-handed reporting and constructive dialogue. It is a useful place to get informed on what is going on in China. Climate Action Tracker – an independent scientific project that tracks government climate action and measures it against the globally agreed Paris Agreement. It tracks 39 countries and the EU, evaluating climate change mitigation targets, policies and actions. It is a great resource for seeing how countries are progressing towards achieving their climate goals. OTHER ADVOCATES, FACTS, AND RESOURCES:WRI: “China is the biggest emitter at 26.4% of global greenhouse gas emissions, followed by the United States at 12.5%.” However, this was as of 2019. According to Our World in Data, it looks like China's contribution to global emissions may have risen to 30.68% in 2022. This webpage also has some interesting graphs showing a breakdown of China's CO2 emissions by source.Rocky Mountain Institute: “China produces three-quarters of all lithium-ion batteries and 70 percent of cathode capacity and processes and refines more than half of the world's lithium, cobalt, and graphite.”Visual Capitalist has some nice graphs on the wind and solar power scale-up: “85% of solar PV is manufactured in China.”Our World in Data: “On the basis of cumulative CO2 emissions measured from 1751 through to 2017, China is responsible for 13% globally and about half of the United States' cumulative emissions.”IEA: “China accounts for almost 60% of new renewable capacity expected to become operational globally by 2028.”Belt and Road Initiative (BRI) – a massive China-led infrastructure project seeking to connect Asia with Africa and Europe via land and maritime networks. Read more about it in this explainer from Chatham House. Soltecture (formerly Sulfurcell) was the German company James referred to that develop and produce thin film solar cells. Jack Ma co-founded Alibaba, one of the world's largest e-commerce businesses. Lauri Myllyvirta is a Senior Fellow at the China Climate Hub, a global non-profit dedicated to understanding Asia through policy, arts, and education.Jeanne-Marie Gescher – one of the world's leading experts on China. We recommend her book All Under Heaven: China's Dreams of Order. Thank you for listening! Please follow us on social media to join the conversation: LinkedIn | Instagram | TikTokMusic: “Just Because Some Bad Wind Blows” by Nick Nuttall, Reptiphon Records. Available at https://nicknuttallmusic.bandcamp.com/album/just-because-some-bad-wind-blows-3Producer: Podshop StudiosHuge thanks to Siobhán Foster, a vital member of the team offering design advice, critical review and organisation that we depend upon.Stay tuned for more insightful discussions on navigating the transition away from fossils to a sustainable future.

Earth Wise
California is the largest emitter of a little-known greenhouse gas

Earth Wise

Play Episode Listen Later Apr 30, 2024 2:00


California is a state known for its aggressive climate policies.  However, and rather ironically, California is also the nation’s greatest emitter of one little-known greenhouse gas: sulfuryl fluoride.  Sulfuryl fluoride is one of the few treatments to rid buildings of drywood termites, a common regional pest that can be found in wooden structures.  Sulfuryl fluoride […]

The ASHE Podcast
Episode 11: The 5th largest emitter...are we saving or costing lives?

The ASHE Podcast

Play Episode Listen Later Jan 8, 2024 45:17


On today's episode of The ASHE Podcast Gonzalo Bearman and Priya Nori are joined by guests Alison G. Freifeld and Ali S. Khan to talk about their article, "The climate crisis and healthcare: What do infection prevention and stewardship professionals need to know?" Our guests discuss what the infectious diseases workforce should know about how the climate crisis might impact their everyday work. They discuss healthcare's big carbon footprint and what can be done about it and also discuss how the One Health approach can be applied to addressing the climate crisis. After listening, be sure to go to Cambridge.org/ashe to read their full manuscript and learn more.

RNZ: Morning Report
Fonterra top emitter for third year running

RNZ: Morning Report

Play Episode Listen Later Oct 12, 2023 3:52


Fonterra is New Zealand's top greenhouse gas emitter for the third year running, followed by big petrol companies Z Energy, BP and Mobil. Figures for the year ending June show ten companies still make more than half the country's emissions. Climate Change Correspondent Eloise Gibson spoke to Ingrid Hipkiss.

Earth SciShow
Earth's Hidden Carbon Dioxide Emitter - Are We Done For?

Earth SciShow

Play Episode Listen Later Oct 10, 2023 8:02


In this episode of Earth SciShow, MrEarthGuy unveils a hidden new process within the global carbon cycle. Called Organic Carbon weathering or OCPetro for short, this new process has brought to light a brand new factor in the natural climatic processes in the Carbon Cycle. Are we passed the point of no return for climate change? or can Earth's natural processes support the rapid changes in climatic carbon. Listen in to find out! #geology #earthscience #climatechange #science

No Gods! No Master Volumes!
07 Ian Pritchard (Collector Emitter) Part 1

No Gods! No Master Volumes!

Play Episode Listen Later Sep 5, 2023 45:19


On this episode of No Gods! No Master Volumes! we talk to Ian Pritchard of Collector Emitter. As a talented musician, pedal demo artist and photographer we had plenty to discuss with Ian including his process, work/life balance and the evolution of YouTube. Hosted on Acast. See acast.com/privacy for more information.

No Gods! No Master Volumes!
08 Ian Pritchard (Collector Emitter) Part 2

No Gods! No Master Volumes!

Play Episode Listen Later Sep 5, 2023 58:29


On this episode of No Gods! No Master Volumes! we talk to Ian Pritchard of Collector Emitter. As a talented musician, pedal demo artist and photographer we had plenty to discuss with Ian including his process, work/life balance and the evolution of YouTube. Hosted on Acast. See acast.com/privacy for more information.

Startup Insider
beeOLED erhält 13,3 Mio. Euro für effizientere OLED-Displays (eCAPITAL • Innovation Industries • KBC Focus Fund)

Startup Insider

Play Episode Listen Later Aug 31, 2023 25:14


In der Nachmittagsfolge begrüßen wir heute Jan Blochwitz-Nimoth, CEO von beeOLED, und sprechen mit ihm über die erfolgreich abgeschlossene Series-A-Finanzierungsrunde in Höhe von 13,3 Millionen Euro. beeOLED entwickelt einen effizienten und stabilen tiefblauen Emitter zur Verbesserung von Displays in Handys, Tablets, Laptops, Fernsehern und sonstigen Geräten. Seine Technologie basiert darauf, die elementare Emission von Atomen für den Einsatz in den heutigen vakuumverarbeiteten OLED-Displays vorzubereiten. Die Display-Technologie, die erstmals solche Moleküle mit der Vakuumverarbeitungstechnologie kompatibel macht, ist durch mehrere Patente geschützt. Die Technologie fügt sich zudem nahtlos in bestehende OLED-Strukturen und etablierte OLED-Display-Herstellungstechnologien ein und ermöglicht eine interne Quanteneffizienz von 100 %, was eine Voraussetzung für die höchste Leistungseffizienz von OLED-Displays darstellt. Außerdem führt die Steigerung der Effizienz des blauen Emitters in OLED-Displays zu einer signifikanten Senkung des Energieverbrauchs in modernen Fernsehern, Tablets und Smartphones. Das Startup wurde im Jahr 2020 von Dr. Carsten Rothe und Dr. Volodymyr Senkovskyy in Dresden gegründet. Mit einer Präsentation auf der Branchenveranstaltung "International Meeting on Information Display" in Südkorea ist das Unternehmen am 25. August 2023 offiziell aus dem Stealth-Modus herausgetreten.Nun hat das Dresdner Deep-Tech-Startup in einer Series A 13,3 Millionen Euro unter der Führung von eCAPITAL und Innovation Industries eingesammelt. Außerdem beteiligten sich der KBC Focus Fund sowie die bestehenden Investoren wie der Corporate-Venture-Capital-Arm von Merck namens M Ventures, HTGF, TGFS und JBN-Invest an der Runde. beeOLED will die Investition nutzen, um seine innovative und hocheffiziente Deep-Blue-Emitter-Technologie bis zur Marktreife weiterzuentwickeln.

Ambient Discourses // conversations with musicians and composers
Daryl Groetsch of Pulse Emitter // conversations about digital composing, the commodification of music, ego vs art, sci-fi inspiration, and communal listening [episode 010, August 6, 2023]

Ambient Discourses // conversations with musicians and composers

Play Episode Listen Later Aug 6, 2023 104:27


Episode 010 / August 6, 2023 In this episode of Ambient Discourses, I have an amazing conversation at notable depths with Oregon-based electronic artist Daryl Groetsch who also operates under the name Pulse Emitter. The topic of our conversation steered through many highly interesting topics of conversation, including finding the balance in using tools and AI in music creation, finding the balance between ego and art, finding community in an isolated musical space, and other fascinating talking points. You can hear more from Daryl Groetsch on the STOLACE | RELAY STATION, episode 3.40, which aired on August 6, 2023. Find more at https://stolace.com/relay-station/episodes/03/40/ [0:01:26] The origin story [0:07:21] Compositional tools and process [0:12:52] “In Blackness” by Daryl Groetsch from “Frozen Waste” [0:21:59] Using apps and AI to aid in music composition [0:35:14] “Suncatcher” by Daryl Groetsch from “Gardens in Glass” [0:45:21] Approaching music creation in a world of commodification [0:50:08] Ego vs. Art [0:59:48] “The Road to Thrax” by Pulse Emitter from “Dusk” [1:05:11] Planting gardens in glass and building worlds [1:11:07] Get your nerd membership card out, we're talking sci-fi [1:15:37] Inspiration to help us get out of our creative ruts [1:20:30] “Gardens in Glass” by Daryl Groetsch from “Gardens in Glass” [1:30:109] Communal listening // ABOUT AMBIENT DISCOURSES // Ambient Discourses is the podcast companion to The STOLACE | RELAY STATION, a weekly 59-minute music program that showcases ambient, neoclassical, new age, and other instrumental music from around the world. Discover new signed and independent artists from nearly every corner of the globe, unwind with the Relay Station at work or at home, and hear from the artists themselves what inspires them, how their latest releases evolved, and other deep topics of conversation. You can find every episode of The STOLACE | RELAY STATION at ⁠https://stolace.com/relay-station/⁠ The STOLACE | RELAY STATION is available on YouTube and the Public Radio Exchange (PRX) platform. // CONNECT WITH STOLACE // ⁠https://stolace.com⁠ ⁠https://youtube.com/stolace⁠⁠ https://twitter.com/stolacemusic⁠ ⁠https://instagram.com/stolacemusic⁠ ⁠https://facebook.com/stolace⁠

Real Life French
Un émetteur (Emitter)

Real Life French

Play Episode Listen Later Apr 28, 2023 2:28


Si le gaspillage de nourriture était un pays il serait le troisième plus gros émetteur de gaz à effet de serre, derrière uniquement la Chine et les Etats Unis.Traduction:If food wastage was a country it would be the third largest emitter of greenhouse gas emissions, trailing only behind China and the United States. Hosted on Acast. See acast.com/privacy for more information.

Real Life French
Un émetteur (Emitter)

Real Life French

Play Episode Listen Later Apr 28, 2023 2:58


Si le gaspillage de nourriture était un pays il serait le troisième plus gros émetteur de gaz à effet de serre, derrière uniquement la Chine et les Etats Unis. Traduction: If food wastage was a country it would be the third largest emitter of greenhouse gas emissions, trailing only behind China and the United States. Learn more about your ad choices. Visit megaphone.fm/adchoices

Louis French Lessons
Un émetteur (Emitter)

Louis French Lessons

Play Episode Listen Later Apr 28, 2023 2:28


Si le gaspillage de nourriture était un pays il serait le troisième plus gros émetteur de gaz à effet de serre, derrière uniquement la Chine et les Etats Unis.Traduction:If food wastage was a country it would be the third largest emitter of greenhouse gas emissions, trailing only behind China and the United States. Hosted on Acast. See acast.com/privacy for more information.

Louis French Lessons
Un émetteur (Emitter)

Louis French Lessons

Play Episode Listen Later Apr 28, 2023 2:58


Si le gaspillage de nourriture était un pays il serait le troisième plus gros émetteur de gaz à effet de serre, derrière uniquement la Chine et les Etats Unis. Traduction: If food wastage was a country it would be the third largest emitter of greenhouse gas emissions, trailing only behind China and the United States. Learn more about your ad choices. Visit megaphone.fm/adchoices

The Sustainability Agenda
Episode 172: Professor Neta Crawford discusses the emissions of the Pentagon -- the world's largest single greenhouse gas emitter.

The Sustainability Agenda

Play Episode Listen Later Mar 27, 2023 55:25


In this eye-opening interview, Professor Neta Crawford discusses the research in her new book The Pentagon, Climate Change, and War focussing on the huge carbon footprint of the Pentagon -- the world's largest single greenhouse gas emitter. She tracks the interconnect long-term cycles of economic growth, and fossil fuel use-and growth of the US military. Crawford believes the most effective way to cut military emissions is to rethink U.S. grand strategy, which would enable the United States to reduce the size and operations of the military.

Energy News Beat Podcast
Daily Energy Standup Episode #85 Coal returns to Pakastan – China still keeps the number one pollution emitter despite claims of the energy transition statements.

Energy News Beat Podcast

Play Episode Listen Later Mar 21, 2023 19:55


Daily Standup Top StoriesMore than 3,000 acres of New Mexico public land being sold for oil and gas amid protestsMarch 20, 2023 Mariel AlumitA sale of New Mexico's public land to the oil and gas industry was expected in May with lands going to auction throughout the Permian Basin in the southeast corner of the state. The auction scheduled […]U.S. raises the offshore rig count anteMarch 20, 2023 Allen SantosBaker Hughes' weekly rig count report shows that the number of offshore rigs in the United States was on the upswing last week with three units added to the mix. The total number of rigs […]U.S. drillers add the most gas rigs in a week since December 2018March 18, 2023 Allen Santos​The oil and gas rig count, an early indicator of future output, rose eight to 754 in the week to March 17. , , Baker Hughes said that puts the total rig count up 91 […]Coal returns to the China-Pakistan Economic CorridorMarch 20, 2023 Mariel AlumitNews that the Pakistan government plans to secure financing and start construction on a long-stalled 300 megawatt coal-fired power plant in the port city of Gwadar has triggered a debate on the direction of the country's energy […]Despite liberal media wishful thinking, China just keeps pumping out more carbon dioxideMarch 20, 2023 Mariel AlumitIf you want to see unshakable hope in the face of all evidence, check out the Americans and Brits who consistently promise that China is going green. One of the most predictable patterns of the past 20 […]Monday's Energy Absurdity: You Won't Believe Who's Getting Blamed For Blowing Up Nord Stream Now  David BlackmonEvery time you get to thinking that energy-related propaganda cannot possibly become any more absurd that it already is, some media platform or another pops your bubble. […]Highlights of the Podcast00:00 – Intro1:12 – Despite liberal media wishful thinking, China just keeps pumping out more carbon dioxide06:11 – Monday's Energy Absurdity: You Won't Believe Who's Getting Blamed For Blowing Up Nord Stream09:23 – Coal returns to the China-Pakistan Economic Corridor12:11 – U.S. Drillers add the most rig count rose 8 to 754 in the week of March 17th13:36 – U.S. raises offshore rig count14:44 – More than 3,000 acres of New Mexico public land being sold for oil and gas amid protests16:34 – Market Updates19:54 – OutroFollow Stuart On LinkedIn and TwitterFollow Michael On LinkedIn and TwitterENB Top NewsENBEnergy DashboardENB PodcastENB Substack

Irrigation Training Series
Maximizing Efficiency: Designing Drip Irrigation Systems with Tape, Tubing, and Emitter line

Irrigation Training Series

Play Episode Listen Later Feb 23, 2023 50:15


It's important to select the right tubing, tape, or emitter line size for your application to ensure your drip irrigation system delivers the right amount of water to your plants. Careful consideration of factors such as flow rate, water pressure, and emitter spacing helps ensure your system is designed for optimal performance. Cory Broad, Irrigation Association Certification Board Member, steps through a process that can help you make the right choice for what you need. During this webinar, you will learn the following: The many offerings Jain Irrigation offers across multiple product classes to help end-users achieve the highest efficiency in irrigation. Learn what sizes are available and what applications various tubing, tape, and emitter line products can be used. Break down the economic and agronomic impacts of choosing the correct size products and learn how Tubing, Tape, and Emitter line sizing affects irrigation design and management.

Energi Talks
Alberta tightens industrial emitter carbon tax, but is it enough?

Energi Talks

Play Episode Listen Later Dec 16, 2022 44:46


Markham interviews Scott MacDougall, a senior advisor with the Pembina Institute focused on carbon pricing, about the improvements to Alberta's TIER industrial emitter carbon tax announced recently.

Sequences Magazine
Sequences Master No 223 Extended

Sequences Magazine

Play Episode Listen Later Dec 9, 2022 237:27


it's time to say goodbye to another year with our final edition of 2022. From the team, Mick, Mike, Andy & Karan, big thanks to all the musicians & labels for their support throughout the year and our worldwide listeners. Have a Happy Christmas & New Year. Download bio pages: https://sequencesmagazinecom.wetransfer.com/downloads/8c605112795ee8958149aad8b5a4336420221209085214/c97d4def45aaa6687a7a3fd9a240f3f320221209085215/2e7e6d Playlist 224 01.39 Walter Holland ‘Event Horizon' (album Music 101, The Free electronic Pieces) https://walterholland.bandcamp.com 09.38 Computerchemist ‘Where The Clouds Touch The Sky' (album Where The Clouds Touch The Sky) ***https://computerchemist.bandcamp.com 18.45 Moonbooter ‘Goodbye Bye My Friend' (album Reminiscence) www.mellowjet.com 24.45 Moonbooter ‘Me In The Mirror' 31.37 Andrew Douglas ‘Rhine-Sunset' www.andrewjdouglas.com 34.35 Andrew Douglas ‘Quiescent Force' album Emitter) https://andrewjdouglas.bandcamp.com/album/emitter 37.46 Lorenzo Montanà ‘Mosaiche' (album Decorar Silenzio)  projektrecords.bandcamp.com name-your-price 43.04 Lorenzo Montanà 'Soffuso' 48.49 This Immortal Coil, Shannon Wright, Christine Ott, Aho Ssan ‘A White Rainbow' (album The World Ended A Long Time Ago' https://thisimmortalcoil.bandcamp.com/album/the-world-ended-a-long-time-ago 55.09 Gilda Razani & Hans Wanning ‘Matab for Theremin & Synthesiser' https://gildarazani.de/ 57.17 d'Voxx ‘Julia'(album 1984) https://dinrecords.bandcamp.com/album/1984-din75 01.03.07 d'Voxx ‘The Place Where There Is No Darkness' 01.08.19 Paul Nagle ‘Ancients Intercede' (album Approximation Index) https://paulnagle.bandcamp.com/album/approximation-index 01.14.08 Paul Nagle ‘Atheism Inferred' 01.16.58 mypan ‘The Sudden Collapse Of The Circle' (album Mix Caseo Patina) https://syngate.bandcamp.com 01.19.14 mypan ‘White And The Black Point' 01.24.08 Argyre Planitia ‘Pharos Crater'(album The Great Dark Spot) https://winter-light.bandcamp.com 01.30.18 Argyre Planitia ‘Messina Chasmata' 01.37.48 Ô Lake ‘Everest' (album Still) https://olakemusic.bandcamp.com 01.42.35 Ô Lake ‘Here' 01.46.27 Bernd Scholl ‘Heaven Can Wait' (EP Quiet Time) www.bscmusic.com 01.49.52 Joerge Dankert ‘Sad Sounds' (album Messages) https://joerg-dankert.bandcamp.com 01.56.00 Joerge Dankert ‘Mils Comms But Hope' 02.03.54 José Javier Castro ‘Per Gianni parte 1' (Melodía a Gianni Toti' (7"/ DL) *** http://buhrecords.bandcamp.com/ 02.06.53 Ann Licater ‘Follow The Call (Horizons' (album Whispers from Earth) https://annlicater.bandcamp.com/album/whispers-from-earth 02.10.48 Ann Licater ‘Whispers From Earth' 02.14.51 Amie Waters ‘Umbra' (album Cosmos Of The Soul) https://amiewaters.bandcamp.com/album/cosmos-of-the-soul 02.19.08 Amie Waters ‘Noche Oscura' 02.24.21 Nautilus ‘Autumn Light' (album The Mystery Of The Waterfalls ) https://nautilus-nedland.de 02.29.22 Nautilus ‘Awakening In The Deep' 02.34.29 Nautilus ‘Departure' (album A Floating City) 02.40.27 Mike Hans Steffl ‘Bitter Sweet' (album Theatre Splinter) https://mikehanssteffl.bandcamp.com/album/theater-splinter 02.49.03 Mike Hans Steffl ‘Brute Force' 02.54.19 Mac of BIOnight ‘Magnitude Part 13' (album Magnitude) https://macofbionight.bandcamp.com/album/magnitude 02.58.13 Mac of BIOnight ‘Magnitude Part 10 03.01.57 Faber ‘Collide With The Earth' (album Sequentium) www.mellowjet.com 03.06.35 Faber ‘Fantasy' 03.13.26 Skoulaman & Ron Boots ‘Exit33' (album Hot August Afternoon) www.groove.nl 03.25.32 Andreas Baaden ‘Sensing Cover' (album Nightwalk) www.mellowjet.com 03.29.30 Andreas Baaden ‘Think First And Do The Second Move' 03.33.33 Fratoroler 'Somewhere In Your Mind' (album Landscape) https://syngate.bandcamp.com 03.43.17 Christopher Caouette ‘Flight Of Cedarsong' (album Tale Of The Oakenwish) https://christophercaouette.com/Shop/ 03.47.02 Christopher Caouette ‘Forest Of Wishes' 03.49.09 Norman Krusche ‘Aquilo Gelidus' (album Hiems Borealis) https://music.apple.com/mr/album/hiems-borealis/1631154343 Edit ***

Wessex LMCs Podcasts
If the health sector were a country, it would be the fifth-largest emitter on the planet...

Wessex LMCs Podcasts

Play Episode Listen Later Oct 13, 2022 17:33


Angela Hayes, Clinical Nurse Specialist at The Christie Foundation Trust in Manchester, talks to Dr Laura Edwards about the sustainability projects she is involved in, and how we can think about our carbon footprint more in healthcare. Green Team Competition ‘The gloves are off' campaign

Lexman Artificial
Ruction and Piaget: What Are the Implications?

Lexman Artificial

Play Episode Listen Later Jul 3, 2022 6:35


In this episode, host Lexman examines the implications of Jean Piaget's theory of cognitive development on the idea of "ruction." Lexman asks Norman Naimark, a professor emeritus at the University of California, San Diego, to share his thoughts on the matter.

Pacific Beat
China is the world's biggest greenhouse emitter. As it looks to gain influence in the Pacific, could that change?

Pacific Beat

Play Episode Listen Later Jun 13, 2022 5:41


As it looks to cement its presence in the region, China has promised development, aid, trade deals and security support to several Pacific nations. But there's one thing Pacific leaders say they want more than anything, and that's action on climate change.

The Economy, Land & Climate Podcast
Is Drax UK's single biggest CO2 emitter? Think-tank Ember give us the answer

The Economy, Land & Climate Podcast

Play Episode Listen Later Nov 2, 2021 16:46 Transcription Available


Alasdair from ELCI talks to Phil MacDonald, Chief Operating Officer of think-tank Ember, about the the energy think-tank's latest analysis which places Drax as the UK's single biggest emitter of carbon dioxide in the UK and among the top 5 emitters in Europe.  Phil provides a startling explanation of how a huge amount of carbon emissions are being missed, and how incentives exist for governments to use biomass for power because of an apparent accounting loophole around its use.

This Is Why
Canada's biggest emitter

This Is Why

Play Episode Listen Later Oct 22, 2021 19:37


Oil and gas is the largest greenhouse emitter of Canadian industry. But given its place in the economy, politicians and policy makers are weighing how it fits in with the country's emission goals. On this episode of This Is Why, we look at what provincial and federal governments could and have done to address Canada's biggest emitter. Contact: Adam Toy - @Adam_Toy on Twitter Dave McIvor - @dmcivor770 on Twitter This is Why - @ThisIsWhy on Twitter Email us - thisiswhy@globalnews.ca Guests: Chris Severson-Baker, Alberta director of the Pembina Institute See omnystudio.com/listener for privacy information.

BizNews Radio
Flash Briefing: Eskom world's biggest sulfur dioxide emitter; NUMSA strike; Covid-19 vaccine certificate launched

BizNews Radio

Play Episode Listen Later Oct 5, 2021 2:13


News headlines: *Eskom Holdings SOC Ltd., South Africa's coal-reliant power utility, has become the world's biggest emitter of sulfur dioxide, a pollutant linked to ailments ranging from asthma to heart attacks, the Centre for Research on Energy and Clean Air said. *Members of the National Union of Metalworkers of South Africa started a national strike on Tuesday following a deadlock in negotiations for a new wage deal. *South Africa's digital Covid-19 vaccine certificate, which features a scannable QR code, has been launched by the department of health.

Ask Ronna
Yadvina's Keys to The Carriage House: The Nocturnal Emitter & Lobsters Take Two (Patreon 26)

Ask Ronna

Play Episode Listen Later Sep 7, 2021 82:06


Ronna (& Bryan) are still on their Free Feed break, but a certain Ukrainian housekeeper is back in Marblehead with a little gift for you. Once again, it's the keys to The Carriage House and a sneak peek at Patreon! This week we travel back to August 7, 2020, with Patreon 26. Agent Provocateur Ronna & CCEO (Bryan) are here with a doozy of a question about what to do when you wake up to your partner energetically masturbating in bed next to you while you're trying to sleep. Then it's on to matters less risqué, including proper bidet etiquette and what to do if your neighbors aren't reciprocating your offers to socialize. Also, (Bryan) took Ronna's notes from the previous week and offers up a new version of the Lobsterman's commercial. We think you'll agree it's...got more panache. Do you want access to The Carriage House every week? Join us on Patreon! Just $5 a month gets you an ALL NEW episode every Friday...even during our Free Feed break! patreon.com/askronna The Negronna is a drink for all seasons! Fall is just around the corner, and there's nothing better to sip while waiting for the sweater weather to arrive than a balanced and boozy Negronna. Go to negronna.com to get yours today, and don't forget that tax and shipping are included on all domestic orders. And speaking of impending sweater weather, it's almost time for us to take the ice out of our delicious Ask Ronna Coffee. Warm up with a cup of Carriage House Blend or Shades of Vanilla, and subscribe and save $3 per bag at askronnacoffee.com

The Critical Hour
Earth Warming Faster Than Previously Thought; US Military Largest Emitter of Greenhouse Gas

The Critical Hour

Play Episode Listen Later Aug 9, 2021 116:43


Ted Rall, political cartoonist and syndicated columnist, joins us to discuss New York Governor Andres Cuomo's sexual harassment scandal. Melissa Derosa, the Governor's top aide, has resigned in what appears to be the start of a mass exodus of the Governor's closest supporters. Also, an executive assistant who accused Cuomo of groping her has come forward.Dan Lazare, investigative journalist and author, joins us to discuss his latest article on domestic US politics. Lazare argues that US partisan politics has devolved into non-substantive emotional spats. Rather than genuine politicians who aim to represent their constituents, he posits that "Congress overflows with hyper-ambitious types willing to do and say anything to advance their careers and serve the interests of capital."Alexander Mercouris, editor-in-chief at theduran.com & host of "Alexander Mercouris & The Duran" on YouTube, joins us to discuss his latest article on Julian Assange. Mercouris argues that "the single-minded U.S. pursuit of Julian Assange as Britain proposes changes to its official secrets law shows the fierce determination of both governments to conceal their secrets."Marvin Weinbaum, director for the Middle East DInstitute's Center for Pakistan and Afghanistan Studies, joins us to discuss Afghanistan. The pace of the Taliban's victories quickens as the theocratic political group over-runs three major cities in a single day. Also, one of the cities that they seized was a provincial capital. How long before the Taliban controls the entire nation?Marcy Winograd, congressional coordinator for Code Pink, joins us to discuss climate change. Brown University's "Cost of War" project reports that the US military creates more greenhouse gases than Denmark, Sweden, or Portugal with the "War on Terror" alone. Marcy's consortium news article argues that the US military is killing humanity in more ways than simply bombs and bullets.Gerald Horne, professor of history at the University of Houston, author, historian, and researcher, joins us to discuss the latest pushback on the Monroe Doctrine from the Global South. We review "Operation Tradewinds," where soldiers from South America and the Caribbean participated in a region-wide military exercise with army personnel from the United States empire. This neo-colonial exercise threatens indigenous political independence.Scott Ritter, former UN weapon inspector in Iraq, joins us to discuss the latest US wargame. Last October, a wargame predicted that a defence of Taiwan would end disastrously for the US military as the loss of communication rendered their smart weapons inoperable. As US wargames have historically been accurate predictors of military outcomes, the US needs to reevaluate its aggression towards other major world powers.Miko Peled, author and activist, joins us to discuss Israel. A Palestinian survivor talks about his time as an Israeli prisoner, and reveals the methods of torture that were used against him and others. Also, dozens of Palestinians and Jordanians have been sentenced in Saudi Arabia after a mass trial.

The Guitar Knobs
229-Interview with Ian Pritchard of Collector//Emitter

The Guitar Knobs

Play Episode Listen Later Aug 9, 2021 83:18


The Knobs interview Ian Pritchard founder of Collector//Emitter. Ian loves the noisey side of the sound spectrum has created a sizeable YouTube guitar demo channel with a special focus on the weird and wonderful tones and effects. Hosted by Todd Novak with Jared Brandon, and Tony Dudzik     Guitar, electric guitar, guitar pedal, pedal effects, pedal fx, guitar amplifier, humbucker, single coil, P90, guitar pickups, guitar setup, fuzz, overdrive, delay, reverb, distortion, guitar player, guitarist, guitar tips, guitar repair, vintage guitar, guitar amp speakers, guitar cabinet, combo amp, guitar amp Visit us at theguitarknobs.com Support our show on Patreon.com/theguitarknobs

PBS NewsHour - Segments
Can concrete, a major Co2 emitter, be made greener?

PBS NewsHour - Segments

Play Episode Listen Later Aug 8, 2021 8:29


After water, concrete is the most consumed substance on the planet and its production is expected to grow from 4.4 billion tons to 5.5 billion tons by 2050. But its production, which involves cement, comes at a huge environmental cost -- accounting for almost eight percent of carbon emissions globally. Mori Rothman reports on the industry's attempt to reduce concrete's carbon footprint with cleaner cement. PBS NewsHour is supported by - https://www.pbs.org/newshour/about/funders

PBS NewsHour - Science
Can concrete, a major CO2 emitter, be made greener?

PBS NewsHour - Science

Play Episode Listen Later Aug 8, 2021 8:29


After water, concrete is the most consumed substance on the planet and its production is expected to grow from 4.4 billion tons to 5.5 billion tons by 2050. But its production, which involves cement, comes at a huge environmental cost -- accounting for almost eight percent of carbon emissions globally. Mori Rothman reports on the industry's attempt to reduce concrete's carbon footprint with cleaner cement. PBS NewsHour is supported by - https://www.pbs.org/newshour/about/funders

The Sunday Session with Francesca Rudkin
Bernadette Casey: Textile industry is the third biggest carbon emitter behind agriculture and oil/gas

The Sunday Session with Francesca Rudkin

Play Episode Listen Later Jul 17, 2021 7:50


Alongside oil, gas and agriculture, the textile industry is one of the biggest carbon-emitters.Annually 220,000 tonnes of used clothing and the like enters landfills.New Zealand company Usedfully is trying to change that. They have sent recommendations to the Government and a hui date is set down for September.Usedfully co-founder Bernadette Casey says nothing really shocked her from their reports on landfill data."[Textiles] are quite low volume but what wasn't understood was the impacts, so while it might be low in volume it's extremely high in embedded carbon."LISTEN ABOVE

Global News Podcast
Brazilian Amazon now a net emitter of greenhouse gases

Global News Podcast

Play Episode Listen Later May 1, 2021 31:32


The Brazilian part of the Amazon rainforest has released 20% more carbon dioxide into the atmosphere in the past decade than it has absorbed. Also: Israel buries first victims after festival crush, and the surge in men using Botox to look better.

Bill Kelly Show
Bill Gates, Climate Warrior. And Super Emitter, Tim Schwab joined Bill Kelly

Bill Kelly Show

Play Episode Listen Later Feb 18, 2021 17:31


During the pandemic, Bill Gates’s personal fortune has increased by an impressive $20 billion, but even these gains pale in comparison to his soaring political influence—as the news media has widely trumpeted his leadership on Covid-19, praising his charitable donations or extolling him as a “visionary” who predicted the outbreak. It’s a highly questionable narrative, one that ignores widespread controversy over the way Gates made his fortune and how he chooses to spend it, but which nonetheless has delivered a windfall of political capital for our philanthropist in chief—which he is now spending down. Here is the link to the full story:  https://www.thenation.com/article/environment/bill-gates-climate-book/ GUEST: Tim Schwab, Freelance Journalist writing about the Gates Foundation See omnystudio.com/listener for privacy information.

Boyer Lectures - ABC RN
01 | Oil vs Water — Confessions of a carbon emitter

Boyer Lectures - ABC RN

Play Episode Listen Later Jan 24, 2021 28:45


In this first Boyer lecture, leading philanthropist and businessman Andrew Forrest calls for an urgent move to green hydrogen "on a global scale". For Dr Forrest, the question is not whether green hydrogen will become the next global energy form, but who will be the first to mass-produce it?

Lichttechnik-Podcast
Der Lichttechnik-Podcast – Folge 24 – weitere optische Sensoren

Lichttechnik-Podcast

Play Episode Listen Later Dec 24, 2020 18:23


Sprecher: Inhalt in dieser Folge:  Fototransistor Ein lichtempfindlicher Transistor als npn oder pnp Ausführung. Verstärkungsfaktor liegt bei ca 100 – 1000. Meist werden bei diesen Transistoren nur der Kollektor und der Emitter herausgeführt. Eine Version bei dem die Basis herausgeführt wird kommt seltener vor.  Sie sind empfindlicher als Photodioden aber auch langsamer. Einsatz bei Dämmerungsschalter, Lichtschranken, Optokoppler. Die maximale Empfindlichkeit bei einem Silizium –Fototransistors liegt bei ca. 850nm. […]

And We Got Older
24 - The Mouth is a Scary Sound Emitter

And We Got Older

Play Episode Listen Later Oct 29, 2020 54:16


This week Andrew talks about Hades the greatest rogue-like to ever exist (it's true, I promise). Coby takes a trip to 2089 in the saw-distic Disc Room. We end the episode with a discussion on horror games and what they need to be horrifying. Happy Halloween everyone!

Green Industry Leaders Network
Choosing the Right Emitter for Your Drip System

Green Industry Leaders Network

Play Episode Listen Later Sep 11, 2020 34:01


No matter where you live, installing a drip system helps ensure that you get water right where the plant needs it. But how do you know if you're using the right emitter and delivering the right amount of water to the plant?With several drip irrigation options, it's easy to grab whatever is available and hope it's right. 1 GPH, 4GPH, button emitters, mini stake sprinklers, shrubblers or bubblers... how do you decide?? How do you take  out the guess work select the correct one based on the plant's needs? What's the formula or science behind choosing the right one?Our guest, Michael Derewenko, Territory Sales Manager and Marketing Manager at Jain Irrigation, helps provide his expert advice and what you should factor when choosing. Considerations include;Crop Coefficients: (breaks down how we calculate a plants demand)SDCWA Landscape Guide: (shows relevant plant watering demands)JAIN Contractor Design Guide: (tips on how to convert to drip and apply water with drip)JAIN Complete Home Garden Kit: (all in one kit for home gardeners)CONNECT WITH OUR GUESTHave questions about this episode or drip irrigation systems? Connect with Michael on Twitter @MDSavesWater and Jain's Facebook and Instagram.CONNECT WITH USEnjoy this episode or have questions? We want to hear from you. Connect with Chris Sabbarese at Corona Tools on Twitter and our GILN Facebook Group. This closed group is like-minded individuals who care about and discuss, gardening and plants, trees and landscaping related topics. 

Irrigation Training Series
Episode 37: Opportunities In Irrigation with Michael Pippen & Richard Restuccia

Irrigation Training Series

Play Episode Listen Later Aug 5, 2020 38:50


My guest will be Michael Pippen, Director of Business Development at Jain Irrigation. Michael is involved in agriculture and irrigation and been exposed to many opportunities often overlooked. Michael is active with the irrigation association and worked in farming, irrigation, and manufacturing. We will review opportunities in agricultural and landscape irrigation and uncover opportunities available to anyone in or thinking of joining the irrigation industry. It will be an informative session providing solid direction for planning your first or next move in the irrigation industry. Special Guest: Michael Pippen.

Irrigation Training Series
Episode 35: Design, Maintenance and Management of Landscape Irrigation with Tom Raden & Richard Restuccia

Irrigation Training Series

Play Episode Listen Later Jul 29, 2020 48:30


I hope you can join us for a training session on – Design, Maintenance and Management of Landscape Irrigation this Wednesday, July 29, at noon PDT. This week we are joined by Tom Raden, from Par 3 Landscape Management in Las Vegas. I wrote this cover article about Tom a couple of years ago, titled, Win By Slashing Clients’ Water Bills, he and Par 3 have continued to accelerate their business using water management as an edge over the competition. This is an opportunity to learn from one of the best irrigation managers in the country and Tom will cover the following: The importance of irrigation in landscape Drip irrigation beyond the design – how contractors can best understand irrigation designs Irrigation maintenance Irrigation management Special Guest: Tom Raden.

Irrigation Training Series
Episode 34: Fertigation for Indoor Growers with Frank Toves & Richard Restuccia

Irrigation Training Series

Play Episode Listen Later Jul 24, 2020 34:08


This week we are joined by Frank Toves, from Irrigation Design and Construction (IDC), to explain the basics of setting up a successful fertigation process for indoor growers. Frank discusses a step by step process for fertigation. He also shows how automation with irrigation helps growers reduce labor and increase yields. Frank looks forward to demonstrating the and answering all the questions you have about fertigation. This is a unique opportunity to discuss fertigation with one of the experts in the industry. Special Guest: Frank Toves.

Irrigation Training Series
Episode 33: How The Agralogics Integration In Jain Logic™ Makes You A Better Grower with Ryan Mcneish & Richard Restuccia

Irrigation Training Series

Play Episode Listen Later Jul 22, 2020 27:36


This week we are joined by Ryan McNeish, VP of Technology at Jain Irrigation and founder of PureSense, to explain the value of the integration and show how this makes growers more efficient. Ryan will demonstrate how the satellite imagery appears on the Jain Logic™ mapping tool. He also shows how easily users access this critical information to speed irrigation decision making. Now faster than ever, users quickly identify and react to irrigation issues and, in some cases, spot issues before they become problems. Ryan is looking forward to demonstrating this feature and answering all the questions you have about the integration. This is a unique opportunity to discuss Jain Logic™ with one of the developers. Special Guest: Ryan Mcneish.

Irrigation Training Series
Episode 32: Management Leaders and the Irrigation Industry with Stacy Sturnot, Tracy Wankner, Nicole Hill, Corrine Crawford & Richard Restuccia

Irrigation Training Series

Play Episode Listen Later Jul 17, 2020 51:41


Join us this Friday for a special episode of our JAIN webinar series. This week we join some of the best SoCal management leaders in Landscape and Property Management. We welcome four women that sit atop their given management fields to bring us expertise from their perspective: Stacey Sturnot, Executive Operations Manager for Landscapes USA Tracy Wankner with Worth Property Management, Nicole Hill, Director of Landscape Operations at Irvine Company Office properties Corrine Crawford from Powerstone Property Management They will all be here to answer our questions and explain some of the dynamics they face in day to day operations Special Guests: Corinne Crawford, Nicole Hill, Stacey Sturnot, and Tracy Wanker.

Irrigation Training Series
Episode 31: Amnon - The Revolution of In-Line Drip Emitters with Kevin Stewart & Richard Restuccia

Irrigation Training Series

Play Episode Listen Later Jul 15, 2020 41:16


In this webinar we’ll discuss the importance of a low CV (coefficient of variation) and the positive impact it will have on your irrigation system. You’ll also learn about all the applications in both agriculture and landscape industries. During this webinar you will also learn how to win a new Apple iPhone 11 from Jain simply by submitting a video or photos. I look forward to seeing you on Wednesday, July 15 at noon. Amnon is a an innovative, pressure compensating drip line utilizing the Cascade Labyrinth technology and includes special anti-siphon and compensating non-leak models. Amnon CNL (Pressure Compensated Non-Leak) is ideal for pulse irrigation and systems you prefer not to drain during irrigation cycles. Amnon AS (Pressure Compensated Anti-Siphon) is ideal for on-ground or buried applications. Amnon emitterline is the choice for greenhouses, vegetables, vineyards and orchards. Special Guest: Kevin Stewart.

Irrigation Training Series
Episode 30: Transformational Irrigation Technologies for 2020 with Aric Olson & Richard Restuccia

Irrigation Training Series

Play Episode Listen Later Jul 10, 2020 51:08


Irrigation technologies are present in Agriculture, Landscape, Nursery/GH, Golf, and Mining. Incredible advancements are happening in each of these industry segments. Some of the tools and technologies in one specific sector may be utilized, all or in part in another segment, to help us save water or grow better crops with fewer resources. Please join Aric Olson, President at Jain Irrigation and AgTech visionary, to learn about technology trends that will increase in 2020 and beyond. He provides a framework for where technologies have come from and how they can be applied to other market segments. Aric and Jain Irrigation, due to their technology acquisitions across multiple segments over the past few years, are in the perfect position to see the future of irrigation. We are fortunate he is going to share it with us this Friday.

Irrigation Training Series
Episode 29: Ultimate Guide to Creating and Managing a Water Budget with Ken Olson, Jim Kauth, Andy Belingheri & Richard Restuccia

Irrigation Training Series

Play Episode Listen Later Jul 8, 2020 47:48


In this session you will learn a step by step process to create a water budget for a commercial property or HOA. Attendees will also learn how to manage water to the budget. In addition learn how to communicate the value of budgets and water management with property owners and managers. We cover all the steps needed to make water budgets a success for your property. Special Guests: Andy Belingheri, Jim Kauth, and Ken Olson.

Irrigation Training Series
Episode 28: Distribution Uniformity: A Key to Grower Profitability with Michael Pippen & Richard Restuccia

Irrigation Training Series

Play Episode Listen Later Jul 1, 2020 47:41


Please join us for this webinar to learn the importance of maintaining a high distribution uniformity (DU) in your farming operations. We’ll discuss the savings of water, electricity, and other inputs to help you optimize your irrigation system and increase yield in quality in your field. Special Guest: Michael Pippen.

Irrigation Training Series
Episode 27: Agriculture & Landscape Photography with Michael Derewenko & Richard Restuccia

Irrigation Training Series

Play Episode Listen Later Jun 26, 2020 53:47


The landscape, agriculture and irrigation industry is reliant on marketing materials that include crisp and colorful images. In this week’s webinar we show contractors, growers, architects and distributors how to shoot proper photos of their properties. Subjects we’ll cover include: Basics of Photography File Management and Software Used Lighting Easy Framing and Lighting Tips iPhone Photography Special Guest: Michael Derewenko.

Irrigation Training Series
Episode 26: Hot Tips for Hot Times with David Lindsey & Richard Restuccia

Irrigation Training Series

Play Episode Listen Later Jun 24, 2020 23:43


The summer heat is on. During this webinar you will learn how to use Jain Logic weather data and alerts to make better irrigation and field staff safety decisions. David Lindsey has worked in irrigation through his fair share of hot summers and will share his best tips and tricks to make summer more profitable for you. You will come away with water management steps you can start taking right away. Special Guest: David Lindsey.

Irrigation Training Series
Episode 25: Filtration: Selecting The Right System with Kevin Stewart, Justin Evans, Arthur Howell & Richard Restuccia

Irrigation Training Series

Play Episode Listen Later Jun 19, 2020 51:22


In this webinar we’ll discuss in-depth the NEED and DEGREE of filtration to help protect your investment. With many filtration options available, we’ll discuss the two best options that JAIN Irrigation provides and determine which one is the right filtration for your system. Special Guest: Kevin Stewart.

Irrigation Training Series
Episode 23: What the Irrigation Association is doing for you with John Farner & Richard Restuccia

Irrigation Training Series

Play Episode Listen Later Jun 17, 2020 44:59


Members expect a lot from their associations especially during difficult times. These times may be the most difficult we have faced. The Irrigation Association has been very proactive in helping members and this is an opportunity to learn about their progress and decide how you and your business can take advantage of the associations work. Please join John Farner, Government and Public Affairs Director for the Irrigation Association, and Richard Restuccia, VP Water Management Solutions, Jain Irrigation, for a discussion about what the Irrigation Association is doing for its member during this abnormal time. The Irrigation Association (IA) is the leading membership organization for irrigation equipment and system manufacturers, dealers, distributors, designers, consultants, contractors and end users. IA is dedicated to promoting efficient irrigation technologies, products and services. The association serves its members and the irrigation industry by: Educating the public on sound practices and water management. Serving as a centralized clearing house for research and innovation. Improving industry proficiency through continuing education. Recognizing and promoting experience and excellence with professional certification. Lending expertise to water-use public policy at the local, state, regional and national level. In 2010 the Association named July “Smart Irrigation Month” in order to promote water conservation in that month, which represents the peak water usage in the U.S. annually. Special Guest: John Farner.

Irrigation Training Series
Episode 24: Using Infiltration Data to Adjust Irrigation Scheduling with David Lindsey & Richard Restuccia

Irrigation Training Series

Play Episode Listen Later Jun 12, 2020 25:12


Learn how to read and interpret infiltration data from the Jain Logic Infiltration Widget and use the information to make irrigation schedule adjustments to keep water in the target root zone. Special Guests: Connor Cunningham and David Lindsey.

Irrigation Training Series
Episode 22: Getting a Grip on Drip with Andy Belingheri & Richard Restuccia

Irrigation Training Series

Play Episode Listen Later Jun 10, 2020 50:31


Andy Belingheri shows how to evaluate an irrigation system for proper design, installation and use. He discusses drip components and teaches us when they are installed in the right place(where do I place my drip emitters), and for the right time (how long do I run my system). Special Guest: Andy Belingheri.

Irrigation Training Series
Episode 21: Combining JAIN Irrigation Technologies To Amplify Individual benefits with Michael Pippen & Richard Restuccia

Irrigation Training Series

Play Episode Listen Later Jun 5, 2020 44:45


Learn how combining multiple Jain Irrigation technologies magnify individual benefits and improves your results. Using individual Jain components increases your success factor considerably, and when you combine several technologies, results increase dramatically. Please join Michael Pippen on Friday to learn how watermelon producers in the boot heel of Missouri combined multiple Jain technologies with great success. Special Guest: Michael Pippen.

Irrigation Training Series
Episode 20: Customer Centric Service at Jain Monitoring & Control with Bill Freeman, Richard Gates, Santino Bianchi, Jeff Tuel & Richard Restuccia

Irrigation Training Series

Play Episode Listen Later Jun 3, 2020 50:31


Experienced, knowledgeable, tech savvy, caring, honest, detailed, tenacious, loud, quiet and hard working. All words used to describe the people that make up the JMC Service Team. Join us for this webinar to meet each team member, learn how we monitor and troubleshoot your Jain Logic system 24/7 and maintain industry leading up-time across thousands of sites. Special Guests: Bill Freeman, Jeff Tuel, Richard Gates, and Santino Bianchi.

Irrigation Training Series
Episode 19: JAIN Growroom Solutions with Michael Derewenko & Richard Restuccia

Irrigation Training Series

Play Episode Listen Later May 29, 2020 49:53


Growing plants inside can be a challenge, we’d like to shine some light on the subject. This Friday JAIN is offering a webinar focused on the irrigation of plants indoors and the components involved in such an installation. We hope you will join us for a presentation on the benefits of valve control, emission devices, flushing and automation in an indoor system. Special Guest: Michael Derewenko.

Irrigation Training Series
Episode 18: Selecting the Correct Drip Tape for Your Crop with Kevin Stewart & Richard Restuccia

Irrigation Training Series

Play Episode Listen Later May 27, 2020 56:09


Jain Irrigation understands the difference and diversity of crops grown throughout the country – this is why Jain has made the investment in different drip technologies to limit a “one-size-fits-all” approach. Join us for this webinar to learn which Jain Drip Tape might be best for your cop application! Special Guest: Kevin Stewart.

Irrigation Training Series
Episode 17: Building Irrigation Sets Using Jain Logic™ with Richard Gates, David Lindsey & Richard Restuccia

Irrigation Training Series

Play Episode Listen Later May 22, 2020 39:07


We know the exact reasons why we irrigate our crop; our plants need water to grow successfully and give us a good ROI on our investment and hard work. Wouldn’t it be nice to have an easy way to know; when did I irrigate, how long did my system run and how much water did I apply? There is a tool within the Jain Logic™ application that allows you to outline your field on a map, add some basic information about the irrigation system being used in that field and track and report on the use of that water. We are going to show you how to use this valuable tool during our session on Friday. I look forward to you joining us. Special Guests: Connor Cunningham and David Lindsey.

Irrigation Training Series
Episode 16: Placement and Sizing of Air Vents with Cory Broad & Richard Restuccia

Irrigation Training Series

Play Episode Listen Later May 20, 2020 36:48


Learn the importance and benefit of using air vents in your irrigation system. In this webinar we’ll teach you the background of air vents, the different styles for best-application, and where to place air vents to maximize the performance of your drip and micro irrigation system Special Guest: Cory Broad.

Irrigation Training Series
Episode 15: Monitoring Your Irrigation Filter Station using Jain Logic Pulse™ with Connor Cunningham & Richard Restuccia

Irrigation Training Series

Play Episode Listen Later May 15, 2020 37:55


Monitoring filter station 24/7 gives growers peace of mind that their filtration system is operating at maximum performance to protect their crop and irrigation system. Always on and always monitoring Pulse keeps an eye on your system to ensure it’s performing as expected; highlighting problem areas and reporting water use. Jain Pulse is your silent partner, monitoring your filter station health 24/7. Learn how using Pulse will help to track water consumption across the farm while also letting you know when issues arise so they can be fixed in a timely matter. We will give an overview, show examples of the hardware and software that go into Jain Pulse. Special Guest: Connor Cunningham.

Irrigation Training Series
Episode 14: HOA Success Stories: Managing Escalating Water Budgets with Andy Belingheri, Jim Kauth, Ken Olson, Rebecca Pollon & Richard Restuccia

Irrigation Training Series

Play Episode Listen Later May 13, 2020 60:29


For many HOAs, landscape irrigation currently accounts for 90 percent or more of all the water used at their properties. Combined with increasing cost of water and knowing as much as 50 percent of water use outdoors is wasted due to inefficient irrigation methods and systems, planning, and investing in water conservation can have a huge payoff for an HOA. Please join us for this live online panel session to hear special guest speakers representing two of the largest HOA planned communities in the Western US – Sun City Grand in Surprise, Arizona and Rossmoor in Walnut Creek, California – talk about their success in reducing outdoor water consumption that led to an immediate reduction in water bills. Conserving water is good for the planet, communities, and an HOA’s bottom line – preserving its reserve funds. You’ll learn in this session strategies for saving water and money on landscape irrigation while improving property value. Special Guests: Andy Belingheri, Jim Kauth, Ken Olson, and Rebecca Pollon.

Irrigation Training Series
Episode 12: Top 10 Factors For A Good Ag Irrigation Design with Perry Continente & Richard Restuccia

Irrigation Training Series

Play Episode Listen Later May 6, 2020 50:22


In this session you will learn key factors to consider when designing a micro irrigation solution. You will hear about the software Perry uses and why. Attendees will learn good goals for proper irrigation design, and terms and definitions to make your design experience better. This is for designers, users and owners of agricultural irrigation systems. Special Guest: Perry Continente.

Irrigation Training Series
Episode 11: Setting Boundaries and Alerts on Jain Logic™ with Richard Gates, David Lindsey & Richard Restuccia

Irrigation Training Series

Play Episode Listen Later May 1, 2020 32:07


In this session David Lindsey and Richard Gates will lead you step by step on the process of setting boundaries and alerts on Jain Logic. These practices help you better manage water in your fields leading to reduced water use and costs. After attending this session attendees will be able to better evaluate the benefits of Jain Logic and become more proficient using the software. It is a must see session for anyone thinking about using field monitoring and control or current users of Jain Logic who want to improve their skill

Irrigation Training Series
Episode 8: In-depth Look at Satellite ETc and NDVI Analytics and Applications with Sumer Johal, Jeff Tuel & Richard Restuccia

Irrigation Training Series

Play Episode Listen Later Apr 22, 2020 58:51


In the past we have briefly touched on the use of remotely sensed ETc to optimize irrigation. In this webinar we have invited Sumer Johal, CEO and Founder of Agralogics, to share a more in-depth look at the numerous applications of satellite based information. We will go beyond just the images and talk about the importance of using analytics in specific on-farm applications, including pest pressure, irrigation system performance, nutrient deficiencies and soil disparities. You will see actual images, analytics and learn how to look for potential problems in the field long before the human eye can detect them. Special Guests: Jeff Tuel and Sumer Johal.

Irrigation Training Series
Episode 13: The State Of The Landscape Industry During COVID-19 with Chris Sabbarese, Jerry L. DeJournett, Shawn Connors & Richard Restuccia

Irrigation Training Series

Play Episode Listen Later Apr 13, 2020 46:32


We have an excellent panel joining us to provide ideas and guidance to help your business not just survive the current situation, but how to thrive. COVID-19 is a challenging situation, and these panelists figured out a way to help customers and keep their teams working. Our panel team comes from manufacturing (Corona Tools), distribution (Horizon), and contracting ( Landscapes USA). You will learn creative ways to solve business challenges you are facing every day. Business is changing for all of us, and these three are leading the change. Special Guests: Chris Sabbarese, Jerry L. DeJournett, and Shawn Connors.

Irrigation Training Series
Episode 5: Control & Automation Applications Using Jain Logic™ with David Lindsey, Jeff Tuel & Richard Restuccia

Irrigation Training Series

Play Episode Listen Later Apr 10, 2020 39:21


In this webinar we will cover how Jain Logic can be used for control and automation in Ag applications. Jain Logic is much more than just the industry leading monitoring system. We will cover installations including pump control, valve control, level sensing and other unique customer uses of Jain Logic to solve real on-farm applications requiring control. Special Guests: David Lindsey and Jeff Tuel.

Irrigation Training Series
Episode 4: The Components of a Drip Irrigation System with Michael Derewenko & Richard Restuccia

Irrigation Training Series

Play Episode Listen Later Apr 8, 2020 55:10


In this week’s training we’ll be reviewing and discussing the key components of a drip irrigation system. We welcome seasoned contractors looking to freshen up and amateurs that want to learn more about what comprises a highly efficient system. Special Guest: Michael Derewenko.

Irrigation Training Series
Episode 3: How to Drip Irrigate Hemp – 10 Key Steps to Grow a Successful Crop with Kevin Stewart & Richard Restuccia

Irrigation Training Series

Play Episode Listen Later Apr 3, 2020 52:21


A recent Cornell University analysis found profits ranged from $130 per acre to as high as $730 per acre for grain and fiber. Compared to soybeans at $200 or less per acre or depending on the market (sometimes a loss) hemp is attractive. Also, hemp grown for CBD ranges in the thousands of dollars per acre price range. Special Guest: Kevin Stewart.

Irrigation Training Series
Episode 2: Irrigation Optimization Using Remotely Sensed ETc and Soil Moisture Monitoring with Jeff Tuel & Richard Restuccia

Irrigation Training Series

Play Episode Listen Later Apr 1, 2020 57:00


The definition of Irrigation Optimization could be hotly debated by academics, growers, agronomists and irrigation industry experts. This short webinar will present a simple definition with a practical strategy using ETc and soil moisture data to sustainably apply irrigation water in frequency and duration to precisely match soil properties with plant water consumption. Grower success stories of achieving water savings of 15% to over 30% will be presented using these strategies. Special Guest: Jeff Tuel.

Irrigation Training Series
Episode 1: Point Source or In-line Irrigation: Which one is right for my landscape? with Andy Belingheri & Richard Restuccia

Irrigation Training Series

Play Episode Listen Later Mar 27, 2020 47:55


A review of the fundamentals, system components, similarities, differences, design variables and ultimately how to choose which drip irrigation approach is best for your landscape. Special Guest: Andy Belingheri.

The Tone Mob Podcast
Ian Pritchard of collector//emitter

The Tone Mob Podcast

Play Episode Listen Later Mar 9, 2020 69:43


On this episode, I am joined by Ian Pritchard. Best known as the man behind the YouTube channel collectore//emitter. We talk a lot about pedals, mojo, emo music and a whole lot more. After you are done with this episode go check out his channel right HERE. Win a $50 Gift Card to Sweetwater by submitting question for the Ask Sweetwater segment at Tonemob.com/asksweetwater Learn more about your ad choices. Visit megaphone.fm/adchoices

Form The Head Podcast
FTH052 - Pulse Emitter (Daryl Groetsch)

Form The Head Podcast

Play Episode Listen Later Feb 7, 2020 65:59


Equally fluent in ambient and noise music, Daryl Groetsch talks with us about the processes involved when creating his spacious works. Decades of learning, growth and experimentation have created a large sonic palette for Daryl’s work as Pulse Emitter. Listen to his latest LP, Swirlings out now on Hausu Mountain.   Intro music: Pulse Emitter - Swirlings - Empty Hold Outro music: Pulse Emitter - Decaying Ships - Decaying Ships 3   http://pulseemitter.com   Support the Form The Head Podcast on Patreon! http://patreon.com/formthehead

CiTR -- Breakfast With The Browns
New Sarah Hennies; Pulse Emitter; Jeff Parker; Winged Victory for the Sullen and Other Delectables...

CiTR -- Breakfast With The Browns

Play Episode Listen Later Jan 27, 2020 183:38


Max Richter; Carl Stone; Aidan Baker; Pan*American; Sarah Hennies; Julia Kent; Aidan Baker / Gareth Davis; Julia Kent; C-Schulz; Pole; Meemo Comma; Pulse Emitter; A Wingerd Victory for the Sullen; Vancouver Women's Ambient Music Collective; Torngat; Gavin Russom; Ela Orleans; Brasstronaut; Cold Specks; Makaya McCraven; Badge Epoque Ensemble; Pheyownah; Jacques Greene & Jeff Parker.

Tesla Owners Online Podcast
Tesla Model 3 Noise Emitter Reverse Sound

Tesla Owners Online Podcast

Play Episode Listen Later Sep 9, 2019 0:27


This is the sound the Tesla Model 3 manufactured as of September 1 2019 makes while in reverse below 19 mph to comply with the new EV noise emitter law.

Tesla Owners Online Podcast
Tesla Model 3 Noise Emitter Forward Sound

Tesla Owners Online Podcast

Play Episode Listen Later Sep 7, 2019 0:18


This is the sound the Tesla Model 3 manufactured as of September 1 2019 makes while in forward below 19 mph to comply with the new EV noise emitter law

The Flame Learning Channel
Particles 101 - Part 1- Intro and Emitter Types

The Flame Learning Channel

Play Episode Listen Later Feb 24, 2016 12:34


The concept behind this series is to cover the basic components and workflows when it comes to using 3D particles. Part 1 gives a brief introduction and shows how to set an easy particle workflow. You also learn about the three types of object that are capable of emitting particles.

Medizinische Fakultät - Digitale Hochschulschriften der LMU - Teil 16/19
Evaluierung neuer nephroprotektiver Strategien in einem Mausmodell der strahleninduzierten Nephropathie durch den ß-Emitter [Lu-177-DOTA0,TYR3]-octreotate mittels in-vivo Tc-99m-MAG3 Nierenfunktionsszintigraphie

Medizinische Fakultät - Digitale Hochschulschriften der LMU - Teil 16/19

Play Episode Listen Later Nov 14, 2013


Thu, 14 Nov 2013 12:00:00 +0100 https://edoc.ub.uni-muenchen.de/16593/ https://edoc.ub.uni-muenchen.de/16593/1/Ilhan_Harun.pdf

Science of War
Joint Threat Emitter Simulates Real Life Attack

Science of War

Play Episode Listen Later Mar 5, 2013


Ritidian Point recently became home to the newest addition in Anderson's effort for better threat readiness. Called the Joint Threat Emitter, these Navy and Air Force radar systems provide a ground threat warning up to the aricraft to simulate a real-life attack.

Science of War
Joint Threat Emitter

Science of War

Play Episode Listen Later Feb 6, 2013


A1C Adam Harder, Reporting 36th Wing Public Affairs: Ritidian Point recently became home to the newest addition in Andersen’s effort for better threat readiness. Called the Joint Threat Emitter, these Navy and Air Force radar systems give aircraft flying from Andersen an opportunity to test their defense procedures. The radars provide a ground threat warning up to the aircraft to simulate a real-life attack. Available in high definition.

Cutting Through the Matrix with Alan Watt Podcast (.xml Format)
May 31, 2010 Alan Watt "Cutting Through The Matrix" LIVE on RBN: "The Mind Masters: Think You're Different -- You're All Canned Peas, Processed, Modified, Your Masters to Please" *Title/Poem and Dialogue Copyrighted Alan Watt - May 31, 2010 (Exempti

Cutting Through the Matrix with Alan Watt Podcast (.xml Format)

Play Episode Listen Later Jun 1, 2010 46:49


--{ The Mind Masters: Think You're Different -- You're All Canned Peas, Processed, Modified, Your Masters to Please: "We're Under the Microscope, Behaviourists' Dream, Who Pass On to World Managers the Info they Glean, They've Endless Data of Personal Information, Supplied Daily By You and Conversation, E-mails, Facebook, Text, You're an Emitter, A Gulliver Yahoo, the Twit in Twitter, The Designer Society, Hedonistic, Narcissistic, Mark IV in the Beehive, Movied-Out, Sadistic, Everything Replaceable, Items, Systems, Lovers, Neutral on Slaughter if it's Rained on 'Others', Unable to Wade through a 'System Textbook', 'Impact of Science on Society', 'The Scientific Outlook', The Me Generation, Blind to All that's Been Done, Perfectly Conditioned, Avoiding Pain, Having Fun, Oblivious of Control, or Global Mandate Directive, Non-Bonding Individually, Perfect for the 'Collective' " © Alan Watt }-- International Socialism (Run, Financed and Owned by International Bankers) - Maurice Strong and Bob Rae - Government as Collector for Debts - Scientifically Designed Society - "The Soviet Story" documentary, George Bernard Shaw - Government-Run Childcare, Extended "Family" of Social Workers - Inoculations to Dumb Down Populations - Socialized Medicine, Cutbacks, Priority Operations, Healthcare Rationing. Bertrand Russell, Creation of Hedonism and Narcissism, Devaluation of Others - Psychological Studies Continuously Done on Public - Loss of Non-verbal Communication and Interaction. De-industrialization of Britain - Lima Declaration, GATT, Transfer of Manufacturing to Developing Nations - Interdependence, Organic Society, Totalitarianism - Worldwide Scientific Dictatorship - Google / Microsoft Tracking System - Social Approval and Disapproval. (See http://www.cuttingthroughthematrix.com for article links.) *Title/Poem and Dialogue Copyrighted Alan Watt - May 31, 2010 (Exempting Music, Literary Quotes, and Callers' Comments)

[Audio] Nanoelectronic Modeling: From Quantum Mechanics and Atoms to Realistic Devices
Nanoelectronic Modeling Lecture 17: Introduction to RTDs - Relaxation Scattering in the Emitter

[Audio] Nanoelectronic Modeling: From Quantum Mechanics and Atoms to Realistic Devices

Play Episode Listen Later Jan 27, 2010


Realistic RTDs will have nonlinear electrostatic potential in their emitter. Typically a triangular well is formed in the emitter due to the applied bias and the emitter thus contains discrete quasi bound states.

[Audio] Nanoelectronic Modeling: From Quantum Mechanics and Atoms to Realistic Devices
Nanoelectronic Modeling Lecture 17: Introduction to RTDs - Relaxation Scattering in the Emitter

[Audio] Nanoelectronic Modeling: From Quantum Mechanics and Atoms to Realistic Devices

Play Episode Listen Later Jan 27, 2010


Realistic RTDs will have nonlinear electrostatic potential in their emitter. Typically a triangular well is formed in the emitter due to the applied bias and the emitter thus contains discrete quasi bound states.

Everyday Science
The Nature of Science Segment 3: More Microwave Experiments

Everyday Science

Play Episode Listen Later Nov 27, 2009 4:16


Sierra, Mary and Brian continue working with microwaves. This time they have constructed a working model of a microwave. They have connected a CD player to a microwave emitter and speakers to a microwave receiver. The microwave emitter carries the music to the receiver, where it is transmitted to the speakers. How can we prove this? Let's watch and find out!

Tierärztliche Fakultät - Digitale Hochschulschriften der LMU - Teil 01/07
Bewertung der lokoregionalen Radioimmuntherapie disseminierter Tumorzellen des diffusen Magenkarzinoms mit einem Bi-213 gekoppelten tumorspezifischen Antikörper im Mausmodell

Tierärztliche Fakultät - Digitale Hochschulschriften der LMU - Teil 01/07

Play Episode Listen Later Jul 17, 2003


Bei diffusen Magenkarzinomen treten in 50% aller Fälle Mutationen im Gen für das Adhäsionsmolekül E-Cadherin auf. Bei einem Fünftel dieser Mutationen ist Exon 9 deletiert, was die Expression einer mutationsspezifischen Proteinstruktur zur Folge hat (d9-E-Cad). Gegen diese tumorspezifische Bindungsstelle wurde ein monoklonaler Antikörper entwickelt(d9MAk). Dieser Antikörper wurde mit Wismut-213 (Bi-213) gekoppelt, einem hochenergetischen alpha-Emitter mit einer Reichweite von 80 µm im Gewebe, einem hohen linearen Energietransfer von 100 keV/µm und einer Halbwertszeit von 45,6 min. Um das therapeutische Potential des lokoregional applizierten Bi-213-Immuinkonjugats bei disseminierter Tumorzellaussaat gegen die Nebenwirkungen auf den Organismus beurteilen zu können, wurde ein Modell der Peritonealkarzinose bei Nacktmäusen durch intraperitoneale Inokulation von humanen Magenkarzinomzellen mit d9-Cad-Expression entwickelt. Sonographie und Kernspintomographie zeigten für die Visualisierung abdominaler Tumormanifestation und posttherapeutischer Tumorregression eine unzureichende Auflösung, während die In-vivo-Fluoreszenzanalyse "Optical Imaging" für diese Anwendungen erste, viel versprechende Ergebnisse lieferte. Diese Darstellungsmethode könnte in weiteren Studien für die Peritonealkarzinose optimiert werden. Mittels Biodistributionsstudien wurde die spezifische Bindung des Bi-213-d9MAk an den Tumor sowie die Verteilung im Organismus im Vegleich zu einem unspezifischen Kontrollantikörper untersucht. Die Bioverteilung zeigte neben einer hochspezifischen Bindung des Bi-213-d9MAk in Tumoren mit d9-E-Cad-Expression niedrige Konzentrationen des Radioimmunkonjugates im Blut und in den Organen. Bei vorliegendem Aszites blieb ein Großteil des Bi-213-d9MAk abdominal retiniert. Die Überlebenszeiten der Tiere nach Inokulation von 1x10E7 Tumorzellen wurden in Abhängigkeit von der applizierten Aktivität des Bi-213-d9MAk in verschiedenen Peritonealkarzinosestadien erfasst. Die mittlere Überlebenszeit von Tieren, die intraperitoneal mit 7,4 MBq Bi-213MAk am Tag 1 nach Tumorzellinokulation therapiert wurden, war mit 232 Tagen etwa zehnmal länger als jene von untherapierten Kontrolltieren, die bereits 24 Tage nach Tumorzellinokulation Aszites, große Tumormassen oder Tumokachexie zeigten. Bei spezifischer Therapie am Tag 8 nach Tumorzellinokulation, also bei fortgeschrittenem Karzinosestadium, verlängerte sich das Überleben der Mäuse auf 187 Tage. Der Unterschied im mittleren Überleben der Tiere nach Applikation von spezifischem Bi-213-d9MAk bzw. von unspezifischem Radioimmunkonjugat war nur bei Therapie am Tag 8 nach Tumorzellinokulation signifikant, da auch unspezifische Radioimmunkonjugate injiziert am Tag 1 nach Tumorzellinokulation deutliche Therapieerfolge bewirkten. Eine i.p. applizierte Aktivität von 22,2 MBq (600 µCi) führte etwa 180 Tage p.i. zu chronischem Nierenversagen. Ohne Nierenprotektion durch kationische Aminosäuren stellt die Niere somit das dosislimitierende Organ bei der Therapie mit Bi-213-d9MAk dar. Die Bewertung von Veränderungen der Tiergewichte ergab keinen toxischen Einfluss von 7,4 MBq (200 µCi) Bi-213-d9MAk auf den Säugetierorganismus. Die Leukozytenzahlen zeigten eine Abnahme in Abhängigkeit von der applizierten Aktivität, erholten sich aber innerhalb von 30 Tagen. Die Häufigkeit chromosomaler Aberrationen erhöhte sich mit zunehmender Aktivität bis 24 h nach Injektion des Bi-213-d9MAk. Zu späteren Zeitpunkten waren keine chromosomalen Aberrationen mehr nachweisbar. Das Radioimmunkonjugat Bi-213-d9MAk eignet sich nach den Resultaten dieser Studie hervorragend für die lokoregionale Anwendung bei disseminierter Tumorzellaussaat im Abdominalraum als Folge primären Magenkarzinoms mit Expression der d9-Mutante des E-Cadherins. Hohe therapeutische Effizienz, insbesondere bei Vorliegen von kleinen Tumorzellaggregaten und Einzelzellen, und niedrige Toxizität zeichnen das neue Radiopharmakon aus. Der therapeutische Einsatz des Bi-213-d9MAk empfiehlt sich besonders perioperativ bei Resektion eines soliden Magenkarzinoms zur Prophylaxe der Peritonealkarzinose aufgrund traumatischer Tumorzelldissemination.

Fakultät für Chemie und Pharmazie - Digitale Hochschulschriften der LMU - Teil 01/06
Epindolidione, Epindoline und lineare sowie trigonale Imidazolderivate

Fakultät für Chemie und Pharmazie - Digitale Hochschulschriften der LMU - Teil 01/06

Play Episode Listen Later Oct 25, 2001


1. Durch N-Alkylierung können sowohl 2,8- als auch 3,9-Dibenzo[b,g][1,5]naphthyridin- 6,12-dione (Epindolidione) löslich gemacht werden. Als Methylierungsagens bewährte sich besonders p-Toluolsulfonsäuremethylester in Kombination mit der Base Kaliumcarbonat. N H N H O O R R R' R' N N O O R R Alkyl Alkyl R' R' Base Alkylierungsagens 1.1. Die als Nebenprodukt entstehenden monoalkylierten Verbindungen können säulenchromatographisch von den Dialkylderivaten abgetrennt werden und zeichnen sich durch um 12 nm kürzerwellige Emissionsmaxima und kleinere Stokes-Verschiebungen gegenüber den Dialkylepindolidionen aus. 1.2. Die alkylierten Verbindungen absorbieren im Bereich 457-494 nm und emittieren bei 464-528 nm. Sie weisen sehr hohe Fluoreszenzquantenausbeuten von bis zu 98 % auf. 1.3. Photostabilitätsmessungen von N,N-Dimethyl-dibenzo[b,g][1,5]naphthyridin-6,12-dion (32d) und N,N-Dibutyl-dibenzo[b,g][1,5]naphthyridin-6,12-dion (32b) ergeben gute Resultate. 1.4. CV-Messungen von N,N-Dimethyl-dibenzo[b,g][1,5]naphthyridin-6,12-dion (32d) und 2,8,N,N-Tetramethyl-dibenzo[b,g][1,5]naphthyridin-6,12-dion (32e) zeigen, dass die Verbindungen leicht reduziert werden können (E1 Red = -1.17 für 32d und E1 Red = -1.22 für 32e). Werden sie in OLEDs eingesetzt, kann Aluminium statt der empfindlichen Calciumkathode verwendet werden. 1.5. Es konnten OLEDs mit 32d und 32e als Emitter gebaut werden, die intensive grüne Emission aufweisen. 1.6. Mittels Suzuki-Kupplung gelingt es neue 2,8- und 3,9-Aryl substituierte Epindolidione herzustellen wie z. B. 34a. 1.7. Die 3,9-Isomere absorbieren und emittieren kürzerwellig als die in 2,8-Stellung substituierten Verbindungen und weisen geringere Fluoreszenzquantenausbeuten auf. 2. Neben der Chlorierung von Dibenzo[b,g][1,5]naphthyridin-6,12-dion (27a) mittels Phosphoroxychlorid unter Zugabe von Kaliumcarbonat gelingt durch Schwefelung mit Phosphorpentasulfid und anschließender Methylierung der Zugang zu den Dibenzo[b,g][1,5]naphthyridinen (Epindolinen). 2.1. Verbindung 69 kann mit aliphatischen und aromatischen Stickstoffnucleophilen mit Quecksilberdichlorid als Katalysator zu 6,12-Diaminoepindolinen umgesetzt werden wie z. B. mit Butylamin zu 70a und mit Anilin zu 70b. Die Verbindungen absorbieren im Bereich von 481-547 nm und emittieren bei 506-571 nm. Hier zeichnet sich N,N’-Dibutyl-dibenzo[b,g][1,5]naphthyridin-6,12-diamin 70a durch eine hohe Fluoreszenzquantenausbeute aus, während die mit aromatischen Aminen substituierten Epindoline nur schwach oder gar nicht fluoreszieren. 2.2. Über die Kumada-Kupplung kann Verbindung 69 mit Arylmagnesiumbromiden umgesetzt werden wie z.B. mit Phenylmagnesiumbromid zu 74a. 2.3. Die Dichlorverbindung 58 lässt sich unter Suzuki-Bedingungen mit Arylboronsäuren kuppeln wie z.B. mit Thienylboronsäure zu 74e. 2.4. Unter Palladiumkatalyse können Alkinyltrialkylstannane mit der Dichlorverbindung 58 zur Reaktion gebracht werden (Stille-Kupplung). Hier muss darauf geachtet werden, dass die Temperatur von 100 °C nicht überschritten wird, da sonst Zersetzung eintritt. 2.5. Die Absorptionsmaxima der Aryl substituierten Epindoline liegen bei 476-553 nm, die Fluoreszenzmaxima bei 523-645 nm. Die Verbindungen weisen große Stokes- Verschiebungen auf. Dies kann auf eine Verdrillung zwischen dem Epindolingrundkörper und den Arylsubstituenten im Grundzustand zurückgeführt werden, die durch AM1-Rechnungen und Röntgenstrukturen belegt werden kann. Verbindung 74e besitzt in dieser Verbindungsreihe die größte Stokes-Verschiebung von 81 nm (2800 cm-1). 3. N-Lithiumhexamethyldisilazan addiert an die N-methylierten Imidazolylbenzonitrile 87 und 89 und man erhält nach der Umsetzung mit Trimethylchlorsilan die persilylierten Amidine 91b und 90. Diese lassen sich mit Vinamidiniumsalzen zu Pyrimidine wie z. B. 93b und 94a kondensieren. Diese Synthese eignet sich auch, um mit bifunktionellen Vinamidiniumsalzen dichromophore Systeme aufzubauen wie z. B. Verbindung 94c. 3.1. Die farblosen bis gelben Verbindungen fluoreszieren intensiv blau bis türkis und haben sehr hohe Fluoreszenzquantenausbeuten von bis zu 100 %. Sie weisen außerdem eine starke Emissionssolvatochromie auf. Der Solvatochromieumfang von z. B. Verbindung 94c beträgt für das Lösungsmittelpaar Toluol/Dimethylsulfoxid 68 nm (3130 cm-1). Neben der hohen Fluoreszenzquantenausbeute zeichnen sich die Verbindungen durch außerordentlich große Stokes-Verschiebungen von bis zu 144 nm (7820 cm-1) und gute Photostabilitäten aus. 4. Es können durch Kondensation verschiedener Trialdehyde 95, 96, 97, 98 und 128 mit aromatischen 1,2-Diketonen und Ammoniumacetat in Eisessig sternförmige trichromophore Imidazole aufgebaut werden. 4.1. Die fünf Verbindungsklassen 113, 115, 119, 124 und 126 zeichnen sich durch große molare Absorptionskoeffizienten, große Stokes-Verschiebungen und mäßige bis hohe Fluoreszenzquantenausbeuten aus. Die Verbindungsklasse 124 weist die kleinsten Fluoreszenzquantenausbeuten auf, da die Intensität der Fluoreszenz durch TICT-Zustände abgeschwächt wird. In den Absorptionsspektren aber noch stärker ausgeprägt in den Fluoreszenzspektren der Verbindungsklassen 115 und 119 ist eine positive Solvatochromie feststellbar. Für die Verbindungsklasse 124 findet man nur eine Solvatochromie in der Fluoreszenz. HRS-Messungen von Verbindung 119b bei einer Fundamentalwellenlänge von 1500 nm ergeben eine molare Hyperpolarisierbarkeit β von 28.8⋅10-30 esu, ein im Vergleich mit p- Nitroanilin β1500 = 18⋅10-30 esu guter Wert.

Fakultät für Chemie und Pharmazie - Digitale Hochschulschriften der LMU - Teil 01/06
Neue Fluoreszenzfarbstoffe mit Pyrrolo[3,4-c]pyrrol-Grundgerüst

Fakultät für Chemie und Pharmazie - Digitale Hochschulschriften der LMU - Teil 01/06

Play Episode Listen Later Sep 27, 2001


1. Durch eine basenfreie Variante der Suzuki-Reaktion gelingt es neue Aryl und Heteroaryl substituierte Pyrrolopyrrol-1,4-dione herzustellen, die durch N-Butylgruppen in vielen organischen Lösungsmitteln löslich sind. 1.1. Die neuen Farbstoffe zeichnen sich im Vergleich zum methylierten DPP-Grundkörper 24 durch höhere Stokes-Shifts (26-51%) bei guten Fluoreszenzquantenausbeuten (78- 89%) aus. 1.2. Anhand von Röntgen-Kristallstrukturanalysen der Verbindungen 38 und 41 kann der Einfluss von Packungseffekten auf die Festkörperfluoreszenz untersucht werden. Dabei zeigt sich, dass in der Packung von 41 die DPP-Chromophore relativ isoliert vorliegen. Die Anordnung in parallelen Doppelschichten in der Packung von 38 macht π-π- Wechselwirkungen zwischen den Chromophoren möglich, die zu einer bathochromen Verschiebung der Festkörperfluoreszenz führen. 2. In einer Eintopf-Reaktion kann durch Stannylierung mit Hexabutyldizinn und anschließende Stille-Reaktion die dichromophore Verbindung 45 in kleinen Ausbeuten hergestellt werden. Als Vergleichsverbindung wird die dichromphore Verbindung 47 durch Suzuki-Reaktion von 30 mit 4,4‘-Biphenylbisboronsäure synthetisiert. 2.1. Das unerwartete Absorptions- und Emissionsverhalten des Dichromophors 45 kann durch das Modell der Excitonenkopplung erklärt werden. 3. Durch die Verwendung von stöchiometrischen Mengen Tetrabutylammoniumbromid als Halogenidquelle zur Stabilisierung des Palladium-Katalysators gelingt die Umsetzung des Brom substituierten Pyrrolopyrrols 30 mit verschiedenen Styrolderivaten zu trans-Alkenyl substituierten DPP-Farbstoffen (Heck-Reaktion). 3.1. Die um eine Phenylvinyl-Einheit erweiterten Pyrrolopyrrole 55-57 zeigen große Stokes- Shifts bei mäßigen bis guten Fluoreszenzquantenausbeuten (47-78%). 3.2. Durch die freie Aminfunktion ist Verbindung 57 grundsätzlich als Fluoreszenzmarker für Immunoassays geeignet. 4. Alkinyltrialkylstannane reagieren mit 30 oder 31 unter Palladium-Katalyse zu Alkinyl substituierten DPP-Farbstoffen (Stille-Reaktion). 4.1. Das durch Desilylierung von 60 zugängliche Alkin 63 kann oxidativ zum Dichromophor 64 dimerisiert werden oder mit Dimethylaminotrimethylzinn stannyliert werden. Das Stannan 71 ermöglicht die Verknüpfung des DPP-Chromophors über eine Alkin-Brücke mit vielen Halogenaryl-Verbindungen unter sehr milden Bedingungen. 4.2. Die Alkinyl substituierten Pyrrolopyrrole zeigen große Stokes-Shifts bei mäßigen bis sehr guten Fluoreszenzquantenausbeuten (52-92%). 74 weist mit 81 nm den größten Stokes-Shift aller für diese Arbeit hergestellten und auch aller literaturbekannten Pyrrolopyrrol-1,4-dione auf. 4.3. Die über verschieden lange Alkin-Brücken verknüpften Dichromophore 64 und 70 zeichnen sich durch große langwellige Verschiebung der Absorption und der Emission gegenüber dem methylierten DPP-Grundkörper 24 aus. 4.4. Unter dem Aspekt der verminderten Aggregations- und Kristallisationsneigung wird der Tetraphenylmethan-Rest mit dem Pyrrolopyrrol-Chromophor verknüpft. Während das symmetrisch aufgebaute vierfach DPP substituierte Tetraphenylmethan 81 gut kristallisiert, zeigt die einfach DPP substituierte Verbindung 80 die erwartete schlechte Kristallisation. 4.5. Es wurde eine Zweischicht-OLED mit 59 als Emitter gebaut, die eine intensive orangefarbene Emission aufweist. 5. Durch die Palladium-katalysierte Aminierung nach Buchwald und Hartwig können verschiedene aliphatische und aromatische Amine mit dem Pyrrolopyrrol-1,4-dion- Chromophor verknüpft werden. Als effektivstes Katalysator/Basen-System erweist sich Pd2(dba)3/P(t-Bu)3 und Kaliumphosphat. 5.1. Die Cyclovoltammogramme der Verbindungen 83, 85 und 86 zeigen, dass diese Amine im selben Bereich oxidiert werden wie die im OLED-Bereich häufig verwendeten Lochleiter NPD und β-TPD. Die Reduzierbarkeit liegt in einem Bereich, der den Einsatz einer Aluminium- statt einer empfindlichen Calciumkathode in OLEDs möglich erscheinen lässt. 5.2. Aufgrund der Donorstärke der Aminsubstituenten weisen die Amine 83-87 in der Absorption und Emission große bathochrome Verschiebungen gegenüber dem methylierten DPP-Grundkörper 24 auf. 5.3. Mit 95% zeigt das zweifach Carbazol substituierte Pyrrolopyrrol 87 die höchste Fluoreszenzquantenausbeute aller für diese Arbeit hergestellten Verbindungen. 5.4. Die niedrige Fluoreszenzquantenausbeute des Phenothiazinyl substituierten Pyrrolopyrrols 85 von 12% in Chloroform, die im polareren Lösungsmittel Methylenchlorid auf 6% abnimmt, weist auf einen Photoelektronentransfer (PET) vom elektronenreichen Phenothiazin auf den Elektronenakzeptor Pyrrolopyrrol-1,4-dion hin. 5.5. Das aliphatisch substituierte Amin 86 wird in einem Essigsäure/2 N Schwefelsäure- Gemisch protoniert. Dadurch verschieben sich Absorption und Emission hypsochrom um ca. 40 nm. 5.6. 84 und 87 bilden in Essigsäure H-Aggregate aus. Darauf deuten die in Essigsäure um ca. 20 nm hypsochrom gegenüber den Messungen in Chloroform verschobenen Absorptionswellenlängen bei unveränderter Fluoreszenz hin. Die in Essigsäure unveränderte Fluoreszenz kann durch die Emission isolierter Einzelmoleküle erklärt werden. H-aggregierte Moleküle zeigen keine Fluoreszenz. 6. Unter den Bedingungen der Suzuki-Reaktion kann das Dichlor substituierte 1,4- Dimethylaminopyrrolopyrrol 94 mit Arylboronsäuren zu den Aryl substituierten Dimethylaminopyrrolopyrrolen 99-104 umgesetzt werden. 6.1. Die unterschiedlichen Absorptions- und Emissionseigenschaften von 99-104 können durch den Donor/Akzeptor-Einfluss der Arylreste auf die Grenzorbitale des Dimethylaminopyrrolopyrrols nicht vollständig erklärt werden. Erst durch die Berücksichtigung der Verdrillung der Arylreste gegenüber dem Pyrrolopyrrol-Chromophor (aus AM1- optimierten Strukturberechnungen) können die spektroskopischen Daten gedeutet werden. 7. Phenylacetylen und TMS-Acetylen reagieren unter Palladium-Katalyse in Gegenwart von Kupfer(I)iodid und Triethylamin zu den Alkinyl substituierten Dimethylaminopyrrolopyrrolen 105 und 106 (Sonogashira-Reaktion). 7.1. Die geringen Stokes-Shifts von 105 und 106 können auf die – nach AM1-Rechung – planare Geometrie dieser Verbindungen im Grundzustand zurückgeführt werden.